Transition metal-free B(dan)-installing reaction (dan: naphthalene-1,8-diaminato): H-B(dan) as a B(dan) electrophile

H-B(dan) was demonstrated to serve as a B(dan) electrophile, despite its highly diminished boron-Lewis acidity, leading to direct and transition metal-free approach to R-B(dan) of high synthetic utility upon treatment with Grignard reagents. Iterative cross-coupling of 5-bromo-2-pyridyl-B(dan), synt...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2020-06, Vol.56 (47), p.6388-6391
Hauptverfasser:	Li, Jialun, Seki, Michinari, Kamio, Shintaro, Yoshida, Hiroto
Format:	Artikel
Sprache:	eng
Schlagworte:	Boron Cross coupling Naphthalene Reagents Transition metals
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creator	Li, Jialun Seki, Michinari Kamio, Shintaro Yoshida, Hiroto
description	H-B(dan) was demonstrated to serve as a B(dan) electrophile, despite its highly diminished boron-Lewis acidity, leading to direct and transition metal-free approach to R-B(dan) of high synthetic utility upon treatment with Grignard reagents. Iterative cross-coupling of 5-bromo-2-pyridyl-B(dan), synthesized by the present method, was also achieved. H-B(dan) serves as a B(dan) electrophile to give directly R-B(dan) by the reaction with Grignard reagents under transition metal-free conditions.
doi_str_mv	10.1039/d0cc02560g
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subjects	Boron Cross coupling Naphthalene Reagents Transition metals
title	Transition metal-free B(dan)-installing reaction (dan: naphthalene-1,8-diaminato): H-B(dan) as a B(dan) electrophile
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