Study of the Formation of Hyperbranched Polyacrylonitrile under the Action of a New Initiating System Based on Bicyclic Tertiary Amine and Ethylene Oxide

The polymerization of acrylonitrile under the action of the new initiating system 1.4-diazabicyclo[2.2.2]octane–ethylene oxide is studied. The polymerization initiated by this system is accompanied by the occurrence of intra- and intermolecular chain transfer to the polymer. It is found that cyclic...

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Veröffentlicht in:	Polymer science. Series B 2020-03, Vol.62 (2), p.85-93
Hauptverfasser:	Tarasov, A. E., Grishchuk, A. A., Karpov, S. V., Podval’naya, Yu. V., Chernyak, A. V., Garifulin, N. O., Badamshina, E. R.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chain transfer Chemistry Chemistry and Materials Science Ethers Ethylene oxide Molecular chains Polyacrylonitrile Polymer Sciences Polymerization Quantum chemistry Tetrahydrofuran Thermodynamic properties
Online-Zugang:	Volltext
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