The effect of B2O3/CdO substitution on structural, thermal, and optical properties of new black PVB/Cd semiconducting oxide glasses
Novel semiconducting P 2 O 5 –V 2 O 5 –(B 2 O 3 /CdO) oxide glasses containing high ratios of V 2 O 5 and P 2 O 5 were synthesized with melting–quenching method and their characterizations were performed. B 2 O 3 were gradually replaced with CdO within the structure. Structural characteristics of th...
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| Veröffentlicht in: | Applied physics. A, Materials science & processing Materials science & processing, 2020-07, Vol.126 (7), Article 507 |
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| creator | Kilic, Gokhan Ilik, Erkan Issever, U. Gokhan Peker, Mehmet |
| description | Novel semiconducting P
2
O
5
–V
2
O
5
–(B
2
O
3
/CdO) oxide glasses containing high ratios of V
2
O
5
and P
2
O
5
were synthesized with melting–quenching method and their characterizations were performed. B
2
O
3
were gradually replaced with CdO within the structure. Structural characteristics of the synthesized glasses were determined with XRD, SEM–EDS, and Fourier transform infrared spectroscopy (FTIR) with diamond ATR. Amorphous character of the glasses was determined with XRD and supported additionally with SEM images. The presence of CdO within the structure was confirmed with EDX spectrum. Structural units of vanadium, phosphate, and boron were determined with FTIR examination. CdO was observed to be present in the structure as a modifier. According to DSC data, glass transition (
T
g
), crystallization (
T
c
), melting (
T
m
) temperatures, and thermal stabilities (Δ
T
) were determined, and their relation with B
2
O
3
/CdO substitution was explained. According to DSC data,
T
g
decreased to 425 °C from 431 °C with the replacement of B
2
O
3
with CdO;
T
c
, increased to 509 °C from 494 °C. Thermal stabilities of the synthesized glass samples increased to 84 °C from 63 °C. Transmittance and absorption spectra were obtained between the range of 200–3000 nm, and the transmittance belonging to the samples was observed to start around 1800 nm. Direct and indirect optical band gaps were determined with Tauc method. In addition, Urbach energies of the samples were determined and obtained results were evaluated. The newly synthesized cadmium–vanadium–phosphate glass is appropriate to be used as an absorbent layer in solar energy systems. |
| doi_str_mv | 10.1007/s00339-020-03689-x |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2412158270</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2412158270</sourcerecordid><originalsourceid>FETCH-LOGICAL-c319t-313f892d8cdd8891f9bc3d9855ac9ed208cd46f50559a1237f6d97a9e0a182b63</originalsourceid><addsrcrecordid>eNp9kEtLAzEUhYMoWKt_wFXArWNvknkkS1t8QaEuqtuQ5tFOnc7UJIN17R83tYI7Lxdu4J7z3XAQuiRwQwCqUQBgTGRAIQNWcpHtjtCA5IxmUDI4RgMQeZVxJspTdBbCGlLllA7Q13xlsXXO6og7h8d0xkYTM8OhX4RYxz7WXYtTh-h7HXuvmmscV9Zv9g_VGtxtY61Vg7e-21ofaxv2nNZ-4EWj9Bt-fh0nIA52U-uuNQlSt0vc7Wpj8bJRIdhwjk6caoK9-J1D9HJ_N588ZtPZw9PkdpppRkTMGGGOC2q4NoZzQZxYaGYELwqlhTUU0iIvXQFFIRShrHKlEZUSFhThdFGyIbo6cNNf33sbolx3vW_TSUlzQknBaQVJRQ8q7bsQvHVy6-uN8p-SgNyHLQ9hyxS2_Alb7pKJHUwhidul9X_of1zfjwGDVg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2412158270</pqid></control><display><type>article</type><title>The effect of B2O3/CdO substitution on structural, thermal, and optical properties of new black PVB/Cd semiconducting oxide glasses</title><source>SpringerLink Journals</source><creator>Kilic, Gokhan ; Ilik, Erkan ; Issever, U. Gokhan ; Peker, Mehmet</creator><creatorcontrib>Kilic, Gokhan ; Ilik, Erkan ; Issever, U. Gokhan ; Peker, Mehmet</creatorcontrib><description>Novel semiconducting P
2
O
5
–V
2
O
5
–(B
2
O
3
/CdO) oxide glasses containing high ratios of V
2
O
5
and P
2
O
5
were synthesized with melting–quenching method and their characterizations were performed. B
2
O
3
