Flexible surface-supported MOF membrane via a convenient approach for efficient iodine adsorption

Flexible surface-supported MOF membranes were successfully prepared on cloth by a simple method and used for iodine adsorption for the first time. CuAceAd crystals were synthesized and deposited in situ on the cloth at 50 ℃. The synthesis of the membranes proved to be robust, stable and consistent,...

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Veröffentlicht in:Journal of radioanalytical and nuclear chemistry 2020-06, Vol.324 (3), p.1167-1177
Hauptverfasser: Li, Min, Yuan, Guoyuan, Zeng, Yang, Yang, Yuanyou, Liao, Jiali, Yang, Jijun, Liu, Ning
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container_end_page 1177
container_issue 3
container_start_page 1167
container_title Journal of radioanalytical and nuclear chemistry
container_volume 324
creator Li, Min
Yuan, Guoyuan
Zeng, Yang
Yang, Yuanyou
Liao, Jiali
Yang, Jijun
Liu, Ning
description Flexible surface-supported MOF membranes were successfully prepared on cloth by a simple method and used for iodine adsorption for the first time. CuAceAd crystals were synthesized and deposited in situ on the cloth at 50 ℃. The synthesis of the membranes proved to be robust, stable and consistent, as demonstrated by the SEM and XRD. The adsorption properties of the MOF membranes were measured in iodine vapor and iodine/cyclohexane solution, which showed a maximum iodine sorption capacity of 609.76 mg g −1 in the vapor and 144 mg g −1 in the solution, respectively. Additionally, the membranes displayed excellent regeneration ability. These results implied that the easy-obtained and environmental-friendly flexible MOF membranes have a great potential for engineering application in iodine adsorption.
doi_str_mv 10.1007/s10967-020-07135-3
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subjects Adsorption
Chemistry
Chemistry and Materials Science
Cloth
Cyclohexane
Diagnostic Radiology
Hadrons
Heavy Ions
Inorganic Chemistry
Iodine
Membranes
Nuclear Chemistry
Nuclear energy
Nuclear Physics
Physical Chemistry
Regeneration
Surface chemistry
title Flexible surface-supported MOF membrane via a convenient approach for efficient iodine adsorption
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