Regenerable magnetic carbonized Calotropis gigantea fiber for hydrophobic-driven fast removal of perfluoroalkyl pollutants
Using Calotropis gigantea fiber (CGF) as the bio-template, the magnetic carbonized fiber (MC-CGF) was successfully prepared by anchoring Fe 3 O 4 onto CGF surface via pyrolysis, and well characterized by means of instrumental analysis. Subsequently, MC-CGF was used as the adsorbent to remove perfluo...
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| Veröffentlicht in: | Cellulose (London) 2020-07, Vol.27 (10), p.5893-5905 |
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| creator | Niu, Bihui Yang, Shuping Li, Yuting Zang, Kun Sun, Changduo Yu, Min Zhou, Lei Zheng, Yian |
| description | Using
Calotropis gigantea
fiber (CGF) as the bio-template, the magnetic carbonized fiber (MC-CGF) was successfully prepared by anchoring Fe
3
O
4
onto CGF surface via pyrolysis, and well characterized by means of instrumental analysis. Subsequently, MC-CGF was used as the adsorbent to remove perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) from water. The adsorption equilibrium of PFOA and PFOS on MC-CGF could be achieved within 1 h and 2 h, with maximum adsorption capacity of ~ 200 mg/g for them at pH 3.0. Coexisting ions (Na
+
, Mg
2+
, Fe
3+
) promoted the adsorption efficiency of MC-CGF to PFOA/PFOS, in particular for multivalent metal cations. During the adsorption process, hydrophobic interaction was principally involved, and was considered to be the driving force for fast removal of perfluoroalkyl pollutants. Such a hydrophobic-driven interaction was further evidenced using other perfluoroalkyl pollutants with different C–F chain length and functional groups as the models. Finally, MC-CGF was easily regenerated and recycled many times, demonstrating its potential for removing perfluoroalkyl pollutants from water in the future.
Graphic abstract |
| doi_str_mv | 10.1007/s10570-020-03192-9 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2409477302</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2409477302</sourcerecordid><originalsourceid>FETCH-LOGICAL-c356t-a6289c0f9dc5c56f6e4db0351bef2df08f89d970d83e3a099c35527f0597e00c3</originalsourceid><addsrcrecordid>eNp9kE1LAzEQhoMoWKt_wFPA8-ps0t1sjlL8goIgCt5CNjvZbk03a7IttL_eaAVvHoY5zPu8Aw8hlzlc5wDiJuZQCMiApeG5ZJk8IpO8ECyrKvZ-TCYgS5nOXJ6SsxhXACAFyydk_4It9hh07ZCuddvj2BlqdKh93-2xoXPt_Bj80EXadq3uR9TUdjUGan2gy12TbktfdyZrQrfFnlodRxpw7bfaUW_pgMG6jQ9eu4-do4N3bjOmnnhOTqx2ES9-95S83d-9zh-zxfPD0_x2kRlelGOmS1ZJA1Y2pjBFaUucNTXwIq_RssZCZSvZSAFNxZFrkDJhBRMWCikQwPApuTr0DsF_bjCOauU3oU8vFZuBnAnBk5gpYYeUCT7GgFYNoVvrsFM5qG_H6uBYJcfqx7GSCeIHKKZw32L4q_6H-gK4W4JZ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2409477302</pqid></control><display><type>article</type><title>Regenerable magnetic carbonized Calotropis gigantea fiber for hydrophobic-driven fast removal of perfluoroalkyl pollutants</title><source>SpringerLink Journals - AutoHoldings</source><creator>Niu, Bihui ; Yang, Shuping ; Li, Yuting ; Zang, Kun ; Sun, Changduo ; Yu, Min ; Zhou, Lei ; Zheng, Yian</creator><creatorcontrib>Niu, Bihui ; Yang, Shuping ; Li, Yuting ; Zang, Kun ; Sun, Changduo ; Yu, Min ; Zhou, Lei ; Zheng, Yian</creatorcontrib><description>Using
Calotropis gigantea
fiber (CGF) as the bio-template, the magnetic carbonized fiber (MC-CGF) was successfully prepared by anchoring Fe
3
O
4
onto CGF surface via pyrolysis, and well characterized by means of instrumental analysis. Subsequently, MC-CGF was used as the adsorbent to remove perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) from water. The adsorption equilibrium of PFOA and PFOS on MC-CGF could be achieved within 1 h and 2 h, with maximum adsorption capacity of ~ 200 mg/g for them at pH 3.0. Coexisting ions (Na
+
, Mg
2+
, Fe
3+
) promoted the adsorption efficiency of MC-CGF to PFOA/PFOS, in particular for multivalent metal cations. During the adsorption process, hydrophobic interaction was principally involved, and was considered to be the driving force for fast removal of perfluoroalkyl pollutants. Such a hydrophobic-driven interaction was further evidenced using other perfluoroalkyl pollutants with different C–F chain length and functional groups as the models. Finally, MC-CGF was easily regenerated and recycled many times, demonstrating its potential for removing perfluoroalkyl pollutants from water in the future.
