FTIR, UV–Vis–NIR spectroscopy, and gamma rays shielding competence of novel ZnO-doped vanadium borophosphate glasses
Structural, optical, and gamma radiation safety properties of 46V 2 O 5 ·46P 2 O 5 ·(8– x )B 2 O 3 · x ZnO ( x = 0,2,4,6, and 8 mol%) abbreviated as VPB/Zn glasses were investigated. The structure of the synthesized glasses has been examined via FTIR spectra within the range of 400–1500 cm −1 at ro...
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| Veröffentlicht in: | Journal of materials science. Materials in electronics 2020-06, Vol.31 (12), p.9099-9113 |
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| creator | Rammah, Y. S. El-Agawany, F. I. Mahmoud, K. A. El-Mallawany, R. Ilik, Erkan Kilic, Gokhan |
| description | Structural, optical, and gamma radiation safety properties of 46V
2
O
5
·46P
2
O
5
·(8–
x
)B
2
O
3
·
x
ZnO (
x
= 0,2,4,6, and 8 mol%) abbreviated as VPB/Zn glasses were investigated. The structure of the synthesized glasses has been examined via FTIR spectra within the range of 400–1500 cm
−1
at room temperature. UV–Vis–NIR measurements of the proposed glasses were performed within the range of 200–3300 nm. The optical characteristics such as optical energy bandgap (
E
Optical
), refractive index (
n
Linear
), and Urbach’s energy (
E
U
) have been determined. In addition, the mass attenuation coefficients (MAC) for VPB/Zn glasses were performed utilizing MCNP-5 simulation code and XCOM program for various gamma ray energy varied in range 0.015–15 MeV. Based on MAC values, the equivalent atomic number (
Z
eq
) and buildup factors (EABF and EBF) were evaluated. Results reveal that the direct
E
Optical
Tauc
′
s
of the VPB/Zn glasses ranged from 0.688 to 0.710 eV, while from 0.560 to 0.647 eV for the indirect transition. The admission of the ZnO improves the MAC of the VPB/Zn glasses. Thus, one can conclude that the proposed glasses can be applied for optical devices as semiconductor glasses and considered as good materials for γ-rays shielding. |
| doi_str_mv | 10.1007/s10854-020-03440-5 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2409109711</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2409109711</sourcerecordid><originalsourceid>FETCH-LOGICAL-c319t-8bced9b44c7c328071f26b8ba9bc0663a5264860b0e028a52327ad2881b2f1c03</originalsourceid><addsrcrecordid>eNp9kM1Kw0AUhQdRsFZfwNWA247e-UkyWUqxWigWpC3iZphMJm1Kk4kzabE738E39EmMVnDn5l4unHMu50PoksI1BUhuAgUZCQIMCHAhgERHqEejhBMh2fMx6kEaJUREjJ2isxDWABALLnvobTQbPw3wfPH5_rEoQzcfx084NNa03gXjmv0A6zrHS11VGnu9DzisSrvJy3qJjasa29raWOwKXLud3eCXekpy19gc73St83Jb4cx516xcaFa6tXi50SHYcI5OCr0J9uJ399F8dDcbPpDJ9H48vJ0Qw2naEpkZm6eZECYxnElIaMHiTGY6zQzEMdcRi4WMIQMLTHYXZ4nOmZQ0YwU1wPvo6pDbePe6taFVa7f1dfdSMQEphTShtFOxg8p0rYO3hWp8WWm_VxTUN2F1IKw6wuqHsIo6Ez-YQieul9b_Rf_j-gK6HoCQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2409109711</pqid></control><display><type>article</type><title>FTIR, UV–Vis–NIR spectroscopy, and gamma rays shielding competence of novel ZnO-doped vanadium borophosphate glasses</title><source>Springer Nature - Complete Springer Journals</source><creator>Rammah, Y. S. ; El-Agawany, F. I. ; Mahmoud, K. A. ; El-Mallawany, R. ; Ilik, Erkan ; Kilic, Gokhan</creator><creatorcontrib>Rammah, Y. S. ; El-Agawany, F. I. ; Mahmoud, K. A. ; El-Mallawany, R. ; Ilik, Erkan ; Kilic, Gokhan</creatorcontrib><description>Structural, optical, and gamma radiation safety properties of 46V
2
O
5
·46P
2
O
5
·(8–
x
)B
2
O
3
·
x
ZnO (
x
= 0,2,4,6, and 8 mol%) abbreviated as VPB/Zn glasses were investigated. The structure of the synthesized glasses has been examined via FTIR spectra within the range of 400–1500 cm
−1
at room temperature. UV–Vis–NIR measurements of the proposed glasses were performed within the range of 200–3300 nm. The optical characteristics such as optical energy bandgap (
E
Optical
), refractive index (
n
Linear
), and Urbach’s energy (
E
U
) have been determined. In addition, the mass attenuation coefficients (MAC) for VPB/Zn glasses were performed utilizing MCNP-5 simulation code and XCOM program for various gamma ray energy varied in range 0.015–15 MeV. Based on MAC values, the equivalent atomic number (
Z
eq
) and buildup factors (EABF and EBF) were evaluated. Results reveal that the direct
E
Optical
Tauc
′
s