were gradually replaced with CdO within the structure. Structural characteristics of the synthesized glasses were determined with XRD, SEM–EDS, and Fourier transform infrared spectroscopy (FTIR) with diamond ATR. Amorphous character of the glasses was determined with XRD and supported additionally with SEM images. The presence of CdO within the structure was confirmed with EDX spectrum. Structural units of vanadium, phosphate, and boron were determined with FTIR examination. CdO was observed to be present in the structure as a modifier. According to DSC data, glass transition (
T
g
), crystallization (
T
c
), melting (
T
m
) temperatures, and thermal stabilities (Δ
T
) were determined, and their relation with B
2
O
3
/CdO substitution was explained. According to DSC data,
T
g
decreased to 425 °C from 431 °C with the replacement of B
2
O
3
with CdO;
T
c
, increased to 509 °C from 494 °C. Thermal stabilities of the synthesized glass samples increased to 84 °C from 63 °C. Transmittance and absorption spectra were obtained between the range of 200–3000 nm, and the transmittance belonging to the samples was observed to start around 1800 nm. Direct and indirect optical band gaps were determined with Tauc method. In addition, Urbach energies of the samples were determined and obtained results were evaluated. The newly synthesized cadmium–vanadium–phosphate glass is appropriate to be used as an absorbent layer in solar energy systems.</description><identifier>ISSN: 0947-8396</identifier><identifier>EISSN: 1432-0630</identifier><identifier>DOI: 10.1007/s00339-020-03689-x</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Absorption spectra ; Applied physics ; Boron ; Boron oxides ; Characterization and Evaluation of Materials ; Condensed Matter Physics ; Crystallization ; Diamonds ; Fourier transforms ; Glass transition ; Infrared spectroscopy ; Machines ; Manufacturing ; Materials science ; Nanotechnology ; Optical and Electronic Materials ; Optical properties ; Phosphate glass ; Phosphorus pentoxide ; Physics ; Physics and Astronomy ; Processes ; Solar energy ; Spectrum analysis ; Substitutes ; Surfaces and Interfaces ; Synthesis ; Thin Films ; Transmittance ; Vanadium pentoxide</subject><ispartof>Applied physics. A, Materials science & processing, 2020-07, Vol.126 (7), Article 507</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020</rights><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-313f892d8cdd8891f9bc3d9855ac9ed208cd46f50559a1237f6d97a9e0a182b63</citedby><cites>FETCH-LOGICAL-c319t-313f892d8cdd8891f9bc3d9855ac9ed208cd46f50559a1237f6d97a9e0a182b63</cites><orcidid>0000-0003-2986-0015 ; 0000-0001-7145-4999 ; 0000-0002-6762-6898</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00339-020-03689-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00339-020-03689-x$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Kilic, Gokhan</creatorcontrib><creatorcontrib>Ilik, Erkan</creatorcontrib><creatorcontrib>Issever, U. Gokhan</creatorcontrib><creatorcontrib>Peker, Mehmet</creatorcontrib><title>The effect of B2O3/CdO substitution on structural, thermal, and optical properties of new black PVB/Cd semiconducting oxide glasses</title><title>Applied physics. A, Materials science & processing</title><addtitle>Appl. Phys. A</addtitle><description>Novel semiconducting P
2
O
5
–V
2
O
5
–(B
2
O
3
/CdO) oxide glasses containing high ratios of V
2
O
5
and P
2
O
5
were synthesized with melting–quenching method and their characterizations were performed. B
2
O
3
were gradually replaced with CdO within the structure. Structural characteristics of the synthesized glasses were determined with XRD, SEM–EDS, and Fourier transform infrared spectroscopy (FTIR) with diamond ATR. Amorphous character of the glasses was determined with XRD and supported additionally with SEM images. The presence of CdO within the structure was confirmed with EDX spectrum. Structural units of vanadium, phosphate, and boron were determined with FTIR examination. CdO was observed to be present in the structure as a modifier. According to DSC data, glass transition (
