A ascorbic acid-imprinted poly(o-phenylenediamine)/zeolite imidazole frameworks-67/carbon cloth for electrochemical sensing ascorbic acid

A flexible ascorbic acid (AA)-imprinted poly(o-phenylenediamine) (ploy(o-PD))/zeolite imidazole frameworks-67 (ZIF-67)/carbon cloth (CC) electrode was prepared for electrochemical sensing AA. The flexible AA-imprinted poly(o-PD)/ZIF-67/CC electrode was prepared by growing ZIF-67 on flexible CC, elec...

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Veröffentlicht in:Journal of materials science 2020-08, Vol.55 (22), p.9425-9435
Hauptverfasser: Guo, Yufei, Wang, Li, Xu, Lijuan, Peng, Canwei, Song, Yonghai
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container_issue 22
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container_title Journal of materials science
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creator Guo, Yufei
Wang, Li
Xu, Lijuan
Peng, Canwei
Song, Yonghai
description A flexible ascorbic acid (AA)-imprinted poly(o-phenylenediamine) (ploy(o-PD))/zeolite imidazole frameworks-67 (ZIF-67)/carbon cloth (CC) electrode was prepared for electrochemical sensing AA. The flexible AA-imprinted poly(o-PD)/ZIF-67/CC electrode was prepared by growing ZIF-67 on flexible CC, electropolymerization of o-PD with AA on ZIF-67/CC and eluting template molecules AA. The results showed that the spherical ZIF-67 crystals were arranged evenly and firmly on the fibers of CC surface. The diameter of spherical ZIF-67 crystals was approximately 500–600 nm, and the spherical ZIF-67 crystals catalyzed the oxidation of AA well. A layer of poly(o-PD) with AA-imprinted pores was covered on the ZIF-67/CC electrode, so the AA-imprinted poly(o-PD)/ZIF-67/CC electrode exhibited better selectivity toward AA detection and good stability. The molecularly imprinted sensor exhibits high sensitivity, and the sensitivity could reach 959.9 μA/mM −1  cm −2 , the detection limit was 0.019 μM, and the concentration range of AA was 0.057 μM–11.4 0 mM. The AA-imprinted poly(o-PD)/ZIF-67/CC electrode also showed higher stability and repeatability. The results proved that the spherical ZIF-67 crystals were good electrode materials for electrochemical AA biosensors.
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The flexible AA-imprinted poly(o-PD)/ZIF-67/CC electrode was prepared by growing ZIF-67 on flexible CC, electropolymerization of o-PD with AA on ZIF-67/CC and eluting template molecules AA. The results showed that the spherical ZIF-67 crystals were arranged evenly and firmly on the fibers of CC surface. The diameter of spherical ZIF-67 crystals was approximately 500–600 nm, and the spherical ZIF-67 crystals catalyzed the oxidation of AA well. A layer of poly(o-PD) with AA-imprinted pores was covered on the ZIF-67/CC electrode, so the AA-imprinted poly(o-PD)/ZIF-67/CC electrode exhibited better selectivity toward AA detection and good stability. The molecularly imprinted sensor exhibits high sensitivity, and the sensitivity could reach 959.9 μA/mM −1  cm −2 , the detection limit was 0.019 μM, and the concentration range of AA was 0.057 μM–11.4 0 mM. The AA-imprinted poly(o-PD)/ZIF-67/CC electrode also showed higher stability and repeatability. 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The flexible AA-imprinted poly(o-PD)/ZIF-67/CC electrode was prepared by growing ZIF-67 on flexible CC, electropolymerization of o-PD with AA on ZIF-67/CC and eluting template molecules AA. The results showed that the spherical ZIF-67 crystals were arranged evenly and firmly on the fibers of CC surface. The diameter of spherical ZIF-67 crystals was approximately 500–600 nm, and the spherical ZIF-67 crystals catalyzed the oxidation of AA well. A layer of poly(o-PD) with AA-imprinted pores was covered on the ZIF-67/CC electrode, so the AA-imprinted poly(o-PD)/ZIF-67/CC electrode exhibited better selectivity toward AA detection and good stability. The molecularly imprinted sensor exhibits high sensitivity, and the sensitivity could reach 959.9 μA/mM −1  cm −2 , the detection limit was 0.019 μM, and the concentration range of AA was 0.057 μM–11.4 0 mM. The AA-imprinted poly(o-PD)/ZIF-67/CC electrode also showed higher stability and repeatability. The results proved that the spherical ZIF-67 crystals were good electrode materials for electrochemical AA biosensors.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-020-04687-3</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0002-7889-2438</orcidid></addata></record>
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subjects Ascorbic acid
Biosensors
Carbon
Characterization and Evaluation of Materials
Chemistry and Materials Science
Classical Mechanics
Cloth
Composites & Nanocomposites
Crystallography and Scattering Methods
Crystals
Detectors
Electrode materials
Electrodes
Imidazole
Materials Science
Oxidation
Phenylenediamine
Polymer Sciences
Polymerization
Selectivity
Sensitivity
Solid Mechanics
Stability
Vitamin C
Zeolites
title A ascorbic acid-imprinted poly(o-phenylenediamine)/zeolite imidazole frameworks-67/carbon cloth for electrochemical sensing ascorbic acid
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