Synthesis, characterization and thermal properties of 1,10-phenanthroline mixed-ligand complexes of cobalt(II) and copper(II): metal-mediated transformations of the dicyanamide ion
The reaction of 1,10-phenanthroline and dicyanamide ligands with Cu(II) and Co(II) nitrates afforded the complexes [Cu(phen)(BMCA)](NO 3 )] ( 1 ) and [Co(phen) 2 (NO 3 )](dcg-)·(H 2 O) ( 2 ). The dicyanamide anion was transformed in 1 and 2 to bis(methoxycarbimido)aminato (BMCA) and dicyanoguanidina...
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| Veröffentlicht in: | Chemical papers 2020-09, Vol.74 (9), p.3003-3016 |
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| creator | Eni, Donatus B. Yufanyi, Divine M. Nono, Jean H. Tabong, Che D. Agwara, Moise O. |
| description | The reaction of 1,10-phenanthroline and dicyanamide ligands with Cu(II) and Co(II) nitrates afforded the complexes [Cu(phen)(BMCA)](NO
3
)] (
1
) and [Co(phen)
2
(NO
3
)](dcg-)·(H
2
O) (
2
). The dicyanamide anion was transformed in
1
and
2
to bis(methoxycarbimido)aminato (BMCA) and dicyanoguanidinate (dcg) anions, respectively. The complexes were characterized by elemental analysis, infrared spectroscopy and ultraviolet–visible spectroscopy, magnetic susceptibility measurement and X-ray crystallography. Both complexes crystallize in the monoclinic crystal system, and the structures are stabilized by extended hydrogen bonding networks as well as aromatic π–π stacking interactions. The thermal and antimicrobial properties of the complexes have also been evaluated. Density functional theory calculations were also performed in order to gain insights into the molecular interactions in the synthesized compounds and to predict some of their electronic properties. |
| doi_str_mv | 10.1007/s11696-020-01109-1 |
| format | Article |
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3
)] (
1
) and [Co(phen)
2
(NO
3
)](dcg-)·(H
2
O) (
2
). The dicyanamide anion was transformed in
1
and
2
to bis(methoxycarbimido)aminato (BMCA) and dicyanoguanidinate (dcg) anions, respectively. The complexes were characterized by elemental analysis, infrared spectroscopy and ultraviolet–visible spectroscopy, magnetic susceptibility measurement and X-ray crystallography. Both complexes crystallize in the monoclinic crystal system, and the structures are stabilized by extended hydrogen bonding networks as well as aromatic π–π stacking interactions. The thermal and antimicrobial properties of the complexes have also been evaluated. Density functional theory calculations were also performed in order to gain insights into the molecular interactions in the synthesized compounds and to predict some of their electronic properties.</description><identifier>ISSN: 2585-7290</identifier><identifier>ISSN: 0366-6352</identifier><identifier>EISSN: 1336-9075</identifier><identifier>DOI: 10.1007/s11696-020-01109-1</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Anions ; Biochemistry ; Biotechnology ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Coordination compounds ; Copper ; Copper compounds ; Crystal structure ; Crystallography ; Density functional theory ; Hydrogen bonding ; Industrial Chemistry/Chemical Engineering ; Infrared analysis ; Ligands ; Magnetic permeability ; Materials Science ; Medicinal Chemistry ; Molecular interactions ; Original Paper ; Spectrum analysis ; Thermodynamic properties</subject><ispartof>Chemical papers, 2020-09, Vol.74 (9), p.3003-3016</ispartof><rights>Institute of Chemistry, Slovak Academy of Sciences 2020</rights><rights>Institute of Chemistry, Slovak Academy of Sciences 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-a1d524da3f649e4f4ab5345ccf4ddf132c63af06ac809ecbbc90894bac2b1e523</citedby><cites>FETCH-LOGICAL-c356t-a1d524da3f649e4f4ab5345ccf4ddf132c63af06ac809ecbbc90894bac2b1e523</cites><orcidid>0000-0001-8889-611X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11696-020-01109-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11696-020-01109-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Eni, Donatus B.