Synthesis and characterization of semi-permeable graphene/graphene oxide membranes for water desalination
In this paper, we present novel semi-permeable graphene-based membranes. Composite filters were designed and fabricated on polysulfone porous scaffolding using combinations of polycrystalline large-area High Strength Metallurgical Graphene (HSMG®), graphene oxide, hydrazine and an in-situ interfacia...
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Veröffentlicht in: | Journal of materials science 2020-08, Vol.55 (23), p.9775-9786 |
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creator | Romaniak, Grzegorz Dybowski, Konrad Jeziorna, Agata Kula, Piotr Kaźmierczak, Tomasz |
description | In this paper, we present novel semi-permeable graphene-based membranes. Composite filters were designed and fabricated on polysulfone porous scaffolding using combinations of polycrystalline large-area High Strength Metallurgical Graphene (HSMG®), graphene oxide, hydrazine and an in-situ interfacial polymerized polyamide. The naturally occurring defects in HSMG® (which were tenths of a nanometer) were the clue in fabricating a filtering membrane. The performance of graphene membranes was evaluated in forward osmosis test. The prepared composites were proved to be semi-permeable membranes with great ions blocking efficiency (over 95%) and water flux only one order of magnitude lower than the commercial reverse osmosis membranes. The experiments’ results demonstrated that the solutions proposed in this work indicate that graphene-based membranes can be used in water treatment technology. |
doi_str_mv | 10.1007/s10853-020-04648-w |
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Composite filters were designed and fabricated on polysulfone porous scaffolding using combinations of polycrystalline large-area High Strength Metallurgical Graphene (HSMG®), graphene oxide, hydrazine and an in-situ interfacial polymerized polyamide. The naturally occurring defects in HSMG® (which were tenths of a nanometer) were the clue in fabricating a filtering membrane. The performance of graphene membranes was evaluated in forward osmosis test. The prepared composites were proved to be semi-permeable membranes with great ions blocking efficiency (over 95%) and water flux only one order of magnitude lower than the commercial reverse osmosis membranes. The experiments’ results demonstrated that the solutions proposed in this work indicate that graphene-based membranes can be used in water treatment technology.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-020-04648-w</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Advanced Nano Materials ; Aquatic resources ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Classical Mechanics ; Crystallography and Scattering Methods ; Desalination ; Fluid filters ; Graphene ; Graphite ; Hydrazines ; Materials Science ; Membranes ; Metallurgy ; Osmosis ; Permeability ; Polyamide resins ; Polyamides ; Polymer Sciences ; Polysulfone resins ; Reverse osmosis ; Saline water conversion ; Scaffolding ; Solid Mechanics ; Water treatment</subject><ispartof>Journal of materials science, 2020-08, Vol.55 (23), p.9775-9786</ispartof><rights>The Author(s) 2020</rights><rights>COPYRIGHT 2020 Springer</rights><rights>The Author(s) 2020. 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subjects | Advanced Nano Materials Aquatic resources Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Crystallography and Scattering Methods Desalination Fluid filters Graphene Graphite Hydrazines Materials Science Membranes Metallurgy Osmosis Permeability Polyamide resins Polyamides Polymer Sciences Polysulfone resins Reverse osmosis Saline water conversion Scaffolding Solid Mechanics Water treatment |
title | Synthesis and characterization of semi-permeable graphene/graphene oxide membranes for water desalination |
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