Ferrocenyl building block constructing porous organic polymer for gas capture and methyl violet adsorption
Ferrocene-based porous organic polymer (FcPOP) was constructed with ferrocene and porphyrin derivatives as building blocks via Schiff-base coupling. FcPOP was well characterized, and exhibited good thermal stability, high porosity, microporous structure, and homogeneous pore size distribution. Ferro...
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| Veröffentlicht in: | Journal of Central South University 2020-04, Vol.27 (4), p.1247-1261 |
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| container_title | Journal of Central South University |
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| creator | Huang, Jin Tan, Zhi-qiang Su, Hui-min Guo, Yi-wen Liu, Huan Liao, Bo Liu, Qing-quan |
| description | Ferrocene-based porous organic polymer (FcPOP) was constructed with ferrocene and porphyrin derivatives as building blocks via Schiff-base coupling. FcPOP was well characterized, and exhibited good thermal stability, high porosity, microporous structure, and homogeneous pore size distribution. Ferrocene blocks with highly electron-rich characteristics endowed FcPOP with excellent adsorption capacity of CO
2
and methyl violet. The kinetic study indicated adsorption of methyl violet onto FcPOP mainly complied with pesudo-second order model. The maximum adsorption capacity of FcPOP derived from Langmuir isotherm model reached up to 516 mg/g. More importantly, FcPOP could be easily regenerated and repeatedly employed for removal of methyl violet with high efficiency. Overall, FcPOP in the present study highlighted prospective applications in the field of gas capture and dyeing wastewater treatment. |
| doi_str_mv | 10.1007/s11771-020-4364-4 |
| format | Article |
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2
and methyl violet. The kinetic study indicated adsorption of methyl violet onto FcPOP mainly complied with pesudo-second order model. The maximum adsorption capacity of FcPOP derived from Langmuir isotherm model reached up to 516 mg/g. More importantly, FcPOP could be easily regenerated and repeatedly employed for removal of methyl violet with high efficiency. Overall, FcPOP in the present study highlighted prospective applications in the field of gas capture and dyeing wastewater treatment.</description><identifier>ISSN: 2095-2899</identifier><identifier>EISSN: 2227-5223</identifier><identifier>DOI: 10.1007/s11771-020-4364-4</identifier><language>eng</language><publisher>Changsha: Central South University</publisher><subject>Adsorption ; Construction ; Engineering ; Imines ; Metallic Materials ; Polymers ; Pore size distribution ; Porosity ; Structural stability ; Thermal stability ; Wastewater treatment</subject><ispartof>Journal of Central South University, 2020-04, Vol.27 (4), p.1247-1261</ispartof><rights>Central South University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2020</rights><rights>Central South University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-542a7cb69a1b8a8023690e435c732176618b44674cf2ce29629684933204db1b3</citedby><cites>FETCH-LOGICAL-c353t-542a7cb69a1b8a8023690e435c732176618b44674cf2ce29629684933204db1b3</cites><orcidid>0000-0003-3846-4268</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11771-020-4364-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11771-020-4364-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Huang, Jin</creatorcontrib><creatorcontrib>Tan, Zhi-qiang</creatorcontrib><creatorcontrib>Su, Hui-min</creatorcontrib><creatorcontrib>Guo, Yi-wen</creatorcontrib><creatorcontrib>Liu, Huan</creatorcontrib><creatorcontrib>Liao, Bo</creatorcontrib><creatorcontrib>Liu, Qing-quan</creatorcontrib><title>Ferrocenyl building block constructing porous organic polymer for gas capture and methyl violet adsorption</title><title>Journal of Central South University</title><addtitle>J. Cent. South Univ</addtitle><description>Ferrocene-based porous organic polymer (FcPOP) was constructed with ferrocene and porphyrin derivatives as building blocks via Schiff-base coupling. FcPOP was well characterized, and exhibited good thermal stability, high porosity, microporous structure, and homogeneous pore size distribution. Ferrocene blocks with highly electron-rich characteristics endowed FcPOP with excellent adsorption capacity of CO
2