of the VPB/Zn glasses ranged from 0.688 to 0.710 eV, while from 0.560 to 0.647 eV for the indirect transition. The admission of the ZnO improves the MAC of the VPB/Zn glasses. Thus, one can conclude that the proposed glasses can be applied for optical devices as semiconductor glasses and considered as good materials for γ-rays shielding.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-020-03440-5</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Atomic properties ; Attenuation coefficients ; Boron oxides ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Fourier transforms ; Gamma rays ; Infrared spectroscopy ; Materials Science ; Optical and Electronic Materials ; Optical properties ; Radiation shielding ; Refractivity ; Room temperature ; Spectrum analysis ; Zinc oxide</subject><ispartof>Journal of materials science. Materials in electronics, 2020-06, Vol.31 (12), p.9099-9113</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2020</rights><rights>Springer Science+Business Media, LLC, part of Springer Nature 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-8bced9b44c7c328071f26b8ba9bc0663a5264860b0e028a52327ad2881b2f1c03</citedby><cites>FETCH-LOGICAL-c319t-8bced9b44c7c328071f26b8ba9bc0663a5264860b0e028a52327ad2881b2f1c03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10854-020-03440-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10854-020-03440-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Rammah, Y. S.</creatorcontrib><creatorcontrib>El-Agawany, F. I.</creatorcontrib><creatorcontrib>Mahmoud, K. A.</creatorcontrib><creatorcontrib>El-Mallawany, R.</creatorcontrib><creatorcontrib>Ilik, Erkan</creatorcontrib><creatorcontrib>Kilic, Gokhan</creatorcontrib><title>FTIR, UV–Vis–NIR spectroscopy, and gamma rays shielding competence of novel ZnO-doped vanadium borophosphate glasses</title><title>Journal of materials science. Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><description>Structural, optical, and gamma radiation safety properties of 46V
2
O
5
·46P
2
O
5
·(8–
x
)B
2
O
3
·
x
ZnO (
x
= 0,2,4,6, and 8 mol%) abbreviated as VPB/Zn glasses were investigated. The structure of the synthesized glasses has been examined via FTIR spectra within the range of 400–1500 cm
−1
at room temperature. UV–Vis–NIR measurements of the proposed glasses were performed within the range of 200–3300 nm. The optical characteristics such as optical energy bandgap (
E
Optical
), refractive index (
n
Linear
), and Urbach’s energy (
E
U
) have been determined. In addition, the mass attenuation coefficients (MAC) for VPB/Zn glasses were performed utilizing MCNP-5 simulation code and XCOM program for various gamma ray energy varied in range 0.015–15 MeV. Based on MAC values, the equivalent atomic number (
Z
eq
) and buildup factors (EABF and EBF) were evaluated. Results reveal that the direct
E
Optical
Tauc
′
s
of the VPB/Zn glasses ranged from 0.688 to 0.710 eV, while from 0.560 to 0.647 eV for the indirect transition. The admission of the ZnO improves the MAC of the VPB/Zn glasses. Thus, one can conclude that the proposed glasses can be applied for optical devices as semiconductor glasses and considered as good materials for γ-rays shielding.</description><subject>Atomic properties</subject><subject>Attenuation coefficients</subject><subject>Boron oxides</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Fourier transforms</subject><subject>Gamma rays</subject><subject>Infrared spectroscopy</subject><subject>Materials Science</subject><subject>Optical and Electronic Materials</subject><subject>Optical properties</subject><subject>Radiation shielding</subject><subject>Refractivity</subject><subject>Room temperature</subject><subject>Spectrum analysis</subject><subject>Zinc oxide</subject><issn>0957-4522</issn><issn>1573-482X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kM1Kw0AUhQdRsFZfwNWA247e-UkyWUqxWigWpC3iZphMJm1Kk4kzabE738E39EmMVnDn5l4unHMu50PoksI1BUhuAgUZCQIMCHAhgERHqEejhBMh2fMx6kEaJUREjJ2isxDWABALLnvobTQbPw3wfPH5_rEoQzcfx084NNa03gXjmv0A6zrHS11VGnu9DzisSrvJy3qJjasa29raWOwKXLud3eCXekpy19gc73St83Jb4cx516xcaFa6tXi50SHYcI5OCr0J9uJ399F8dDcbPpDJ9H48vJ0Qw2naEpkZm6eZECYxnElIaMHiTGY6zQzEMdcRi4WMIQMLTHYXZ4nOmZQ0YwU1wPvo6pDbePe6taFVa7f1dfdSMQEphTShtFOxg8p0rYO3hWp8WWm_VxTUN2F1IKw6wuqHsIo6Ez-YQieul9b_Rf_j-gK6HoCQ</recordid><startdate>20200601</startdate><enddate>20200601</enddate><creator>Rammah, Y. S.</creator><creator>El-Agawany, F. I.</creator><creator>Mahmoud, K. A.</creator><creator>El-Mallawany, R.