Thermodynamic properties, crystal structure and phase relations of pushcharovskite [Cu(AsO3OH) (H2O) center dot 0.5H(2)O], geminite [Cu(AsO3OH)(H2O)] and liroconite [Cu2Al(AsO4)(OH)(4) center dot 4H(2)O]

The phases pushcharovskite, geminite and liroconite were synthesized or acquired and characterized by powder X-ray diffraction, infrared spectroscopy, electron microprobe analysis, thermogravimetric analysis and optical emission spectrometry, as needed. Their thermodynamic properties were determined...

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Veröffentlicht in:	European journal of mineralogy (Stuttgart) 2020-05, Vol.32 (3), p.285-304
Hauptverfasser:	Plumhoff, Alexandra M., Plasil, Jakub, Dachs, Edgar, Benisek, Artur, Sejkora, Jiri, Stevko, Martin, Rumsey, Mike S., Majzlan, Juraj
Format:	Artikel
Sprache:	eng
Schlagworte:	Acidic water Arsenic Calorimetry Carbonates Computational fluid dynamics Copper Crystal structure Electron probe microanalysis Electron probes Emission analysis Gypsum Heat measurement Infrared analysis Infrared spectroscopy Laboratories Mineralization Mineralogy Minerals Optical emission spectroscopy Optical properties Oxidation Physical Sciences Precipitates Science & Technology Silica Silicon dioxide Single crystals Software Spectrometry Spectrum analysis Thermodynamic models Thermodynamic properties Thermogravimetric analysis X ray powder diffraction X-ray diffraction
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