Efficient alkene hydrosilation with bis(8-quinolyl)phosphine (NPN) nickel catalysts. The dominant role of silyl-over hydrido-nickel catalytic intermediates

A cationic nickel complex of the bis(8-quinolyl)(3,5-di- tert -butylphenoxy)phosphine (NPN) ligand, [(NPN)NiCl] + , is a precursor to efficient catalysts for the hydrosilation of alkenes with a variety of hydrosilanes under mild conditions and low catalyst loadings. DFT studies reveal the presence o...

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Veröffentlicht in:	Chemical science (Cambridge) 2020-05, Vol.11 (19), p.543-551
Hauptverfasser:	Yang, Jian, Postils, Verònica, Lipschutz, Michael I, Fasulo, Meg, Raynaud, Christophe, Clot, Eric, Eisenstein, Odile, Tilley, T. Don
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Catalysis Catalysts Chemical reactions Chemical Sciences Chemistry Crystallography Inorganic chemistry Mathematical analysis Nickel or physical chemistry Phosphines Theoretical and
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