Turnover of a Methane Oxidation Tricopper Cluster Catalyst: Implications for the Mechanism of the Particulate Methane Monooxygenase (pMMO)

The CuICuICuI tricopper cluster complex is the only known catalyst capable of efficient methane oxidation near room temperature similar to the particulate methane monooxygenase (pMMO). Here, we compare the turnover of the CuICuICuI tricopper catalyst with the biochemistry of the functional pMMO. Ins...

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