and methyl violet. The kinetic study indicated adsorption of methyl violet onto FcPOP mainly complied with pesudo-second order model. The maximum adsorption capacity of FcPOP derived from Langmuir isotherm model reached up to 516 mg/g. More importantly, FcPOP could be easily regenerated and repeatedly employed for removal of methyl violet with high efficiency. Overall, FcPOP in the present study highlighted prospective applications in the field of gas capture and dyeing wastewater treatment.</description><subject>Adsorption</subject><subject>Construction</subject><subject>Engineering</subject><subject>Imines</subject><subject>Metallic Materials</subject><subject>Polymers</subject><subject>Pore size distribution</subject><subject>Porosity</subject><subject>Structural stability</subject><subject>Thermal stability</subject><subject>Wastewater treatment</subject><issn>2095-2899</issn><issn>2227-5223</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp1UMtKxDAUDaLgMM4HuAu4jubVpF3K4KgguNF1SNK0duwkNUmF-XszVHAlXO6Lc869HACuCb4lGMu7RIiUBGGKEWeCI34GVpRSiSpK2XnpcVMhWjfNJdikNBjMCBVMNGIF9jsXY7DOH0do5mFsB99DMwb7CW3wKcfZ5tNqCjHMCYbYaz_YMo7Hg4uwCxH2OkGrpzxHB7Vv4cHlj6L2PYTRZajbFOKUh-CvwEWnx-Q2v3UN3ncPb9sn9PL6-Ly9f0GWVSyjilMtrRGNJqbWNablUew4q6xklEghSG04F5LbjlpHG1Gi5g1jFPPWEMPW4GbRnWL4ml3Kah_m6MtJRTlmjFS8kgVFFpSNIaXoOjXF4aDjURGsTq6qxVVVXFUnV0taA7pwUsH63sU_5f9JP9MxepQ</recordid><startdate>20200401</startdate><enddate>20200401</enddate><creator>Huang, Jin</creator><creator>Tan, Zhi-qiang</creator><creator>Su, Hui-min</creator><creator>Guo, Yi-wen</creator><creator>Liu, Huan</creator><creator>Liao, Bo</creator><creator>Liu, Qing-quan</creator><general>Central South University</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-3846-4268</orcidid></search><sort><creationdate>20200401</creationdate><title>Ferrocenyl building block constructing porous organic polymer for gas capture and methyl violet adsorption</title><author>Huang, Jin ; Tan, Zhi-qiang ; Su, Hui-min ; Guo, Yi-wen ; Liu, Huan ; Liao, Bo ; Liu, Qing-quan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-542a7cb69a1b8a8023690e435c732176618b44674cf2ce29629684933204db1b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Adsorption</topic><topic>Construction</topic><topic>Engineering</topic><topic>Imines</topic><topic>Metallic Materials</topic><topic>Polymers</topic><topic>Pore size distribution</topic><topic>Porosity</topic><topic>Structural stability</topic><topic>Thermal stability</topic><topic>Wastewater treatment</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Huang, Jin</creatorcontrib><creatorcontrib>Tan, Zhi-qiang</creatorcontrib><creatorcontrib>Su, Hui-min</creatorcontrib><creatorcontrib>Guo, Yi-wen</creatorcontrib><creatorcontrib>Liu, Huan</creatorcontrib><creatorcontrib>Liao, Bo</creatorcontrib><creatorcontrib>Liu, Qing-quan</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of Central South University</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Huang, Jin</au><au>Tan, Zhi-qiang</au><au>Su, Hui-min</au><au>Guo, Yi-wen</au><au>Liu, Huan</au><au>Liao, Bo</au><au>Liu, Qing-quan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ferrocenyl building block constructing porous organic polymer for gas capture and methyl violet adsorption</atitle><jtitle>Journal of Central South University</jtitle><stitle>J. Cent. South Univ</stitle><date>2020-04-01</date><risdate>2020</risdate><volume>27</volume><issue>4</issue><spage>1247</spage><epage>1261</epage><pages>1247-1261</pages><issn>2095-2899</issn><eissn>2227-5223</eissn><abstract>Ferrocene-based porous organic polymer (FcPOP) was constructed with ferrocene and porphyrin derivatives as building blocks via Schiff-base coupling. FcPOP was well characterized, and exhibited good thermal stability, high porosity, microporous structure, and homogeneous pore size distribution. Ferrocene blocks with highly electron-rich characteristics endowed FcPOP with excellent adsorption capacity of CO
2
and methyl violet. The kinetic study indicated adsorption of methyl violet onto FcPOP mainly complied with pesudo-second order model. The maximum adsorption capacity of FcPOP derived from Langmuir isotherm model reached up to 516 mg/g. More importantly, FcPOP could be easily regenerated and repeatedly employed for removal of methyl violet with high efficiency. Overall, FcPOP in the present study highlighted prospective applications in the field of gas capture and dyeing wastewater treatment.</abstract><cop>Changsha</cop><pub>Central South University</pub><doi>10.1007/s11771-020-4364-4</doi><tpages>15</tpages><orcidid>https://orcid.org/0000-0003-3846-4268</orcidid></addata></record> |
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| subjects | Adsorption Construction Engineering Imines Metallic Materials Polymers Pore size distribution Porosity Structural stability Thermal stability Wastewater treatment |
| title | Ferrocenyl building block constructing porous organic polymer for gas capture and methyl violet adsorption |
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