</creatorcontrib><creatorcontrib>Yufanyi, Divine M.</creatorcontrib><creatorcontrib>Nono, Jean H.</creatorcontrib><creatorcontrib>Tabong, Che D.</creatorcontrib><creatorcontrib>Agwara, Moise O.</creatorcontrib><title>Synthesis, characterization and thermal properties of 1,10-phenanthroline mixed-ligand complexes of cobalt(II) and copper(II): metal-mediated transformations of the dicyanamide ion</title><title>Chemical papers</title><addtitle>Chem. Pap</addtitle><description>The reaction of 1,10-phenanthroline and dicyanamide ligands with Cu(II) and Co(II) nitrates afforded the complexes [Cu(phen)(BMCA)](NO
3
)] (
1
) and [Co(phen)
2
(NO
3
)](dcg-)·(H
2
O) (
2
). The dicyanamide anion was transformed in
1
and
2
to bis(methoxycarbimido)aminato (BMCA) and dicyanoguanidinate (dcg) anions, respectively. The complexes were characterized by elemental analysis, infrared spectroscopy and ultraviolet–visible spectroscopy, magnetic susceptibility measurement and X-ray crystallography. Both complexes crystallize in the monoclinic crystal system, and the structures are stabilized by extended hydrogen bonding networks as well as aromatic π–π stacking interactions. The thermal and antimicrobial properties of the complexes have also been evaluated. Density functional theory calculations were also performed in order to gain insights into the molecular interactions in the synthesized compounds and to predict some of their electronic properties.</description><subject>Anions</subject><subject>Biochemistry</subject><subject>Biotechnology</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Coordination compounds</subject><subject>Copper</subject><subject>Copper compounds</subject><subject>Crystal structure</subject><subject>Crystallography</subject><subject>Density functional theory</subject><subject>Hydrogen bonding</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Infrared analysis</subject><subject>Ligands</subject><subject>Magnetic permeability</subject><subject>Materials Science</subject><subject>Medicinal Chemistry</subject><subject>Molecular interactions</subject><subject>Original Paper</subject><subject>Spectrum analysis</subject><subject>Thermodynamic properties</subject><issn>2585-7290</issn><issn>0366-6352</issn><issn>1336-9075</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kU1rFTEUhoMoeKn9A64CbhQazdd8uZNS2wsFF7brcCY56Y3MJGMyhV5_lz_Q3I7gzlVIzvuc95y8hLwV_KPgvPtUhGiHlnHJGReCD0y8IDuhVMsG3jUvyU42fcM6OfDX5LyUMHKtOyX7ttuR39-PcT1gCeWC2gNksCvm8AvWkCKF6Ggt5hkmuuS0YF4DFpo8FReCs-WAESqd0xQi0jk8oWNTeDhhNs3LhE-b2qYRpvX9fv-BbrWltjpdP9MZV5jYjC7AitUtQyw-VcfTAM9wHYC6YI8QYQ4OaX1_Q155mAqe_z3PyP3Xq7vLG3b77Xp_-eWWWdW0KwPhGqkdKN_qAbXXMDZKN9Z67ZwXStpWgect2J4PaMfRDrwf9AhWjgIbqc7Iu61vXf7nI5bV_EiPOVZLI7XQ9cPbvqkqualsTqVk9GbJYYZ8NIKbU0BmC8hUvXkOyIgKqQ0qVRwfMP9r_R_qD85Ul1A</recordid><startdate>20200901</startdate><enddate>20200901</enddate><creator>Eni, Donatus B.</creator><creator>Yufanyi, Divine M.</creator><creator>Nono, Jean H.</creator><creator>Tabong, Che D.</creator><creator>Agwara, Moise O.</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-8889-611X</orcidid></search><sort><creationdate>20200901</creationdate><title>Synthesis, characterization and thermal properties of 1,10-phenanthroline mixed-ligand complexes of cobalt(II) and copper(II): metal-mediated transformations of the dicyanamide ion</title><author>Eni, Donatus B. ; Yufanyi, Divine M. ; Nono, Jean H. ; Tabong, Che D. ; Agwara, Moise O.