Hydrodechlorination of p-Chlorophenol on Pd-Coated Fe3O4@polypyrrole Catalyst with Ammonia Borane as Hydrogen Donor
Ammonia borane (AB) (hydrogen donor), was used for the hydrodechlorination of p -chlorophenol on Fe 3 O 4 @PPY@Pd at room temperature and pressure. Fe 3 O 4 @PPY@Pd was characterized by scanning electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. The high-performance liquid...
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| Veröffentlicht in: | Catalysis letters 2019-03, Vol.149 (3), p.823-830 |
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| creator | Wei, Xuefeng Wan, Xiaoyang Miao, Juan Zhang, Ruichang Zhang, Jun Niu, Qingshan Jason |
| description | Ammonia borane (AB) (hydrogen donor), was used for the hydrodechlorination of
p
-chlorophenol on Fe
3
O
4
@PPY@Pd at room temperature and pressure. Fe
3
O
4
@PPY@Pd was characterized by scanning electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. The high-performance liquid chromatography and carbon balance results showed that
p
-chlorophenol was efficiently and quantitatively transformed into phenol. At the AB and catalyst contents of 2.5 mmol and 60 mg, respectively, the dechlorination of
p
-chlorophenol (100 mg/L) followed pseudo-first-order kinetics (rate constant = 0.023 min
−1
), and removal efficiency up to 92.5% was obtained in 120 min. The apparent activation energy was 31.6 kJ/mol. The Fe
3
O
4
@PPY@Pd composite catalyst could be reused without a significant loss in activity. This confirms the good stability of the catalyst. Here, a reductive approach for the dechlorination of organic compounds in water is provided. It is also useful for the fabrication of Pd-based nanocatalysts with easy accessibility, superior activity, and convenient recovery.
Graphical Abstract |
| doi_str_mv | 10.1007/s10562-019-02664-3 |
| format | Article |
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p
-chlorophenol on Fe
3
O
4
@PPY@Pd at room temperature and pressure. Fe
3
O
4
@PPY@Pd was characterized by scanning electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. The high-performance liquid chromatography and carbon balance results showed that
p
-chlorophenol was efficiently and quantitatively transformed into phenol. At the AB and catalyst contents of 2.5 mmol and 60 mg, respectively, the dechlorination of
p
-chlorophenol (100 mg/L) followed pseudo-first-order kinetics (rate constant = 0.023 min
−1
), and removal efficiency up to 92.5% was obtained in 120 min. The apparent activation energy was 31.6 kJ/mol. The Fe
3
O
4
@PPY@Pd composite catalyst could be reused without a significant loss in activity. This confirms the good stability of the catalyst. Here, a reductive approach for the dechlorination of organic compounds in water is provided. It is also useful for the fabrication of Pd-based nanocatalysts with easy accessibility, superior activity, and convenient recovery.
Graphical Abstract</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-019-02664-3</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Ammonia ; Catalysis ; Catalysts ; Chemistry ; Chemistry and Materials Science ; Chlorophenol ; Dechlorination ; High performance liquid chromatography ; Hydrodechlorination ; Industrial Chemistry/Chemical Engineering ; Iron oxides ; Organic compounds ; Organometallic Chemistry ; Oxidation ; Photoelectrons ; Physical Chemistry ; Polypyrroles ; Reaction kinetics ; Room temperature</subject><ispartof>Catalysis letters, 2019-03, Vol.149 (3), p.823-830</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019</rights><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c249t-4ccd0d7d352121d698de4ff2529729622aeb94747c494aefdb47eb54d16e2e373</citedby><cites>FETCH-LOGICAL-c249t-4ccd0d7d352121d698de4ff2529729622aeb94747c494aefdb47eb54d16e2e373</cites><orcidid>0000-0003-1872-3365</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10562-019-02664-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10562-019-02664-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Wei, Xuefeng</creatorcontrib><creatorcontrib>Wan, Xiaoyang</creatorcontrib><creatorcontrib>Miao, Juan</creatorcontrib><creatorcontrib>Zhang, Ruichang</creatorcontrib><creatorcontrib>Zhang, Jun</creatorcontrib><creatorcontrib>Niu, Qingshan Jason</creatorcontrib><title>Hydrodechlorination of p-Chlorophenol on Pd-Coated Fe3O4@polypyrrole Catalyst with Ammonia Borane as Hydrogen Donor</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>Ammonia borane (AB) (hydrogen donor), was used for the hydrodechlorination of
p
-chlorophenol on Fe
3
O
4
@PPY@Pd at room temperature and pressure. Fe
3
O
4
@PPY@Pd was characterized by scanning electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. The high-performance liquid chromatography and carbon balance results showed that
p
-chlorophenol was efficiently and quantitatively transformed into phenol. At the AB and catalyst contents of 2.5 mmol and 60 mg, respectively, the dechlorination of
p
-chlorophenol (100 mg/L) followed pseudo-first-order kinetics (rate constant = 0.023 min
−1
), and removal efficiency up to 92.5% was obtained in 120 min. The apparent activation energy was 31.6 kJ/mol. The Fe
3
O
4
@PPY@Pd composite catalyst could be reused without a significant loss in activity. This confirms the good stability of the catalyst. Here, a reductive approach for the dechlorination of organic compounds in water is provided. It is also useful for the fabrication of Pd-based nanocatalysts with easy accessibility, superior activity, and convenient recovery.
