Luminescent properties of a polymeric copper(I)-bromide complex in a PMMA film

The [Cu2Br2(DIB)2(PPh2)2]n complex, obtained by the reaction between [Cu4Br4(PPh3)4] and 1,4-diisocyanobenzene (DIB), was found to have a bridged polymeric structure with a planar {Cu2Br2} core. The compound exhibited bluish-green (λmax = 498 nm) and green (λmax = 515 nm) luminescence at 295 and 77...

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Veröffentlicht in:	Japanese Journal of Applied Physics 2020-07, Vol.59 (7), p.77001
Hauptverfasser:	Nanzan, Chika, Takazawa, Yorimasa, Suzuki, Mitsuaki, Teramae, Hiroyuki, Sakata, Tomomi
Format:	Artikel
Sprache:	eng
Schlagworte:	Color Coordination compounds Cu(I) complex dual emission Luminescence mechanochromism Optical properties PMMA film Polymethyl methacrylate Restoration thermochromism
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