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-a1d524da3f649e4f4ab5345ccf4ddf132c63af06ac809ecbbc90894bac2b1e523</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Anions</topic><topic>Biochemistry</topic><topic>Biotechnology</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Coordination compounds</topic><topic>Copper</topic><topic>Copper compounds</topic><topic>Crystal structure</topic><topic>Crystallography</topic><topic>Density functional theory</topic><topic>Hydrogen bonding</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Infrared analysis</topic><topic>Ligands</topic><topic>Magnetic permeability</topic><topic>Materials Science</topic><topic>Medicinal Chemistry</topic><topic>Molecular interactions</topic><topic>Original Paper</topic><topic>Spectrum analysis</topic><topic>Thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Eni, Donatus B.</creatorcontrib><creatorcontrib>Yufanyi, Divine M.</creatorcontrib><creatorcontrib>Nono, Jean H.</creatorcontrib><creatorcontrib>Tabong, Che D.</creatorcontrib><creatorcontrib>Agwara, Moise O.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical papers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Eni, Donatus B.</au><au>Yufanyi, Divine M.</au><au>Nono, Jean H.</au><au>Tabong, Che D.</au><au>Agwara, Moise O.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, characterization and thermal properties of 1,10-phenanthroline mixed-ligand complexes of cobalt(II) and copper(II): metal-mediated transformations of the dicyanamide ion</atitle><jtitle>Chemical papers</jtitle><stitle>Chem. Pap</stitle><date>2020-09-01</date><risdate>2020</risdate><volume>74</volume><issue>9</issue><spage>3003</spage><epage>3016</epage><pages>3003-3016</pages><issn>2585-7290</issn><issn>0366-6352</issn><eissn>1336-9075</eissn><abstract>The reaction of 1,10-phenanthroline and dicyanamide ligands with Cu(II) and Co(II) nitrates afforded the complexes [Cu(phen)(BMCA)](NO
3
)] (
1
) and [Co(phen)
2
(NO
3
)](dcg-)·(H
2
O) (
2
). The dicyanamide anion was transformed in
1
and
2
to bis(methoxycarbimido)aminato (BMCA) and dicyanoguanidinate (dcg) anions, respectively. The complexes were characterized by elemental analysis, infrared spectroscopy and ultraviolet–visible spectroscopy, magnetic susceptibility measurement and X-ray crystallography. Both complexes crystallize in the monoclinic crystal system, and the structures are stabilized by extended hydrogen bonding networks as well as aromatic π–π stacking interactions. The thermal and antimicrobial properties of the complexes have also been evaluated. Density functional theory calculations were also performed in order to gain insights into the molecular interactions in the synthesized compounds and to predict some of their electronic properties.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s11696-020-01109-1</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0001-8889-611X</orcidid></addata></record> |
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| ispartof | Chemical papers, 2020-09, Vol.74 (9), p.3003-3016 |
| issn | 2585-7290 0366-6352 1336-9075 |
| language | eng |
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| source | SpringerNature Journals |
| subjects | Anions Biochemistry Biotechnology Chemical synthesis Chemistry Chemistry and Materials Science Chemistry/Food Science Coordination compounds Copper Copper compounds Crystal structure Crystallography Density functional theory Hydrogen bonding Industrial Chemistry/Chemical Engineering Infrared analysis Ligands Magnetic permeability Materials Science Medicinal Chemistry Molecular interactions Original Paper Spectrum analysis Thermodynamic properties |
| title | Synthesis, characterization and thermal properties of 1,10-phenanthroline mixed-ligand complexes of cobalt(II) and copper(II): metal-mediated transformations of the dicyanamide ion |
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