Furfuryl Cation Induced Three‐Component Reaction to Synthesize Triazole‐Substituted Thioesters

A furfuryl cation induced three‐component thioesterification reaction between thiols, 5‐bromo‐2‐furylcarbinols and azides is reported. This metal‐free method relies on the acetyl chloride/HFIP‐mediated cascade formal [3+2] cycloaddition/ring‐opening/thioesterification, which allows the efficient con...

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Veröffentlicht in:	European journal of organic chemistry 2020-06, Vol.2020 (22), p.3251-3256
Hauptverfasser:	Zhong, Ying, Xu, Xiaoming, Xing, Qingzhao, Yang, Song, Gou, Jing, Gao, Ziwei, Yu, Binxun
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetyl chloride Cations Chemical synthesis Cycloaddition Dearomatization Furans Multicomponent reactions Synthetic methods Thioesterification Thioesters Thiols Triazoles
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