</creator><creator>Ilik, Erkan</creator><creator>Kilic, Gokhan</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F28</scope><scope>FR3</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>L7M</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>S0W</scope></search><sort><creationdate>20200601</creationdate><title>FTIR, UV–Vis–NIR spectroscopy, and gamma rays shielding competence of novel ZnO-doped vanadium borophosphate glasses</title><author>Rammah, Y. S. ; El-Agawany, F. I. ; Mahmoud, K. A. ; El-Mallawany, R. ; Ilik, Erkan ; Kilic, Gokhan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-8bced9b44c7c328071f26b8ba9bc0663a5264860b0e028a52327ad2881b2f1c03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Atomic properties</topic><topic>Attenuation coefficients</topic><topic>Boron oxides</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Fourier transforms</topic><topic>Gamma rays</topic><topic>Infrared spectroscopy</topic><topic>Materials Science</topic><topic>Optical and Electronic Materials</topic><topic>Optical properties</topic><topic>Radiation shielding</topic><topic>Refractivity</topic><topic>Room temperature</topic><topic>Spectrum analysis</topic><topic>Zinc oxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rammah, Y. S.</creatorcontrib><creatorcontrib>El-Agawany, F. I.</creatorcontrib><creatorcontrib>Mahmoud, K. A.</creatorcontrib><creatorcontrib>El-Mallawany, R.</creatorcontrib><creatorcontrib>Ilik, Erkan</creatorcontrib><creatorcontrib>Kilic, Gokhan</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>DELNET Engineering & Technology Collection</collection><jtitle>Journal of materials science. Materials in electronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rammah, Y. S.</au><au>El-Agawany, F. I.</au><au>Mahmoud, K. A.</au><au>El-Mallawany, R.</au><au>Ilik, Erkan</au><au>Kilic, Gokhan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>FTIR, UV–Vis–NIR spectroscopy, and gamma rays shielding competence of novel ZnO-doped vanadium borophosphate glasses</atitle><jtitle>Journal of materials science. Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><date>2020-06-01</date><risdate>2020</risdate><volume>31</volume><issue>12</issue><spage>9099</spage><epage>9113</epage><pages>9099-9113</pages><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>Structural, optical, and gamma radiation safety properties of 46V
2
O
5
·46P
2
O
5
·(8–
x
)B
2
O
3
·
x
ZnO (
x
= 0,2,4,6, and 8 mol%) abbreviated as VPB/Zn glasses were investigated. The structure of the synthesized glasses has been examined via FTIR spectra within the range of 400–1500 cm
−1
at room temperature. UV–Vis–NIR measurements of the proposed glasses were performed within the range of 200–3300 nm. The optical characteristics such as optical energy bandgap (
E
Optical
), refractive index (
n
Linear
), and Urbach’s energy (
E
U
) have been determined. In addition, the mass attenuation coefficients (MAC) for VPB/Zn glasses were performed utilizing MCNP-5 simulation code and XCOM program for various gamma ray energy varied in range 0.015–15 MeV. Based on MAC values, the equivalent atomic number (
Z
eq
) and buildup factors (EABF and EBF) were evaluated. Results reveal that the direct
E
Optical
Tauc
′
s
of the VPB/Zn glasses ranged from 0.688 to 0.710 eV, while from 0.560 to 0.647 eV for the indirect transition. The admission of the ZnO improves the MAC of the VPB/Zn glasses. Thus, one can conclude that the proposed glasses can be applied for optical devices as semiconductor glasses and considered as good materials for γ-rays shielding.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10854-020-03440-5</doi><tpages>15</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0957-4522 |
| ispartof | Journal of materials science. Materials in electronics, 2020-06, Vol.31 (12), p.9099-9113 |
| issn | 0957-4522 1573-482X |
| language | eng |
| recordid | cdi_proquest_journals_2409109711 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Atomic properties Attenuation coefficients Boron oxides Characterization and Evaluation of Materials Chemistry and Materials Science Fourier transforms Gamma rays Infrared spectroscopy Materials Science Optical and Electronic Materials Optical properties Radiation shielding Refractivity Room temperature Spectrum analysis Zinc oxide |
| title | FTIR, UV–Vis–NIR spectroscopy, and gamma rays shielding competence of novel ZnO-doped vanadium borophosphate glasses |
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