Identification of Pesticide Residues and Prediction of Their Fate in Agricultural Soil
Fourteen pesticides were screened and determined through quick, easy, cheap, effective, rugged, and safe (QuEChERS) extraction process combined with GC-MS/MS in arid agriculture soil. The aims of the current investigation were to account the occurrence of organochlorine (OCP) and organophosphates (O...
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| description | Fourteen pesticides were screened and determined through quick, easy, cheap, effective, rugged, and safe (QuEChERS) extraction process combined with GC-MS/MS in arid agriculture soil. The aims of the current investigation were to account the occurrence of organochlorine (OCP) and organophosphates (OPP) pesticide residues as well as other groups of pyrethroids (PYRs), carbamates, and biopesticides using a combined of QuEChERS and GC-MS/MS techniques in agriculture soils at Al-Kharj region, Saudi Arabia, and to investigate correlation between pesticide losses in soils and some physicochemical characteristics of pesticides including an octanol-water coefficient partition (
K
ow
) and the vapor pressure (
V
p). Prediction of pesticide fate by considering both pesticide and soil physio-chemical properties will facilitate the management of pesticide application and minimize the hazards of environmental pollution. The fate of pesticide residue in soils is generally controlled by soil/air exchange, water interaction, and biodegradation. The results indicated that 14 pesticide residues were measured in collected samples of various soils, spinosad, chlorpyrifos methyl, dimethoate, chlorpyrifos, lindane (γ-HCH), permethrin, and methomyl which were the most abundant sources of contamination in the studied region. p,p-DDT, o,p-DDT, bifenthion, β-cyfluthrin, and methidathion were less commonly detected. Single parameter least squares regression equations (sp-LSRE) for
V
p and
K
ow
against the loss of each pesticide residue showed a significant change in concentration levels (
p
|
| doi_str_mv | 10.1007/s11270-020-04619-6 |
| format | Article |
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K
ow
) and the vapor pressure (
V
p). Prediction of pesticide fate by considering both pesticide and soil physio-chemical properties will facilitate the management of pesticide application and minimize the hazards of environmental pollution. The fate of pesticide residue in soils is generally controlled by soil/air exchange, water interaction, and biodegradation. The results indicated that 14 pesticide residues were measured in collected samples of various soils, spinosad, chlorpyrifos methyl, dimethoate, chlorpyrifos, lindane (γ-HCH), permethrin, and methomyl which were the most abundant sources of contamination in the studied region. p,p-DDT, o,p-DDT, bifenthion, β-cyfluthrin, and methidathion were less commonly detected. Single parameter least squares regression equations (sp-LSRE) for
V
p and
K
ow
against the loss of each pesticide residue showed a significant change in concentration levels (
p
< 0.05) between the two seasons. The results showed that vapor pressure and octanol-water partition coefficient data are not enough to model pesticide residue losses in arid low organic carbon soil. More soil-related data is needed to describe the dissipation mechanisms of these pesticide residues in the region.</description><identifier>ISSN: 0049-6979</identifier><identifier>EISSN: 1573-2932</identifier><identifier>DOI: 10.1007/s11270-020-04619-6</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Agricultural land ; Agricultural management ; Agriculture ; Agrochemicals ; Analysis ; Aridity ; Atmospheric Protection/Air Quality Control/Air Pollution ; Biodegradation ; Carbamate pesticides ; Carbamates ; Carbamates (tradename) ; Carbon content ; Chemical properties ; Chemicophysical properties ; Chlorine compounds ; Chlorpyrifos ; Climate Change/Climate Change Impacts ; Contamination ; DDT ; Dimethoate ; Earth and Environmental Science ; Environment ; Environmental monitoring ; Hexachlorocyclohexane ; Hydrogeology ; Insecticides ; Lindane ; Methidathion ; Octanol-water partition coefficients ; Organic carbon ; Organic compounds ; Organic soils ; Organochlorine compounds ; Organochlorine pesticides ; Organophosphates ; Permethrin ; Pesticide application ; Pesticide residues ; Pesticides ; Pollution sources ; Pyrethroids ; Residues ; Soil ; Soil chemistry ; Soil contamination ; Soil investigations ; Soil pollution ; Soil properties ; Soil Science & Conservation ; Soil water ; Soils ; Spinosad ; Vapor pressure ; Vapors ; Vapour pressure ; Water pollution ; Water Quality/Water Pollution</subject><ispartof>Water, air, and soil pollution, 2020-06, Vol.231 (6), Article 284</ispartof><rights>Springer Nature Switzerland AG 2020</rights><rights>COPYRIGHT 2020 Springer</rights><rights>Springer Nature Switzerland AG 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a409t-b318e3b1daf89a98375fd18f687e72854bd689c1f1630ceb15102ba5379d77c13</citedby><cites>FETCH-LOGICAL-a409t-b318e3b1daf89a98375fd18f687e72854bd689c1f1630ceb15102ba5379d77c13</cites><orcidid>0000-0001-9341-711X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11270-020-04619-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11270-020-04619-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27922,27923,41486,42555,51317</link.rule.ids></links><search><creatorcontrib>EL-Saeid, Mohamed H.