T
g
), crystallization (
T
c
), melting (
T
m
) temperatures, and thermal stabilities (Δ
T
) were determined, and their relation with B
2
O
3
/CdO substitution was explained. According to DSC data,
T
g
decreased to 425 °C from 431 °C with the replacement of B
2
O
3
with CdO;
T
c
, increased to 509 °C from 494 °C. Thermal stabilities of the synthesized glass samples increased to 84 °C from 63 °C. Transmittance and absorption spectra were obtained between the range of 200–3000 nm, and the transmittance belonging to the samples was observed to start around 1800 nm. Direct and indirect optical band gaps were determined with Tauc method. In addition, Urbach energies of the samples were determined and obtained results were evaluated. The newly synthesized cadmium–vanadium–phosphate glass is appropriate to be used as an absorbent layer in solar energy systems.</description><subject>Absorption spectra</subject><subject>Applied physics</subject><subject>Boron</subject><subject>Boron oxides</subject><subject>Characterization and Evaluation of Materials</subject><subject>Condensed Matter Physics</subject><subject>Crystallization</subject><subject>Diamonds</subject><subject>Fourier transforms</subject><subject>Glass transition</subject><subject>Infrared spectroscopy</subject><subject>Machines</subject><subject>Manufacturing</subject><subject>Materials science</subject><subject>Nanotechnology</subject><subject>Optical and Electronic Materials</subject><subject>Optical properties</subject><subject>Phosphate glass</subject><subject>Phosphorus pentoxide</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Processes</subject><subject>Solar energy</subject><subject>Spectrum analysis</subject><subject>Substitutes</subject><subject>Surfaces and Interfaces</subject><subject>Synthesis</subject><subject>Thin Films</subject><subject>Transmittance</subject><subject>Vanadium pentoxide</subject><issn>0947-8396</issn><issn>1432-0630</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLAzEUhYMoWKt_wFXArWNvknkkS1t8QaEuqtuQ5tFOnc7UJIN17R83tYI7Lxdu4J7z3XAQuiRwQwCqUQBgTGRAIQNWcpHtjtCA5IxmUDI4RgMQeZVxJspTdBbCGlLllA7Q13xlsXXO6og7h8d0xkYTM8OhX4RYxz7WXYtTh-h7HXuvmmscV9Zv9g_VGtxtY61Vg7e-21ofaxv2nNZ-4EWj9Bt-fh0nIA52U-uuNQlSt0vc7Wpj8bJRIdhwjk6caoK9-J1D9HJ_N588ZtPZw9PkdpppRkTMGGGOC2q4NoZzQZxYaGYELwqlhTUU0iIvXQFFIRShrHKlEZUSFhThdFGyIbo6cNNf33sbolx3vW_TSUlzQknBaQVJRQ8q7bsQvHVy6-uN8p-SgNyHLQ9hyxS2_Alb7pKJHUwhidul9X_of1zfjwGDVg</recordid><startdate>20200701</startdate><enddate>20200701</enddate><creator>Kilic, Gokhan</creator><creator>Ilik, Erkan</creator><creator>Issever, U. Gokhan</creator><creator>Peker, Mehmet</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-2986-0015</orcidid><orcidid>https://orcid.org/0000-0001-7145-4999</orcidid><orcidid>https://orcid.org/0000-0002-6762-6898</orcidid></search><sort><creationdate>20200701</creationdate><title>The effect of B2O3/CdO substitution on structural, thermal, and optical properties of new black PVB/Cd semiconducting oxide glasses</title><author>Kilic, Gokhan ; Ilik, Erkan ; Issever, U. Gokhan ; Peker, Mehmet</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-313f892d8cdd8891f9bc3d9855ac9ed208cd46f50559a1237f6d97a9e0a182b63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Absorption spectra</topic><topic>Applied physics</topic><topic>Boron</topic><topic>Boron oxides</topic><topic>Characterization and Evaluation of Materials</topic><topic>Condensed Matter Physics</topic><topic>Crystallization</topic><topic>Diamonds</topic><topic>Fourier transforms</topic><topic>Glass transition</topic><topic>Infrared spectroscopy</topic><topic>Machines</topic><topic>Manufacturing</topic><topic>Materials science</topic><topic>Nanotechnology</topic><topic>Optical and Electronic Materials</topic><topic>Optical properties</topic><topic>Phosphate glass</topic><topic>Phosphorus pentoxide</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Processes</topic><topic>Solar energy</topic><topic>Spectrum