Sum of oscillator-strength moments and asymptotic behaviour of thermally induced broadening and shift of energy levels of Rydberg atom circular states

Based on the rules for summing oscillator-strength moments, we derive analytical expressions for environmentally (thermally) induced energy-level shifts and broadenings of circular Rydberg states with maximum orbital (l) and magnetic (m) quantum numbers, l = |m| = n - 1. The formulae for the energy...

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Veröffentlicht in:Quantum electronics (Woodbury, N.Y.) N.Y.), 2020-06, Vol.50 (6), p.581-589
Hauptverfasser: Glukhov, I.L., Kamenski, A.A., Ovsiannikov, V.D.
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creator Glukhov, I.L.
Kamenski, A.A.
Ovsiannikov, V.D.
description Based on the rules for summing oscillator-strength moments, we derive analytical expressions for environmentally (thermally) induced energy-level shifts and broadenings of circular Rydberg states with maximum orbital (l) and magnetic (m) quantum numbers, l = |m| = n - 1. The formulae for the energy of interaction with blackbody radiation are presented in the form of series expansion in even powers of the small parameter η = Z2/(n3kBT) ≪ 1 in the region of high temperatures T and principal quantum numbers n (Z is the charge of the residual ion). The expression for the thermally induced width contains a negative temperature-independent term coinciding in absolute value with the spontaneous width, so that the temperature-independent term is absent in the expression for the sum of the spontaneous and thermally induced widths. A similar expansion in powers of η for the thermally induced shift also contains a temperature-independent term proportional to 1/n6.
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subjects Asymptotic properties
ASYMPTOTIC SOLUTIONS
ATOMIC AND MOLECULAR PHYSICS
ATOMS
Black body radiation
BLACKBODY RADIATION
CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS
CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Energy levels
INTERACTIONS
Mathematical analysis
OSCILLATOR STRENGTHS
QUANTUM NUMBERS
RYDBERG STATES
Series expansion
TEMPERATURE RANGE 0400-1000 K
title Sum of oscillator-strength moments and asymptotic behaviour of thermally induced broadening and shift of energy levels of Rydberg atom circular states
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