One-step and template-free fabrication of hollow carbon-modified Fe3O4 for catalyzing solvent-free aerobic oxidation of benzyl alcohol
A hollow carbon-modified Fe 3 O 4 (H-C-Fe 3 O 4 ) has been fabricated by a one-step and template-free solvothermal method with ethanol as the solvent. The catalytic activity of H-C-Fe 3 O 4 (ethanol) is investigated for solvent-free aerobic oxidation of benzyl alcohol to benzaldehyde with O 2 . It i...
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| Veröffentlicht in: | Journal of porous materials 2020, Vol.27 (3), p.701-705 |
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| container_issue | 3 |
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| container_title | Journal of porous materials |
| container_volume | 27 |
| creator | Gu, Yingqiu Lu, Pan Zhan, Wenwen Zhang, Yadong Sun, Liming Chen, Guojian Long, Zhouyang |
| description | A hollow carbon-modified Fe
3
O
4
(H-C-Fe
3
O
4
) has been fabricated by a one-step and template-free solvothermal method with ethanol as the solvent. The catalytic activity of H-C-Fe
3
O
4
(ethanol) is investigated for solvent-free aerobic oxidation of benzyl alcohol to benzaldehyde with O
2
. It is found that H-C-Fe
3
O
4
(ethanol) offer a superior benzaldehyde yield and selectivity. The good catalytic performance of H-C-Fe
3
O
4
(ethanol) benefits from the rich interfaces between the carbon and Fe
3
O
4
, plus the interspace voids introduced by its hollow structure. Besides, the target H-C-Fe
3
O
4
(ethanol) can be facilely recycled with a magnet and exhibits good potential for catalyst reuse. |
| doi_str_mv | 10.1007/s10934-020-00858-4 |
| format | Article |
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3
O
4
(H-C-Fe
3
O
4
) has been fabricated by a one-step and template-free solvothermal method with ethanol as the solvent. The catalytic activity of H-C-Fe
3
O
4
(ethanol) is investigated for solvent-free aerobic oxidation of benzyl alcohol to benzaldehyde with O
2
. It is found that H-C-Fe
3
O
4
(ethanol) offer a superior benzaldehyde yield and selectivity. The good catalytic performance of H-C-Fe
3
O
4
(ethanol) benefits from the rich interfaces between the carbon and Fe
3
O
4
, plus the interspace voids introduced by its hollow structure. Besides, the target H-C-Fe
3
O
4
(ethanol) can be facilely recycled with a magnet and exhibits good potential for catalyst reuse.</description><identifier>ISSN: 1380-2224</identifier><identifier>EISSN: 1573-4854</identifier><identifier>DOI: 10.1007/s10934-020-00858-4</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Benzaldehyde ; Benzyl alcohol ; Carbon ; Catalysis ; Catalytic activity ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Ethanol ; Iron oxides ; Oxidation ; Physical Chemistry ; Selectivity ; Solvents</subject><ispartof>Journal of porous materials, 2020, Vol.27 (3), p.701-705</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2020</rights><rights>Springer Science+Business Media, LLC, part of Springer Nature 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3374-1ba22b3aa2362326d743c000c71998f23ddc92b01d930c81bfb05da2fa29b51a3</citedby><cites>FETCH-LOGICAL-c3374-1ba22b3aa2362326d743c000c71998f23ddc92b01d930c81bfb05da2fa29b51a3</cites><orcidid>0000-0002-5520-6263</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10934-020-00858-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10934-020-00858-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51298</link.rule.ids></links><search><creatorcontrib>Gu, Yingqiu</creatorcontrib><creatorcontrib>Lu, Pan</creatorcontrib><creatorcontrib>Zhan, Wenwen</creatorcontrib><creatorcontrib>Zhang, Yadong</creatorcontrib><creatorcontrib>Sun, Liming</creatorcontrib><creatorcontrib>Chen, Guojian</creatorcontrib><creatorcontrib>Long, Zhouyang</creatorcontrib><title>One-step and template-free fabrication of hollow carbon-modified Fe3O4 for catalyzing solvent-free aerobic oxidation of benzyl alcohol</title><title>Journal of porous materials</title><addtitle>J Porous Mater</addtitle><description>A hollow carbon-modified Fe
3
O
4
(H-C-Fe
3
O
4
) has been fabricated by a one-step and template-free solvothermal method with ethanol as the solvent. The catalytic activity of H-C-Fe
3
O
4
(ethanol) is investigated for solvent-free aerobic oxidation of benzyl alcohol to benzaldehyde with O
2
. It is found that H-C-Fe
3
O
4
(ethanol) offer a superior benzaldehyde yield and selectivity. The good catalytic performance of H-C-Fe
3
O
4
(ethanol) benefits from the rich interfaces between the carbon and Fe
3
O
4
, plus the interspace voids introduced by its hollow structure. Besides, the target H-C-Fe