analysis</topic><topic>Substitutes</topic><topic>Surfaces and Interfaces</topic><topic>Synthesis</topic><topic>Thin Films</topic><topic>Transmittance</topic><topic>Vanadium pentoxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kilic, Gokhan</creatorcontrib><creatorcontrib>Ilik, Erkan</creatorcontrib><creatorcontrib>Issever, U. Gokhan</creatorcontrib><creatorcontrib>Peker, Mehmet</creatorcontrib><collection>CrossRef</collection><jtitle>Applied physics. A, Materials science & processing</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kilic, Gokhan</au><au>Ilik, Erkan</au><au>Issever, U. Gokhan</au><au>Peker, Mehmet</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The effect of B2O3/CdO substitution on structural, thermal, and optical properties of new black PVB/Cd semiconducting oxide glasses</atitle><jtitle>Applied physics. A, Materials science & processing</jtitle><stitle>Appl. Phys. A</stitle><date>2020-07-01</date><risdate>2020</risdate><volume>126</volume><issue>7</issue><artnum>507</artnum><issn>0947-8396</issn><eissn>1432-0630</eissn><abstract>Novel semiconducting P
2
O
5
–V
2
O
5
–(B
2
O
3
/CdO) oxide glasses containing high ratios of V
2
O
5
and P
2
O
5
were synthesized with melting–quenching method and their characterizations were performed. B
2
O
3
were gradually replaced with CdO within the structure. Structural characteristics of the synthesized glasses were determined with XRD, SEM–EDS, and Fourier transform infrared spectroscopy (FTIR) with diamond ATR. Amorphous character of the glasses was determined with XRD and supported additionally with SEM images. The presence of CdO within the structure was confirmed with EDX spectrum. Structural units of vanadium, phosphate, and boron were determined with FTIR examination. CdO was observed to be present in the structure as a modifier. According to DSC data, glass transition (
T
g
), crystallization (
T
c
), melting (
T
m
) temperatures, and thermal stabilities (Δ
T
) were determined, and their relation with B
2
O
3
/CdO substitution was explained. According to DSC data,
T
g
decreased to 425 °C from 431 °C with the replacement of B
2
O
3
with CdO;
T
c
, increased to 509 °C from 494 °C. Thermal stabilities of the synthesized glass samples increased to 84 °C from 63 °C. Transmittance and absorption spectra were obtained between the range of 200–3000 nm, and the transmittance belonging to the samples was observed to start around 1800 nm. Direct and indirect optical band gaps were determined with Tauc method. In addition, Urbach energies of the samples were determined and obtained results were evaluated. The newly synthesized cadmium–vanadium–phosphate glass is appropriate to be used as an absorbent layer in solar energy systems.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00339-020-03689-x</doi><orcidid>https://orcid.org/0000-0003-2986-0015</orcidid><orcidid>https://orcid.org/0000-0001-7145-4999</orcidid><orcidid>https://orcid.org/0000-0002-6762-6898</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0947-8396 |
| ispartof | Applied physics. A, Materials science & processing, 2020-07, Vol.126 (7), Article 507 |
| issn | 0947-8396 1432-0630 |
| language | eng |
| recordid | cdi_proquest_journals_2412158270 |
| source | SpringerLink Journals |
| subjects | Absorption spectra Applied physics Boron Boron oxides Characterization and Evaluation of Materials Condensed Matter Physics Crystallization Diamonds Fourier transforms Glass transition Infrared spectroscopy Machines Manufacturing Materials science Nanotechnology Optical and Electronic Materials Optical properties Phosphate glass Phosphorus pentoxide Physics Physics and Astronomy Processes Solar energy Spectrum analysis Substitutes Surfaces and Interfaces Synthesis Thin Films Transmittance Vanadium pentoxide |
| title | The effect of B2O3/CdO substitution on structural, thermal, and optical properties of new black PVB/Cd semiconducting oxide glasses |
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