Graphic abstract</description><identifier>ISSN: 0969-0239</identifier><identifier>EISSN: 1572-882X</identifier><identifier>DOI: 10.1007/s10570-020-03192-9</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Adsorption ; Anchoring ; Bioorganic Chemistry ; Ceramics ; Chemistry ; Chemistry and Materials Science ; Composites ; Functional groups ; Glass ; Hydrophobicity ; Iron oxides ; Natural Materials ; Organic Chemistry ; Original Research ; Perfluoro compounds ; Perfluoroalkyl & polyfluoroalkyl substances ; Physical Chemistry ; Pollutants ; Polymer Sciences ; Pyrolysis ; Sustainable Development</subject><ispartof>Cellulose (London), 2020-07, Vol.27 (10), p.5893-5905</ispartof><rights>Springer Nature B.V. 2020</rights><rights>Springer Nature B.V. 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-a6289c0f9dc5c56f6e4db0351bef2df08f89d970d83e3a099c35527f0597e00c3</citedby><cites>FETCH-LOGICAL-c356t-a6289c0f9dc5c56f6e4db0351bef2df08f89d970d83e3a099c35527f0597e00c3</cites><orcidid>0000-0001-7783-9929</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10570-020-03192-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10570-020-03192-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Niu, Bihui</creatorcontrib><creatorcontrib>Yang, Shuping</creatorcontrib><creatorcontrib>Li, Yuting</creatorcontrib><creatorcontrib>Zang, Kun</creatorcontrib><creatorcontrib>Sun, Changduo</creatorcontrib><creatorcontrib>Yu, Min</creatorcontrib><creatorcontrib>Zhou, Lei</creatorcontrib><creatorcontrib>Zheng, Yian</creatorcontrib><title>Regenerable magnetic carbonized Calotropis gigantea fiber for hydrophobic-driven fast removal of perfluoroalkyl pollutants</title><title>Cellulose (London)</title><addtitle>Cellulose</addtitle><description>Using
Calotropis gigantea
fiber (CGF) as the bio-template, the magnetic carbonized fiber (MC-CGF) was successfully prepared by anchoring Fe
3
O
4
onto CGF surface via pyrolysis, and well characterized by means of instrumental analysis. Subsequently, MC-CGF was used as the adsorbent to remove perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) from water. The adsorption equilibrium of PFOA and PFOS on MC-CGF could be achieved within 1 h and 2 h, with maximum adsorption capacity of ~ 200 mg/g for them at pH 3.0. Coexisting ions (Na
+
, Mg
2+
, Fe
3+
) promoted the adsorption efficiency of MC-CGF to PFOA/PFOS, in particular for multivalent metal cations. During the adsorption process, hydrophobic interaction was principally involved, and was considered to be the driving force for fast removal of perfluoroalkyl pollutants. Such a hydrophobic-driven interaction was further evidenced using other perfluoroalkyl pollutants with different C–F chain length and functional groups as the models. Finally, MC-CGF was easily regenerated and recycled many times, demonstrating its potential for removing perfluoroalkyl pollutants from water in the future.