3
O
4
(ethanol) can be facilely recycled with a magnet and exhibits good potential for catalyst reuse.</description><subject>Benzaldehyde</subject><subject>Benzyl alcohol</subject><subject>Carbon</subject><subject>Catalysis</subject><subject>Catalytic activity</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Ethanol</subject><subject>Iron oxides</subject><subject>Oxidation</subject><subject>Physical Chemistry</subject><subject>Selectivity</subject><subject>Solvents</subject><issn>1380-2224</issn><issn>1573-4854</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kMtOwzAQRSMEEqXwA6wssTaMH2mSJaooIFXqBtaWnyVVagc7BcoH8N0YgmDHyiP53jOaUxTnBC4JQHWVCDSMY6CAAeqyxvygmJCyYpjXJT_MM6sBU0r5cXGS0gYAmrqqJsXHylucBtsj6Q0a7Lbv5GCxi9YiJ1VstRza4FFw6Cl0XXhFWkYVPN4G07rWGrSwbMWRCzH_DLLbv7d-jVLoXqwfRo60MahWo_DWml-asv593yHZ6ZDBp8WRk12yZz_vtHhc3DzM7_BydXs_v15izVjFMVGSUsWkpGxGGZ2ZijOdb9EVaZraUWaMbqgCYhoGuibKKSiNpE7SRpVEsmlxMXL7GJ53Ng1iE3bR55WCcigbKFnFcoqOKR1DStE60cd2K-NeEBBfvsXoW2Tf4tu34LnExlLKYb-28Q_9T-sTFd2Ecg</recordid><startdate>2020</startdate><enddate>2020</enddate><creator>Gu, Yingqiu</creator><creator>Lu, Pan</creator><creator>Zhan, Wenwen</creator><creator>Zhang, Yadong</creator><creator>Sun, Liming</creator><creator>Chen, Guojian</creator><creator>Long, Zhouyang</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-5520-6263</orcidid></search><sort><creationdate>2020</creationdate><title>One-step and template-free fabrication of hollow carbon-modified Fe3O4 for catalyzing solvent-free aerobic oxidation of benzyl alcohol</title><author>Gu, Yingqiu ; Lu, Pan ; Zhan, Wenwen ; Zhang, Yadong ; Sun, Liming ; Chen, Guojian ; Long, Zhouyang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3374-1ba22b3aa2362326d743c000c71998f23ddc92b01d930c81bfb05da2fa29b51a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Benzaldehyde</topic><topic>Benzyl alcohol</topic><topic>Carbon</topic><topic>Catalysis</topic><topic>Catalytic activity</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Ethanol</topic><topic>Iron oxides</topic><topic>Oxidation</topic><topic>Physical Chemistry</topic><topic>Selectivity</topic><topic>Solvents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gu, Yingqiu</creatorcontrib><creatorcontrib>Lu, Pan</creatorcontrib><creatorcontrib>Zhan, Wenwen</creatorcontrib><creatorcontrib>Zhang, Yadong</creatorcontrib><creatorcontrib>Sun, Liming</creatorcontrib><creatorcontrib>Chen, Guojian</creatorcontrib><creatorcontrib>Long, Zhouyang</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of porous materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gu, Yingqiu</au><au>Lu, Pan</au><au>Zhan, Wenwen</au><au>Zhang, Yadong</au><au>Sun, Liming</au><au>Chen, Guojian</au><au>Long, Zhouyang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>One-step and template-free fabrication of hollow carbon-modified Fe3O4 for catalyzing solvent-free aerobic oxidation of benzyl alcohol</atitle><jtitle>Journal of porous materials</jtitle><stitle>J Porous Mater</stitle><date>2020</date><risdate>2020</risdate><volume>27</volume><issue>3</issue><spage>701</spage><epage>705</epage><pages>701-705</pages><issn>1380-2224</issn><eissn>1573-4854</eissn><abstract>A hollow carbon-modified Fe
3
O
4
(H-C-Fe
3
O
4
) has been fabricated by a one-step and template-free solvothermal method with ethanol as the solvent. The catalytic activity of H-C-Fe
3
O
4
(ethanol) is investigated for solvent-free aerobic oxidation of benzyl alcohol to benzaldehyde with O
2
. It is found that H-C-Fe
3
O
4
(ethanol) offer a superior benzaldehyde yield and selectivity. The good catalytic performance of H-C-Fe
3
O
4
(ethanol) benefits from the rich interfaces between the carbon and Fe
3
O
4
, plus the interspace voids introduced by its hollow structure. Besides, the target H-C-Fe
3
O
4
(ethanol) can be facilely recycled with a magnet and exhibits good potential for catalyst reuse.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10934-020-00858-4</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-5520-6263</orcidid></addata></record> |
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| issn | 1380-2224 1573-4854 |
| language | eng |
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| source | SpringerLink |
| subjects | Benzaldehyde Benzyl alcohol Carbon Catalysis Catalytic activity Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Ethanol Iron oxides Oxidation Physical Chemistry Selectivity Solvents |
| title | One-step and template-free fabrication of hollow carbon-modified Fe3O4 for catalyzing solvent-free aerobic oxidation of benzyl alcohol |
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