Efficient Synthesis of γ-Valerolactone-A Potential Fuel from Biomass Derived Levulinic Acid Using Catalytic Transfer Hydrogenation Over Hf@CCSO3H Catalyst
A new hafnium based carbonaceous catalyst (Hf@CCSO 3 H) was prepared by simultaneous carbonization and sulfonation of readily available glucose, followed by incorporation of hafnium metal on the surface of catalyst. The catalyst was well characterized using FT-IR, PXRD, EDX, SEM, 13 C CPNMR, XPS and...
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| Veröffentlicht in: | Catalysis letters 2020-07, Vol.150 (7), p.2038-2044 |
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| creator | Jori, Popat K. Jadhav, Vrushali H. |
| description | A new hafnium based carbonaceous catalyst (Hf@CCSO
3
H) was prepared by simultaneous carbonization and sulfonation of readily available glucose, followed by incorporation of hafnium metal on the surface of catalyst. The catalyst was well characterized using FT-IR, PXRD, EDX, SEM,
13
C CPNMR, XPS and BET analysis. The catalytic activity of Hf@CCSO
3
H was evaluated for synthesis of γ-valerolactone-a potential fuel and green solvent. γ-valerolactone was synthesized from biomass derived levulinic acid by catalytic transfer hydrogenation using 150 wt% of catalyst at 200 ℃ for 24 h in isopropanol solvent as a hydrogen donor. 100% conversion of levulinic acid was achieved with an excellent yield of 96% with more than 99% selectivity of γ-valerolactone as evident from GC analysis. The method developed is simple, efficient and economical.
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| doi_str_mv | 10.1007/s10562-020-03119-w |
| format | Article |
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3
H) was prepared by simultaneous carbonization and sulfonation of readily available glucose, followed by incorporation of hafnium metal on the surface of catalyst. The catalyst was well characterized using FT-IR, PXRD, EDX, SEM,
13
C CPNMR, XPS and BET analysis. The catalytic activity of Hf@CCSO
3
H was evaluated for synthesis of γ-valerolactone-a potential fuel and green solvent. γ-valerolactone was synthesized from biomass derived levulinic acid by catalytic transfer hydrogenation using 150 wt% of catalyst at 200 ℃ for 24 h in isopropanol solvent as a hydrogen donor. 100% conversion of levulinic acid was achieved with an excellent yield of 96% with more than 99% selectivity of γ-valerolactone as evident from GC analysis. The method developed is simple, efficient and economical.
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3
H) was prepared by simultaneous carbonization and sulfonation of readily available glucose, followed by incorporation of hafnium metal on the surface of catalyst. The catalyst was well characterized using FT-IR, PXRD, EDX, SEM,
13
C CPNMR, XPS and BET analysis. The catalytic activity of Hf@CCSO
3
H was evaluated for synthesis of γ-valerolactone-a potential fuel and green solvent. γ-valerolactone was synthesized from biomass derived levulinic acid by catalytic transfer hydrogenation using 150 wt% of catalyst at 200 ℃ for 24 h in isopropanol solvent as a hydrogen donor. 100% conversion of levulinic acid was achieved with an excellent yield of 96% with more than 99% selectivity of γ-valerolactone as evident from GC analysis. The method developed is simple, efficient and economical.
Graphic Abstract</description><subject>Biomass</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Economic analysis</subject><subject>Fuels</subject><subject>Hafnium</subject><subject>Hydrogen storage</subject><subject>Hydrogenation</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Levulinic acid</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><subject>Selectivity</subject><subject>Solvents</subject><subject>X ray photoelectron spectroscopy</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kctKAzEYhQdR8PoCrgKuo7lNM9lZx2qFQgUvdBfSmaRGpokmaUufxcfwPXwmUyu4c_UfDt85_-IUxSlG5xghfhExKnsEIoIgohgLuNopDnDJCay4mOxmjTCGlJPJfnEY4ytCSHAsDoqPgTG2sdol8LB26UVHG4E34OsTPqtOB9-pJnmnYR_c-5Qxqzpws9AdMMHPwZX1cxUjuNbBLnULRnq56KyzDeg3tgVP0boZqFVS3Tpl8zEoF40OYLhug59pp5L1DoyXG8tc1vXDmA5_-ZiOiz2juqhPfu9R8XQzeKyHcDS-vav7I9hQLBIkFafTErOq6omeMXTKcUuUYIhUlPUqhg3BRLS40YwyLrJuRLtRiBnFTUuPirNt71vw7wsdk3z1i-DyS0kYYiUtmUCZIluqCT7GoI18C3auwlpiJDcjyO0IMo8gf0aQqxyi21DMsJvp8Ff9T-obRQ2L0A</recordid><startdate>20200701</startdate><enddate>20200701</enddate><creator>Jori, Popat K.</creator><creator>Jadhav, Vrushali H.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20200701</creationdate><title>Efficient Synthesis of γ-Valerolactone-A Potential Fuel from Biomass Derived Levulinic Acid Using Catalytic Transfer Hydrogenation Over Hf@CCSO3H Catalyst</title><author>Jori, Popat K. ; Jadhav, Vrushali H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-2873b51488696ff3b71d2a94028346841f2129d1ce43479129c9d347904fa7fd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Biomass</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Economic analysis</topic><topic>Fuels</topic><topic>Hafnium</topic><topic>Hydrogen storage</topic><topic>Hydrogenation</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Levulinic acid</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><topic>Selectivity</topic><topic>Solvents</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jori, Popat K.</creatorcontrib><creatorcontrib>Jadhav, Vrushali H.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jori, Popat K.</au><au>Jadhav, Vrushali H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Efficient Synthesis of γ-Valerolactone-A Potential Fuel from Biomass Derived Levulinic Acid Using Catalytic Transfer Hydrogenation Over Hf@CCSO3H Catalyst</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2020-07-01</date><risdate>2020</risdate><volume>150</volume><issue>7</issue><spage>2038</spage><epage>2044</epage><pages>2038-2044</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>A new hafnium based carbonaceous catalyst (Hf@CCSO
3
H) was prepared by simultaneous carbonization and sulfonation of readily available glucose, followed by incorporation of hafnium metal on the surface of catalyst. The catalyst was well characterized using FT-IR, PXRD, EDX, SEM,
13
C CPNMR, XPS and BET analysis. The catalytic activity of Hf@CCSO
3
H was evaluated for synthesis of γ-valerolactone-a potential fuel and green solvent. γ-valerolactone was synthesized from biomass derived levulinic acid by catalytic transfer hydrogenation using 150 wt% of catalyst at 200 ℃ for 24 h in isopropanol solvent as a hydrogen donor. 100% conversion of levulinic acid was achieved with an excellent yield of 96% with more than 99% selectivity of γ-valerolactone as evident from GC analysis. The method developed is simple, efficient and economical.
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| ispartof | Catalysis letters, 2020-07, Vol.150 (7), p.2038-2044 |
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| language | eng |
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| subjects | Biomass Catalysis Catalysts Catalytic activity Chemistry Chemistry and Materials Science Economic analysis Fuels Hafnium Hydrogen storage Hydrogenation Industrial Chemistry/Chemical Engineering Levulinic acid Organometallic Chemistry Physical Chemistry Selectivity Solvents X ray photoelectron spectroscopy |
| title | Efficient Synthesis of γ-Valerolactone-A Potential Fuel from Biomass Derived Levulinic Acid Using Catalytic Transfer Hydrogenation Over Hf@CCSO3H Catalyst |
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