Fe–PNP Pincer Complex Immobilized on Graphene Oxide as a Catalyst for Suzuki–Miyaura Coupling Reactions
Fe–PNP pincer complexes are the upcoming homogenous catalyst for organic reactions to overcome the need of much expensive Pd based catalysts. However, the lack of recovery and reusability are two significant challenges for homogeneous catalysts. We report herein a Fe–PNP complex immobilized on graph...
Gespeichert in:
Veröffentlicht in: | Catalysis letters 2019-04, Vol.149 (4), p.1118-1124 |
---|---|
Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 1124 |
---|---|
container_issue | 4 |
container_start_page | 1118 |
container_title | Catalysis letters |
container_volume | 149 |
creator | Kumar, Lolakshi Mahesh Mishra Praveen Bhat, Badekai Ramachandra |
description | Fe–PNP pincer complexes are the upcoming homogenous catalyst for organic reactions to overcome the need of much expensive Pd based catalysts. However, the lack of recovery and reusability are two significant challenges for homogeneous catalysts. We report herein a Fe–PNP complex immobilized on graphene oxide as a heterogeneous catalyst for the Suzuki coupling reactions. The prepared composite showed remarkable conversion efficiency towards Suzuki coupling reaction between phenylboronic acid and aryl halides. The study also discusses the parameters that are affecting the coupling reaction. The proposed catalyst can be quickly recovered and reused without any significant reduction in performance. |
doi_str_mv | 10.1007/s10562-019-02652-7 |
format | Article |
fullrecord | <record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_journals_2406784187</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2406784187</sourcerecordid><originalsourceid>FETCH-LOGICAL-p183t-1fd4cf0c488cc31a7885e7633a7351249abe8578b5b91ac6a6587819eeb06ef33</originalsourceid><addsrcrecordid>eNotjd1KwzAYhoMoOKc34FHA42i-pGnSQynuB6Yb_sDORtp91WxdU5sWth15D96hV2JBj94HHnheQq6B3wLn-i4AV7FgHBLGRawE0ydkAEoLZnSyPO2ZAzCpxfKcXISw4ZwnGpIB2Y7w5-t78bSgC1fl2NDU7-oS93S62_nMle6Ia-orOm5s_YEV0vnerZHaQC1NbWvLQ2hp4Rv60h27retbj-5gu6a3vqtLV73TZ7R563wVLslZYcuAV_87JG-jh9d0wmbz8TS9n7EajGwZFOsoL3geGZPnEqw2RqGOpbRaKhBRYjM0SptMZQnYPLaxMtpAgpjxGAsph-Tmr1s3_rPD0K42vmuq_nIlIh5rE4HR8he8gFzZ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2406784187</pqid></control><display><type>article</type><title>Fe–PNP Pincer Complex Immobilized on Graphene Oxide as a Catalyst for Suzuki–Miyaura Coupling Reactions</title><source>SpringerLink Journals - AutoHoldings</source><creator>Kumar, Lolakshi Mahesh ; Mishra Praveen ; Bhat, Badekai Ramachandra</creator><creatorcontrib>Kumar, Lolakshi Mahesh ; Mishra Praveen ; Bhat, Badekai Ramachandra</creatorcontrib><description>Fe–PNP pincer complexes are the upcoming homogenous catalyst for organic reactions to overcome the need of much expensive Pd based catalysts. However, the lack of recovery and reusability are two significant challenges for homogeneous catalysts. We report herein a Fe–PNP complex immobilized on graphene oxide as a heterogeneous catalyst for the Suzuki coupling reactions. The prepared composite showed remarkable conversion efficiency towards Suzuki coupling reaction between phenylboronic acid and aryl halides. The study also discusses the parameters that are affecting the coupling reaction. The proposed catalyst can be quickly recovered and reused without any significant reduction in performance.</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-019-02652-7</identifier><language>eng</language><publisher>Dordrecht: Springer Nature B.V</publisher><subject>Aromatic compounds ; Catalysts ; Chemical reactions ; Coupling ; Graphene ; Halides</subject><ispartof>Catalysis letters, 2019-04, Vol.149 (4), p.1118-1124</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Kumar, Lolakshi Mahesh</creatorcontrib><creatorcontrib>Mishra Praveen</creatorcontrib><creatorcontrib>Bhat, Badekai Ramachandra</creatorcontrib><title>Fe–PNP Pincer Complex Immobilized on Graphene Oxide as a Catalyst for Suzuki–Miyaura Coupling Reactions</title><title>Catalysis letters</title><description>Fe–PNP pincer complexes are the upcoming homogenous catalyst for organic reactions to overcome the need of much expensive Pd based catalysts. However, the lack of recovery and reusability are two significant challenges for homogeneous catalysts. We report herein a Fe–PNP complex immobilized on graphene oxide as a heterogeneous catalyst for the Suzuki coupling reactions. The prepared composite showed remarkable conversion efficiency towards Suzuki coupling reaction between phenylboronic acid and aryl halides. The study also discusses the parameters that are affecting the coupling reaction. The proposed catalyst can be quickly recovered and reused without any significant reduction in performance.