Ion-Tagged Prolinamide Organocatalysts for the Direct Aldol Reaction On-Water

A concise synthesis of two imidazolium ion-tagged prolinamide organocatalysts 3 and 4, varying in anionic component (CF 3 COO − and PF 6 − , respectively) is presented. The latter could be classified as an ionic liquid with a melting point of 66.3 °C, and glass transition temperature of 14.5 °C. The...

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Veröffentlicht in:	Catalysis letters 2016, Vol.146 (1), p.212-219
Hauptverfasser:	Eyckens, Daniel J., Brozinski, Hannah L., Delaney, Joshua P., Servinis, Linden, Naghashian, Sahar, Henderson, Luke C.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Catalysis Catalysts Chemical synthesis Chemistry Chemistry and Materials Science Comparative analysis Glass transition temperature Industrial Chemistry/Chemical Engineering Ionic liquids Melting points Organometallic Chemistry Physical Chemistry Substrates Surface active agents
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