Graphic abstract</description><subject>Adsorption</subject><subject>Anchoring</subject><subject>Bioorganic Chemistry</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Functional groups</subject><subject>Glass</subject><subject>Hydrophobicity</subject><subject>Iron oxides</subject><subject>Natural Materials</subject><subject>Organic Chemistry</subject><subject>Original Research</subject><subject>Perfluoro compounds</subject><subject>Perfluoroalkyl & polyfluoroalkyl substances</subject><subject>Physical Chemistry</subject><subject>Pollutants</subject><subject>Polymer Sciences</subject><subject>Pyrolysis</subject><subject>Sustainable Development</subject><issn>0969-0239</issn><issn>1572-882X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kE1LAzEQhoMoWKt_wFPA8-ps0t1sjlL8goIgCt5CNjvZbk03a7IttL_eaAVvHoY5zPu8Aw8hlzlc5wDiJuZQCMiApeG5ZJk8IpO8ECyrKvZ-TCYgS5nOXJ6SsxhXACAFyydk_4It9hh07ZCuddvj2BlqdKh93-2xoXPt_Bj80EXadq3uR9TUdjUGan2gy12TbktfdyZrQrfFnlodRxpw7bfaUW_pgMG6jQ9eu4-do4N3bjOmnnhOTqx2ES9-95S83d-9zh-zxfPD0_x2kRlelGOmS1ZJA1Y2pjBFaUucNTXwIq_RssZCZSvZSAFNxZFrkDJhBRMWCikQwPApuTr0DsF_bjCOauU3oU8vFZuBnAnBk5gpYYeUCT7GgFYNoVvrsFM5qG_H6uBYJcfqx7GSCeIHKKZw32L4q_6H-gK4W4JZ</recordid><startdate>20200701</startdate><enddate>20200701</enddate><creator>Niu, Bihui</creator><creator>Yang, Shuping</creator><creator>Li, Yuting</creator><creator>Zang, Kun</creator><creator>Sun, Changduo</creator><creator>Yu, Min</creator><creator>Zhou, Lei</creator><creator>Zheng, Yian</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0001-7783-9929</orcidid></search><sort><creationdate>20200701</creationdate><title>Regenerable magnetic carbonized Calotropis gigantea fiber for hydrophobic-driven fast removal of perfluoroalkyl pollutants</title><author>Niu, Bihui ; Yang, Shuping ; Li, Yuting ; Zang, Kun ; Sun, Changduo ; Yu, Min ; Zhou, Lei ; Zheng, Yian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-a6289c0f9dc5c56f6e4db0351bef2df08f89d970d83e3a099c35527f0597e00c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Adsorption</topic><topic>Anchoring</topic><topic>Bioorganic Chemistry</topic><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composites</topic><topic>Functional groups</topic><topic>Glass</topic><topic>Hydrophobicity</topic><topic>Iron oxides</topic><topic>Natural Materials</topic><topic>Organic Chemistry</topic><topic>Original Research</topic><topic>Perfluoro compounds</topic><topic>Perfluoroalkyl & polyfluoroalkyl substances</topic><topic>Physical Chemistry</topic><topic>Pollutants</topic><topic>Polymer Sciences</topic><topic>Pyrolysis</topic><topic>Sustainable Development</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Niu, Bihui</creatorcontrib><creatorcontrib>Yang, Shuping</creatorcontrib><creatorcontrib>Li, Yuting</creatorcontrib><creatorcontrib>Zang, Kun</creatorcontrib><creatorcontrib>Sun, Changduo</creatorcontrib><creatorcontrib>Yu, Min</creatorcontrib><creatorcontrib>Zhou, Lei</creatorcontrib><creatorcontrib>Zheng, Yian</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Cellulose (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Niu, Bihui</au><au>Yang, Shuping</au><au>Li, Yuting</au><au>Zang, Kun</au><au>Sun, Changduo</au><au>Yu, Min</au><au>Zhou, Lei</au><au>Zheng, Yian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Regenerable magnetic carbonized Calotropis gigantea fiber for hydrophobic-driven fast removal of perfluoroalkyl pollutants</atitle><jtitle>Cellulose (London)</jtitle><stitle>Cellulose</stitle><date>2020-07-01</date><risdate>2020</risdate><volume>27</volume><issue>10</issue><spage>5893</spage><epage>5905</epage><pages>5893-5905</pages><issn>0969-0239</issn><eissn>1572-882X</eissn><abstract>Using
Calotropis gigantea
fiber (CGF) as the bio-template, the magnetic carbonized fiber (MC-CGF) was successfully prepared by anchoring Fe
3
O
4
onto CGF surface via pyrolysis, and well characterized by means of instrumental analysis. Subsequently, MC-CGF was used as the adsorbent to remove perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) from water. The adsorption equilibrium of PFOA and PFOS on MC-CGF could be achieved within 1 h and 2 h, with maximum adsorption capacity of ~ 200 mg/g for them at pH 3.0. Coexisting ions (Na
+
, Mg
2+
, Fe
3+
) promoted the adsorption efficiency of MC-CGF to PFOA/PFOS, in particular for multivalent metal cations. During the adsorption process, hydrophobic interaction was principally involved, and was considered to be the driving force for fast removal of perfluoroalkyl pollutants. Such a hydrophobic-driven interaction was further evidenced using other perfluoroalkyl pollutants with different C–F chain length and functional groups as the models. Finally, MC-CGF was easily regenerated and recycled many times, demonstrating its potential for removing perfluoroalkyl pollutants from water in the future.
Graphic abstract</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10570-020-03192-9</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0001-7783-9929</orcidid></addata></record> |
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| subjects | Adsorption Anchoring Bioorganic Chemistry Ceramics Chemistry Chemistry and Materials Science Composites Functional groups Glass Hydrophobicity Iron oxides Natural Materials Organic Chemistry Original Research Perfluoro compounds Perfluoroalkyl & polyfluoroalkyl substances Physical Chemistry Pollutants Polymer Sciences Pyrolysis Sustainable Development |
| title | Regenerable magnetic carbonized Calotropis gigantea fiber for hydrophobic-driven fast removal of perfluoroalkyl pollutants |
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