Synthesis and Optical and Electrochemical Properties of Novel Random Terpolymers Based on Diketopyrrolopyrrole and Benzodithiazole/Quinoxaline Units for Polymer Solar Cells
Two new binary polymers ( P16 , P20 ) and three random terpolymers ( P17 , P18 , P19 ) with different ratios of the A1 (DPP) and A2 (BTTQ) acceptors in the polymer chains were developed and synthesized. Their optical and electrochemical properties were studied. The random terpolymers ( P17 , P18 , P...
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| Veröffentlicht in: | Doklady. Chemistry 2020, Vol.490 (1), p.6-10 |
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| container_title | Doklady. Chemistry |
| container_volume | 490 |
| creator | Keshtov, M. L. Kuklin, S. A. Konstantinov, I. O. Ostapov, I. E. Mahaeva, E. E. Khokhlov, A. R. Xie, Z. Sharma, G. D. |
| description | Two new binary polymers (
P16
,
P20
) and three random terpolymers (
P17
,
P18
,
P19
) with different ratios of the A1 (DPP) and A2 (BTTQ) acceptors in the polymer chains were developed and synthesized. Their optical and electrochemical properties were studied. The random terpolymers (
P17
,
P18
,
P19
) possess wider absorption spectra than the binary D–A copolymers (
P16
,
P20
). It was shown that the position of absorption bands and energy levels can be easily tuned by varying the molar ratios of the two different acceptor units in the terpolymer backbone. The synthesized random terpolymers can be used as efficient donor materials for fullerene and non-fullerene polymer solar cells. |
| doi_str_mv | 10.1134/S0012500820010036 |
| format | Article |
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P16
,
P20
) and three random terpolymers (
P17
,
P18
,
P19
) with different ratios of the A1 (DPP) and A2 (BTTQ) acceptors in the polymer chains were developed and synthesized. Their optical and electrochemical properties were studied. The random terpolymers (
P17
,
P18
,
P19
) possess wider absorption spectra than the binary D–A copolymers (
P16
,
P20
). It was shown that the position of absorption bands and energy levels can be easily tuned by varying the molar ratios of the two different acceptor units in the terpolymer backbone. The synthesized random terpolymers can be used as efficient donor materials for fullerene and non-fullerene polymer solar cells.</description><identifier>ISSN: 0012-5008</identifier><identifier>EISSN: 1608-3113</identifier><identifier>DOI: 10.1134/S0012500820010036</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Absorption spectra ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Copolymers ; Donor materials ; Electrochemical analysis ; Energy levels ; Fullerenes ; Industrial Chemistry/Chemical Engineering ; Optical properties ; Photovoltaic cells ; Polymers ; Quinoxalines ; Solar cells ; Terpolymers</subject><ispartof>Doklady. Chemistry, 2020, Vol.490 (1), p.6-10</ispartof><rights>Pleiades Publishing, Ltd. 2020</rights><rights>Pleiades Publishing, Ltd. 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-9b4873c93ff3da55b7199dd4b1d25529a1de91f0eb9793a0a0dc906e16877d503</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0012500820010036$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0012500820010036$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Keshtov, M. L.</creatorcontrib><creatorcontrib>Kuklin, S. A.</creatorcontrib><creatorcontrib>Konstantinov, I. O.</creatorcontrib><creatorcontrib>Ostapov, I. E.</creatorcontrib><creatorcontrib>Mahaeva, E. E.</creatorcontrib><creatorcontrib>Khokhlov, A. R.</creatorcontrib><creatorcontrib>Xie, Z.</creatorcontrib><creatorcontrib>Sharma, G. D.</creatorcontrib><title>Synthesis and Optical and Electrochemical Properties of Novel Random Terpolymers Based on Diketopyrrolopyrrole and Benzodithiazole/Quinoxaline Units for Polymer Solar Cells</title><title>Doklady. Chemistry</title><addtitle>Dokl Chem</addtitle><description>Two new binary polymers (
P16
,
P20
) and three random terpolymers (
P17
,
P18
,
P19
) with different ratios of the A1 (DPP) and A2 (BTTQ) acceptors in the polymer chains were developed and synthesized. Their optical and electrochemical properties were studied. The random terpolymers (
P17
,
P18
,
P19
) possess wider absorption spectra than the binary D–A copolymers (
P16
,
P20
