Covalently Copper(II) Porphyrin Cross-Linked Graphene Oxide: Preparation and Catalytic Activity
In this study, copper(II)-coordinated 5,10,15,20-tetrakis(aminophenyl)porphyrin (CuPPh) as a macrocyclic copper complex was covalently linked to the surface of graphene oxide (GO–CuPPh). This covalently cross-linked catalyst was characterized with various analysis such as FT-IR, SEM, TEM, EDS, ICP,...
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| Veröffentlicht in: | Catalysis letters 2019-03, Vol.149 (3), p.713-722 |
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| creator | Khojastehnezhad, Amir Bakavoli, Mehdi Javid, Ali Khakzad Siuki, Mohammad Mehdi Moeinpour, Farid |
| description | In this study, copper(II)-coordinated 5,10,15,20-tetrakis(aminophenyl)porphyrin (CuPPh) as a macrocyclic copper complex was covalently linked to the surface of graphene oxide (GO–CuPPh). This covalently cross-linked catalyst was characterized with various analysis such as FT-IR, SEM, TEM, EDS, ICP, TGA and UV–Vis. All analysis confirm the successful covalently immobilization of CuPPh on the GO. Then, the activity of catalyst has been tested for the preparation of propargylamine derivatives by the reaction of different aldehydes/ketones various amines and phenylacetylene via A
3
and KA
2
coupling reactions. The catalytic system indicated great catalytic activity in this reaction and the yields of the products were good to marvelous. The results of this work are hoped to aid the establishment of new class of heterogeneous catalysts as the high performance and low-cost candidates for industrial applications.
Graphical Abstract |
| doi_str_mv | 10.1007/s10562-019-02665-2 |
| format | Article |
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3
and KA
2
coupling reactions. The catalytic system indicated great catalytic activity in this reaction and the yields of the products were good to marvelous. The results of this work are hoped to aid the establishment of new class of heterogeneous catalysts as the high performance and low-cost candidates for industrial applications.
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3
and KA
2
coupling reactions. The catalytic system indicated great catalytic activity in this reaction and the yields of the products were good to marvelous. The results of this work are hoped to aid the establishment of new class of heterogeneous catalysts as the high performance and low-cost candidates for industrial applications.
Graphical Abstract</description><subject>Aldehydes</subject><subject>Amines</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Chemical reactions</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination compounds</subject><subject>Copper</subject><subject>Copper (Metal)</subject><subject>Copper compounds</subject><subject>Covalence</subject><subject>Crosslinking</subject><subject>Graphene</subject><subject>Graphite</subject><subject>Industrial applications</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Industrial equipment</subject><subject>Infrared analysis</subject><subject>Ketones</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><subject>Porphyrins</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kM1q3DAURk1pIdOkL5CVoJt0oUS_ltXdYNpkYCBZtJCdkOXrjKYzkiMroX77KnGgu3BBV4jvXEmnqs4puaSEqKuJElkzTKjGhNW1xOxDtaJSMdwoff-x7AmlmCt2f1J9nqY9IUQrqleVaeOzPUDIhxm1cRwhXWw239BdTONuTj6gNsVpwlsf_kCPrpMddxAA3f71PXxHdwlGm2z2MSAbetTabA9z9g6tXfbPPs9n1afBHib48tZPq98_f_xqb_D29nrTrrfYcdlkDJ0WzinXEW4F14JS2jEqQTZNxzrGeQ-dGGoyCKFh4MoprbnUoqY9V11ZTquvy9wxxccnmLLZx6cUypWGCVIrLRqlSupyST2UPxsfhpiTdaV6OHoXAwy-nK-l4rq4YrIAbAHci4YEgxmTP9o0G0rMi3mzmDfFvHk1b1iB-AJNJRweIP1_yzvUP2Eohbg</recordid><startdate>20190301</startdate><enddate>20190301</enddate><creator>Khojastehnezhad, Amir</creator><creator>Bakavoli, Mehdi</creator><creator>Javid, Ali</creator><creator>Khakzad Siuki, Mohammad Mehdi</creator><creator>Moeinpour, Farid</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20190301</creationdate><title>Covalently Copper(II) Porphyrin Cross-Linked Graphene Oxide: Preparation and Catalytic Activity</title><author>Khojastehnezhad, Amir ; Bakavoli, Mehdi ; Javid, Ali ; Khakzad Siuki, Mohammad Mehdi ; Moeinpour, Farid</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c358t-eb94cc7cb03a4394111b215e588b2b233deb4f60f449ef37c799359461d37b1d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Aldehydes</topic><topic>Amines</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Chemical reactions</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination compounds</topic><topic>Copper</topic><topic>Copper (Metal)</topic><topic>Copper compounds</topic><topic>Covalence</topic><topic>Crosslinking</topic><topic>Graphene</topic><topic>Graphite</topic><topic>Industrial applications</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Industrial equipment</topic><topic>Infrared analysis</topic><topic>Ketones</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><topic>Porphyrins</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Khojastehnezhad, Amir</creatorcontrib><creatorcontrib>Bakavoli, Mehdi</creatorcontrib><creatorcontrib>Javid, Ali</creatorcontrib><creatorcontrib>Khakzad Siuki, Mohammad Mehdi</creatorcontrib><creatorcontrib>Moeinpour, Farid</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Khojastehnezhad, Amir</au><au>Bakavoli, Mehdi</au><au>Javid, Ali</au><au>Khakzad Siuki, Mohammad Mehdi</au><au>Moeinpour, Farid</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Covalently Copper(II) Porphyrin Cross-Linked Graphene Oxide: Preparation and Catalytic Activity</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2019-03-01</date><risdate>2019</risdate><volume>149</volume><issue>3</issue><spage>713</spage><epage>722</epage><pages>713-722</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>In this study, copper(II)-coordinated 5,10,15,20-tetrakis(aminophenyl)porphyrin (CuPPh) as a macrocyclic copper complex was covalently linked to the surface of graphene oxide (GO–CuPPh). This covalently cross-linked catalyst was characterized with various analysis such as FT-IR, SEM, TEM, EDS, ICP, TGA and UV–Vis. All analysis confirm the successful covalently immobilization of CuPPh on the GO. Then, the activity of catalyst has been tested for the preparation of propargylamine derivatives by the reaction of different aldehydes/ketones various amines and phenylacetylene via A
3
and KA
2
coupling reactions. The catalytic system indicated great catalytic activity in this reaction and the yields of the products were good to marvelous. The results of this work are hoped to aid the establishment of new class of heterogeneous catalysts as the high performance and low-cost candidates for industrial applications.
Graphical Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10562-019-02665-2</doi><tpages>10</tpages></addata></record> |
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| subjects | Aldehydes Amines Catalysis Catalysts Catalytic activity Chemical reactions Chemistry Chemistry and Materials Science Coordination compounds Copper Copper (Metal) Copper compounds Covalence Crosslinking Graphene Graphite Industrial applications Industrial Chemistry/Chemical Engineering Industrial equipment Infrared analysis Ketones Organometallic Chemistry Physical Chemistry Porphyrins |
| title | Covalently Copper(II) Porphyrin Cross-Linked Graphene Oxide: Preparation and Catalytic Activity |
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