</creatorcontrib><creatorcontrib>Alghamdi, Abdulaziz G.</creatorcontrib><title>Identification of Pesticide Residues and Prediction of Their Fate in Agricultural Soil</title><title>Water, air, and soil pollution</title><addtitle>Water Air Soil Pollut</addtitle><description>Fourteen pesticides were screened and determined through quick, easy, cheap, effective, rugged, and safe (QuEChERS) extraction process combined with GC-MS/MS in arid agriculture soil. The aims of the current investigation were to account the occurrence of organochlorine (OCP) and organophosphates (OPP) pesticide residues as well as other groups of pyrethroids (PYRs), carbamates, and biopesticides using a combined of QuEChERS and GC-MS/MS techniques in agriculture soils at Al-Kharj region, Saudi Arabia, and to investigate correlation between pesticide losses in soils and some physicochemical characteristics of pesticides including an octanol-water coefficient partition (
K
ow
) and the vapor pressure (
V
p). Prediction of pesticide fate by considering both pesticide and soil physio-chemical properties will facilitate the management of pesticide application and minimize the hazards of environmental pollution. The fate of pesticide residue in soils is generally controlled by soil/air exchange, water interaction, and biodegradation. The results indicated that 14 pesticide residues were measured in collected samples of various soils, spinosad, chlorpyrifos methyl, dimethoate, chlorpyrifos, lindane (γ-HCH), permethrin, and methomyl which were the most abundant sources of contamination in the studied region. p,p-DDT, o,p-DDT, bifenthion, β-cyfluthrin, and methidathion were less commonly detected. Single parameter least squares regression equations (sp-LSRE) for
V
p and
K
ow
against the loss of each pesticide residue showed a significant change in concentration levels (
p
< 0.05) between the two seasons. The results showed that vapor pressure and octanol-water partition coefficient data are not enough to model pesticide residue losses in arid low organic carbon soil. More soil-related data is needed to describe the dissipation mechanisms of these pesticide residues in the region.</description><subject>Agricultural land</subject><subject>Agricultural management</subject><subject>Agriculture</subject><subject>Agrochemicals</subject><subject>Analysis</subject><subject>Aridity</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Biodegradation</subject><subject>Carbamate pesticides</subject><subject>Carbamates</subject><subject>Carbamates (tradename)</subject><subject>Carbon content</subject><subject>Chemical properties</subject><subject>Chemicophysical properties</subject><subject>Chlorine compounds</subject><subject>Chlorpyrifos</subject><subject>Climate Change/Climate Change Impacts</subject><subject>Contamination</subject><subject>DDT</subject><subject>Dimethoate</subject><subject>Earth and Environmental Science</subject><subject>Environment</subject><subject>Environmental monitoring</subject><subject>Hexachlorocyclohexane</subject><subject>Hydrogeology</subject><subject>Insecticides</subject><subject>Lindane</subject><subject>Methidathion</subject><subject>Octanol-water partition coefficients</subject><subject>Organic carbon</subject><subject>Organic compounds</subject><subject>Organic soils</subject><subject>Organochlorine compounds</subject><subject>Organochlorine pesticides</subject><subject>Organophosphates</subject><subject>Permethrin</subject><subject>Pesticide application</subject><subject>Pesticide residues</subject><subject>Pesticides</subject><subject>Pollution sources</subject><subject>Pyrethroids</subject><subject>Residues</subject><subject>Soil</subject><subject>Soil chemistry</subject><subject>Soil contamination</subject><subject>Soil investigations</subject><subject>Soil pollution</subject><subject>Soil properties</subject><subject>Soil Science & Conservation</subject><subject>Soil water</subject><subject>Soils</subject><subject>Spinosad</subject><subject>Vapor pressure</subject><subject>Vapors</subject><subject>Vapour pressure</subject><subject>Water pollution</subject><subject>Water Quality/Water 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of Pesticide Residues and Prediction of Their Fate in Agricultural Soil</title><author>EL-Saeid, Mohamed H. ; Alghamdi, Abdulaziz G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a409t-b318e3b1daf89a98375fd18f687e72854bd689c1f1630ceb15102ba5379d77c13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Agricultural land</topic><topic>Agricultural management</topic><topic>Agriculture</topic><topic>Agrochemicals</topic><topic>Analysis</topic><topic>Aridity</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Biodegradation</topic><topic>Carbamate pesticides</topic><topic>Carbamates</topic><topic>Carbamates (tradename)</topic><topic>Carbon content</topic><topic>Chemical properties</topic><topic>Chemicophysical properties</topic><topic>Chlorine compounds</topic><topic>Chlorpyrifos</topic><topic>Climate Change/Climate Change Impacts</topic><topic>Contamination</topic><topic>DDT</topic><topic>Dimethoate</topic><topic>Earth and Environmental Science</topic><topic>Environment</topic><topic>Environmental monitoring</topic><topic>Hexachlorocyclohexane</topic><topic>Hydrogeology</topic><topic>Insecticides</topic><topic>Lindane</topic><topic>Methidathion</topic><topic>Octanol-water partition coefficients</topic><topic>Organic carbon</topic><topic>Organic