Bimetallic Reactivities of Dinuclear Iridium and Rhodium Complexes Generated from Two Types of Alkyne‐Containing Bisphosphine Ligands

We have investigated the reactivities of a series of dinuclear iridium(II,II) and rhodium(II,II) 1,3‐butadiene‐1,4‐diyl complexes derived from two types of alkyne‐containing ligands. Newly developed ligand 2 afforded 2nd generation diiridium complexes that have higher reactivity toward halide substi...

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Veröffentlicht in:	European journal of inorganic chemistry 2020-05, Vol.2020 (19), p.1894-1901
Hauptverfasser:	Sasakura, Kohei, Okamoto, Kazuhiro, Ohe, Kouichi
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkyne ligands Alkynes Bimetals Butadiene Coordination compounds Crystallography Dinuclear complexes Inorganic chemistry Iridium Ligand substitution Ligands Reactivity Rhodium
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