Graphical Abstract</description><subject>Ammonia</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chlorophenol</subject><subject>Dechlorination</subject><subject>High performance liquid chromatography</subject><subject>Hydrodechlorination</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Iron oxides</subject><subject>Organic compounds</subject><subject>Organometallic Chemistry</subject><subject>Oxidation</subject><subject>Photoelectrons</subject><subject>Physical Chemistry</subject><subject>Polypyrroles</subject><subject>Reaction kinetics</subject><subject>Room temperature</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kE9LwzAYxoMoOKdfwFPAczRJ02a5OatzwmAeFHYLWfN26-iSmnRIv73dKnjz9L48PH_gh9Ato_eMUvkQGU0zTihThPIsEyQ5QyOWSk4mUq3O-58yRhLJV5foKsYdpVRJpkYozjsbvIViW_tQOdNW3mFf4obkR8U3W3C-xr34bknuTQsWzyBZisfG113TheBrwLlpTd3FFn9X7RZP93vvKoOffDAOsIn4NLIBh5-98-EaXZSmjnDze8foc_bykc_JYvn6lk8XpOBCtUQUhaVW2iTljDObqYkFUZY85UpylXFuYK2EFLIQShgo7VpIWKfCsgw4JDIZo7uhtwn-6wCx1Tt_CK6f1FzQTCoxEbR38cFVBB9jgFI3odqb0GlG9RGuHuDqHq4-wdVJH0qGUOzNbgPhr_qf1A93wH3d</recordid><startdate>20190301</startdate><enddate>20190301</enddate><creator>Wei, Xuefeng</creator><creator>Wan, Xiaoyang</creator><creator>Miao, Juan</creator><creator>Zhang, Ruichang</creator><creator>Zhang, Jun</creator><creator>Niu, Qingshan Jason</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0003-1872-3365</orcidid></search><sort><creationdate>20190301</creationdate><title>Hydrodechlorination of p-Chlorophenol on Pd-Coated Fe3O4@polypyrrole Catalyst with Ammonia Borane as Hydrogen Donor</title><author>Wei, Xuefeng ; Wan, Xiaoyang ; Miao, Juan ; Zhang, Ruichang ; Zhang, Jun ; Niu, Qingshan Jason</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c249t-4ccd0d7d352121d698de4ff2529729622aeb94747c494aefdb47eb54d16e2e373</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Ammonia</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chlorophenol</topic><topic>Dechlorination</topic><topic>High performance liquid chromatography</topic><topic>Hydrodechlorination</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Iron oxides</topic><topic>Organic compounds</topic><topic>Organometallic Chemistry</topic><topic>Oxidation</topic><topic>Photoelectrons</topic><topic>Physical Chemistry</topic><topic>Polypyrroles</topic><topic>Reaction kinetics</topic><topic>Room temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wei, Xuefeng</creatorcontrib><creatorcontrib>Wan, Xiaoyang</creatorcontrib><creatorcontrib>Miao, Juan</creatorcontrib><creatorcontrib>Zhang, Ruichang</creatorcontrib><creatorcontrib>Zhang, Jun</creatorcontrib><creatorcontrib>Niu, Qingshan Jason</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wei, Xuefeng</au><au>Wan, Xiaoyang</au><au>Miao, Juan</au><au>Zhang, Ruichang</au><au>Zhang, Jun</au><au>Niu, Qingshan Jason</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrodechlorination of p-Chlorophenol on Pd-Coated Fe3O4@polypyrrole Catalyst with Ammonia Borane as Hydrogen Donor</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2019-03-01</date><risdate>2019</risdate><volume>149</volume><issue>3</issue><spage>823</spage><epage>830</epage><pages>823-830</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>Ammonia borane (AB) (hydrogen donor), was used for the hydrodechlorination of
p
-chlorophenol on Fe
3
O
4
@PPY@Pd at room temperature and pressure. Fe
3
O
4
@PPY@Pd was characterized by scanning electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. The high-performance liquid chromatography and carbon balance results showed that
p
-chlorophenol was efficiently and quantitatively transformed into phenol. At the AB and catalyst contents of 2.5 mmol and 60 mg, respectively, the dechlorination of
p
-chlorophenol (100 mg/L) followed pseudo-first-order kinetics (rate constant = 0.023 min
−1
), and removal efficiency up to 92.5% was obtained in 120 min. The apparent activation energy was 31.6 kJ/mol. The Fe
3
O
4
@PPY@Pd composite catalyst could be reused without a significant loss in activity. This confirms the good stability of the catalyst. Here, a reductive approach for the dechlorination of organic compounds in water is provided. It is also useful for the fabrication of Pd-based nanocatalysts with easy accessibility, superior activity, and convenient recovery.
Graphical Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10562-019-02664-3</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-1872-3365</orcidid></addata></record> |
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| subjects | Ammonia Catalysis Catalysts Chemistry Chemistry and Materials Science Chlorophenol Dechlorination High performance liquid chromatography Hydrodechlorination Industrial Chemistry/Chemical Engineering Iron oxides Organic compounds Organometallic Chemistry Oxidation Photoelectrons Physical Chemistry Polypyrroles Reaction kinetics Room temperature |
| title | Hydrodechlorination of p-Chlorophenol on Pd-Coated Fe3O4@polypyrrole Catalyst with Ammonia Borane as Hydrogen Donor |
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