compounds</topic><topic>Organic soils</topic><topic>Organochlorine compounds</topic><topic>Organochlorine pesticides</topic><topic>Organophosphates</topic><topic>Permethrin</topic><topic>Pesticide application</topic><topic>Pesticide residues</topic><topic>Pesticides</topic><topic>Pollution sources</topic><topic>Pyrethroids</topic><topic>Residues</topic><topic>Soil</topic><topic>Soil chemistry</topic><topic>Soil contamination</topic><topic>Soil investigations</topic><topic>Soil pollution</topic><topic>Soil properties</topic><topic>Soil Science & Conservation</topic><topic>Soil water</topic><topic>Soils</topic><topic>Spinosad</topic><topic>Vapor pressure</topic><topic>Vapors</topic><topic>Vapour pressure</topic><topic>Water pollution</topic><topic>Water Quality/Water Pollution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>EL-Saeid, Mohamed H.</creatorcontrib><creatorcontrib>Alghamdi, Abdulaziz G.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Aqualine</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Pollution Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Water Resources Abstracts</collection><collection>ABI/INFORM Collection</collection><collection>ABI/INFORM Global (PDF only)</collection><collection>Agricultural Science Collection</collection><collection>Health & Medical Collection</collection><collection>ProQuest 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Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><jtitle>Water, air, and soil pollution</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>EL-Saeid, Mohamed H.</au><au>Alghamdi, Abdulaziz G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Identification of Pesticide Residues and Prediction of Their Fate in Agricultural Soil</atitle><jtitle>Water, air, and soil pollution</jtitle><stitle>Water Air Soil Pollut</stitle><date>2020-06-01</date><risdate>2020</risdate><volume>231</volume><issue>6</issue><artnum>284</artnum><issn>0049-6979</issn><eissn>1573-2932</eissn><abstract>Fourteen pesticides were screened and determined through quick, easy, cheap, effective, rugged, and safe (QuEChERS) extraction process combined with GC-MS/MS in arid agriculture soil. The aims of the current investigation were to account the occurrence of organochlorine (OCP) and organophosphates (OPP) pesticide residues as well as other groups of pyrethroids (PYRs), carbamates, and biopesticides using a combined of QuEChERS and GC-MS/MS techniques in agriculture soils at Al-Kharj region, Saudi Arabia, and to investigate correlation between pesticide losses in soils and some physicochemical characteristics of pesticides including an octanol-water coefficient partition (
K
ow
) and the vapor pressure (
V
p). Prediction of pesticide fate by considering both pesticide and soil physio-chemical properties will facilitate the management of pesticide application and minimize the hazards of environmental pollution. The fate of pesticide residue in soils is generally controlled by soil/air exchange, water interaction, and biodegradation. The results indicated that 14 pesticide residues were measured in collected samples of various soils, spinosad, chlorpyrifos methyl, dimethoate, chlorpyrifos, lindane (γ-HCH), permethrin, and methomyl which were the most abundant sources of contamination in the studied region. p,p-DDT, o,p-DDT, bifenthion, β-cyfluthrin, and methidathion were less commonly detected. Single parameter least squares regression equations (sp-LSRE) for
V
p and
K
ow
against the loss of each pesticide residue showed a significant change in concentration levels (
p
< 0.05) between the two seasons. The results showed that vapor pressure and octanol-water partition coefficient data are not enough to model pesticide residue losses in arid low organic carbon soil. More soil-related data is needed to describe the dissipation mechanisms of these pesticide residues in the region.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s11270-020-04619-6</doi><orcidid>https://orcid.org/0000-0001-9341-711X</orcidid></addata></record> |
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| ispartof | Water, air, and soil pollution, 2020-06, Vol.231 (6), Article 284 |
| issn | 0049-6979 1573-2932 |
| language | eng |
| recordid | cdi_proquest_journals_2408732707 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Agricultural land Agricultural management Agriculture Agrochemicals Analysis Aridity Atmospheric Protection/Air Quality Control/Air Pollution Biodegradation Carbamate pesticides Carbamates Carbamates (tradename) Carbon content Chemical properties Chemicophysical properties Chlorine compounds Chlorpyrifos Climate Change/Climate Change Impacts Contamination DDT Dimethoate Earth and Environmental Science Environment Environmental monitoring Hexachlorocyclohexane Hydrogeology Insecticides Lindane Methidathion Octanol-water partition coefficients Organic carbon Organic compounds Organic soils Organochlorine compounds Organochlorine pesticides Organophosphates Permethrin Pesticide application Pesticide residues Pesticides Pollution sources Pyrethroids Residues Soil Soil chemistry Soil contamination Soil investigations Soil pollution Soil properties Soil Science & Conservation Soil water Soils Spinosad Vapor pressure Vapors Vapour pressure Water pollution Water Quality/Water Pollution |
| title | Identification of Pesticide Residues and Prediction of Their Fate in Agricultural Soil |
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