). It was shown that the position of absorption bands and energy levels can be easily tuned by varying the molar ratios of the two different acceptor units in the terpolymer backbone. The synthesized random terpolymers can be used as efficient donor materials for fullerene and non-fullerene polymer solar cells.</description><subject>Absorption spectra</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Copolymers</subject><subject>Donor materials</subject><subject>Electrochemical analysis</subject><subject>Energy levels</subject><subject>Fullerenes</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Optical properties</subject><subject>Photovoltaic cells</subject><subject>Polymers</subject><subject>Quinoxalines</subject><subject>Solar cells</subject><subject>Terpolymers</subject><issn>0012-5008</issn><issn>1608-3113</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp1UclOwzAQtRBIlOUDuFniHDqOs_kIZZUQW-EcufGEGlw72C6ifBMfSdoicUCc3tPb5jCEHDA4YoxnwzEAS3OAKu0JAC82yIAVUCW8tzfJYGknS3-b7ITwAgCi5NWAfI0XNk4x6EClVfS2i7qRZsXPDDbRu2aKs5V2512HPmoM1LX0xr2joQ990M3oI_rOmcUMfaAnMqCiztJT_YrRdQvvnfkBXA2foP10Sseplp-9Nryfa-s-pNEW6ZPVMdDWeXq3HqRjZ6SnIzQm7JGtVpqA-z-4S57Ozx5Hl8n17cXV6Pg6adKiiomYZFXJG8HbliuZ55OSCaFUNmEqzfNUSKZQsBZwIkrBJUhQjYACWVGVpcqB75LD9W7n3dscQ6xf3Nzb_mSdZpDzVGRQ9Cm2TjXeheCxrTuvZ9Ivagb18in1n6f0nXTdCX3WPqP_Xf6_9A0bO5Hg</recordid><startdate>2020</startdate><enddate>2020</enddate><creator>Keshtov, M. L.</creator><creator>Kuklin, S. A.</creator><creator>Konstantinov, I. O.</creator><creator>Ostapov, I. E.</creator><creator>Mahaeva, E. E.</creator><creator>Khokhlov, A. R.</creator><creator>Xie, Z.</creator><creator>Sharma, G. D.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2020</creationdate><title>Synthesis and Optical and Electrochemical Properties of Novel Random Terpolymers Based on Diketopyrrolopyrrole and Benzodithiazole/Quinoxaline Units for Polymer Solar Cells</title><author>Keshtov, M. L. ; Kuklin, S. A. ; Konstantinov, I. O. ; Ostapov, I. E. ; Mahaeva, E. E. ; Khokhlov, A. R. ; Xie, Z. ; Sharma, G. D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-9b4873c93ff3da55b7199dd4b1d25529a1de91f0eb9793a0a0dc906e16877d503</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Absorption spectra</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Copolymers</topic><topic>Donor materials</topic><topic>Electrochemical analysis</topic><topic>Energy levels</topic><topic>Fullerenes</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Optical properties</topic><topic>Photovoltaic cells</topic><topic>Polymers</topic><topic>Quinoxalines</topic><topic>Solar cells</topic><topic>Terpolymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Keshtov, M. L.</creatorcontrib><creatorcontrib>Kuklin, S. A.</creatorcontrib><creatorcontrib>Konstantinov, I. O.</creatorcontrib><creatorcontrib>Ostapov, I. E.</creatorcontrib><creatorcontrib>Mahaeva, E. E.</creatorcontrib><creatorcontrib>Khokhlov, A. R.</creatorcontrib><creatorcontrib>Xie, Z.</creatorcontrib><creatorcontrib>Sharma, G. D.</creatorcontrib><collection>CrossRef</collection><jtitle>Doklady. Chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Keshtov, M. L.</au><au>Kuklin, S. A.</au><au>Konstantinov, I. O.</au><au>Ostapov, I. E.</au><au>Mahaeva, E. E.</au><au>Khokhlov, A. R.</au><au>Xie, Z.</au><au>Sharma, G. D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Optical and Electrochemical Properties of Novel Random Terpolymers Based on Diketopyrrolopyrrole and Benzodithiazole/Quinoxaline Units for Polymer Solar Cells</atitle><jtitle>Doklady. Chemistry</jtitle><stitle>Dokl Chem</stitle><date>2020</date><risdate>2020</risdate><volume>490</volume><issue>1</issue><spage>6</spage><epage>10</epage><pages>6-10</pages><issn>0012-5008</issn><eissn>1608-3113</eissn><abstract>Two new binary polymers (
P16
,
P20
) and three random terpolymers (
P17
,
P18
,
P19
) with different ratios of the A1 (DPP) and A2 (BTTQ) acceptors in the polymer chains were developed and synthesized. Their optical and electrochemical properties were studied. The random terpolymers (
P17
,
P18
,
P19
) possess wider absorption spectra than the binary D–A copolymers (
P16
,
P20
). It was shown that the position of absorption bands and energy levels can be easily tuned by varying the molar ratios of the two different acceptor units in the terpolymer backbone. The synthesized random terpolymers can be used as efficient donor materials for fullerene and non-fullerene polymer solar cells.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0012500820010036</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Doklady. Chemistry, 2020, Vol.490 (1), p.6-10 |
| issn | 0012-5008 1608-3113 |
| language | eng |
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| source | Springer Online Journals Complete |
| subjects | Absorption spectra Chemistry Chemistry and Materials Science Chemistry/Food Science Copolymers Donor materials Electrochemical analysis Energy levels Fullerenes Industrial Chemistry/Chemical Engineering Optical properties Photovoltaic cells Polymers Quinoxalines Solar cells Terpolymers |
| title | Synthesis and Optical and Electrochemical Properties of Novel Random Terpolymers Based on Diketopyrrolopyrrole and Benzodithiazole/Quinoxaline Units for Polymer Solar Cells |
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