</description><subject>Aromatic compounds</subject><subject>Catalysts</subject><subject>Chemical reactions</subject><subject>Coupling</subject><subject>Graphene</subject><subject>Halides</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNotjd1KwzAYhoMoOKc34FHA42i-pGnSQynuB6Yb_sDORtp91WxdU5sWth15D96hV2JBj94HHnheQq6B3wLn-i4AV7FgHBLGRawE0ydkAEoLZnSyPO2ZAzCpxfKcXISw4ZwnGpIB2Y7w5-t78bSgC1fl2NDU7-oS93S62_nMle6Ia-orOm5s_YEV0vnerZHaQC1NbWvLQ2hp4Rv60h27retbj-5gu6a3vqtLV73TZ7R563wVLslZYcuAV_87JG-jh9d0wmbz8TS9n7EajGwZFOsoL3geGZPnEqw2RqGOpbRaKhBRYjM0SptMZQnYPLaxMtpAgpjxGAsph-Tmr1s3_rPD0K42vmuq_nIlIh5rE4HR8he8gFzZ</recordid><startdate>20190401</startdate><enddate>20190401</enddate><creator>Kumar, Lolakshi Mahesh</creator><creator>Mishra Praveen</creator><creator>Bhat, Badekai Ramachandra</creator><general>Springer Nature B.V</general><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20190401</creationdate><title>Fe–PNP Pincer Complex Immobilized on Graphene Oxide as a Catalyst for Suzuki–Miyaura Coupling Reactions</title><author>Kumar, Lolakshi Mahesh ; Mishra Praveen ; Bhat, Badekai Ramachandra</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p183t-1fd4cf0c488cc31a7885e7633a7351249abe8578b5b91ac6a6587819eeb06ef33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Aromatic compounds</topic><topic>Catalysts</topic><topic>Chemical reactions</topic><topic>Coupling</topic><topic>Graphene</topic><topic>Halides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kumar, Lolakshi Mahesh</creatorcontrib><creatorcontrib>Mishra Praveen</creatorcontrib><creatorcontrib>Bhat, Badekai Ramachandra</creatorcontrib><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kumar, Lolakshi Mahesh</au><au>Mishra Praveen</au><au>Bhat, Badekai Ramachandra</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fe–PNP Pincer Complex Immobilized on Graphene Oxide as a Catalyst for Suzuki–Miyaura Coupling Reactions</atitle><jtitle>Catalysis letters</jtitle><date>2019-04-01</date><risdate>2019</risdate><volume>149</volume><issue>4</issue><spage>1118</spage><epage>1124</epage><pages>1118-1124</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>Fe–PNP pincer complexes are the upcoming homogenous catalyst for organic reactions to overcome the need of much expensive Pd based catalysts. However, the lack of recovery and reusability are two significant challenges for homogeneous catalysts. We report herein a Fe–PNP complex immobilized on graphene oxide as a heterogeneous catalyst for the Suzuki coupling reactions. The prepared composite showed remarkable conversion efficiency towards Suzuki coupling reaction between phenylboronic acid and aryl halides. The study also discusses the parameters that are affecting the coupling reaction. The proposed catalyst can be quickly recovered and reused without any significant reduction in performance.</abstract><cop>Dordrecht</cop><pub>Springer Nature B.V</pub><doi>10.1007/s10562-019-02652-7</doi><tpages>7</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 1011-372X |
ispartof | Catalysis letters, 2019-04, Vol.149 (4), p.1118-1124 |
issn | 1011-372X 1572-879X |
language | eng |
recordid | cdi_proquest_journals_2406784187 |
source | SpringerLink Journals - AutoHoldings |
subjects | Aromatic compounds Catalysts Chemical reactions Coupling Graphene Halides |
title | Fe–PNP Pincer Complex Immobilized on Graphene Oxide as a Catalyst for Suzuki–Miyaura Coupling Reactions |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-07T20%3A14%3A12IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Fe%E2%80%93PNP%20Pincer%20Complex%20Immobilized%20on%20Graphene%20Oxide%20as%20a%20Catalyst%20for%20Suzuki%E2%80%93Miyaura%20Coupling%20Reactions&rft.jtitle=Catalysis%20letters&rft.au=Kumar,%20Lolakshi%20Mahesh&rft.date=2019-04-01&rft.volume=149&rft.issue=4&rft.spage=1118&rft.epage=1124&rft.pages=1118-1124&rft.issn=1011-372X&rft.eissn=1572-879X&rft_id=info:doi/10.1007/s10562-019-02652-7&rft_dat=%3Cproquest%3E2406784187%3C/proquest%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2406784187&rft_id=info:pmid/&rfr_iscdi=true |