Tetrazole Based Porous Metal Organic Framework (MOF): Topological Analysis and Dye Adsorption Properties
A tetrazole based metal organic framework [Cu(Metet)] n (MOF-1) (MetetH = 5-methyl-1H-tetrazole) has been prepared under solvothermal condition using sodium azide and nitrile in presence of CuCl 2 ·2H 2 O. The crystalline product thus obtained was characterized by spectral (FTIR, UV–visible and fluo...
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| Veröffentlicht in: | Journal of inorganic and organometallic polymers and materials 2020-06, Vol.30 (6), p.1935-1943 |
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| container_title | Journal of inorganic and organometallic polymers and materials |
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| creator | Mariyam, Abeda Shahid, M. I., Mantasha Khan, M. Shahnawaz Ahmad, M. Shahwaz |
| description | A tetrazole based metal organic framework [Cu(Metet)]
n
(MOF-1) (MetetH = 5-methyl-1H-tetrazole) has been prepared under solvothermal condition using sodium azide and nitrile in presence of CuCl
2
·2H
2
O. The crystalline product thus obtained was characterized by spectral (FTIR, UV–visible and fluorescence) and single crystal X-ray diffraction analysis. Tetrazole ligand is formed in situ by the reaction of azide and nitrile used. X-ray data confirm the tetrahedral geometry around the Cu(II) ion where all the four coordination sites are provided by four N of the four different ligand (Metet). MOF-1 has trigonal crystal system with R-3 m space group. Topological analysis of MOF-1 shows 4,4-c binodal net with uncommon
ptr
topology and stoichiometry, (4-c)(4-c). The detailed structural analysis reveals the porous nature of the MOF with channel of dimensions, R
f
= 0.6 Å and R
fi
= 2 Å. Further, the present MOF shows excellent adsorption properties towards organic dye, Methylene blue (MB) and thus can be employed as a good adsorbent for organic pollutants to remove MB from waste water. The possible rationale behind the dye adsorption is the porous nature of the MOF-1.
Graphic Abstract |
| doi_str_mv | 10.1007/s10904-019-01334-6 |
| format | Article |
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n
(MOF-1) (MetetH = 5-methyl-1H-tetrazole) has been prepared under solvothermal condition using sodium azide and nitrile in presence of CuCl
2
·2H
2
O. The crystalline product thus obtained was characterized by spectral (FTIR, UV–visible and fluorescence) and single crystal X-ray diffraction analysis. Tetrazole ligand is formed in situ by the reaction of azide and nitrile used. X-ray data confirm the tetrahedral geometry around the Cu(II) ion where all the four coordination sites are provided by four N of the four different ligand (Metet). MOF-1 has trigonal crystal system with R-3 m space group. Topological analysis of MOF-1 shows 4,4-c binodal net with uncommon
ptr
topology and stoichiometry, (4-c)(4-c). The detailed structural analysis reveals the porous nature of the MOF with channel of dimensions, R
f
= 0.6 Å and R
fi
= 2 Å. Further, the present MOF shows excellent adsorption properties towards organic dye, Methylene blue (MB) and thus can be employed as a good adsorbent for organic pollutants to remove MB from waste water. The possible rationale behind the dye adsorption is the porous nature of the MOF-1.
Graphic Abstract</description><identifier>ISSN: 1574-1443</identifier><identifier>EISSN: 1574-1451</identifier><identifier>DOI: 10.1007/s10904-019-01334-6</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Adsorption ; Chemistry ; Chemistry and Materials Science ; Copper ; Dyes ; Fluorescence ; Inorganic Chemistry ; Ligands ; Metal-organic frameworks ; Methylene blue ; Organic Chemistry ; Pollutants ; Polymer Sciences ; Single crystals ; Sodium azides ; Stoichiometry ; Structural analysis ; Tetrazoles ; Topology ; Wastewater treatment</subject><ispartof>Journal of inorganic and organometallic polymers and materials, 2020-06, Vol.30 (6), p.1935-1943</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019</rights><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-8afe780d12af996f6748f8f246b2060653dd72e9108536f02a380f52ffd9fbe73</citedby><cites>FETCH-LOGICAL-c356t-8afe780d12af996f6748f8f246b2060653dd72e9108536f02a380f52ffd9fbe73</cites><orcidid>0000-0003-3817-0286</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10904-019-01334-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10904-019-01334-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Mariyam, Abeda</creatorcontrib><creatorcontrib>Shahid, M.</creatorcontrib><creatorcontrib>I., Mantasha</creatorcontrib><creatorcontrib>Khan, M. Shahnawaz</creatorcontrib><creatorcontrib>Ahmad, M. Shahwaz</creatorcontrib><title>Tetrazole Based Porous Metal Organic Framework (MOF): Topological Analysis and Dye Adsorption Properties</title><title>Journal of inorganic and organometallic polymers and materials</title><addtitle>J Inorg Organomet Polym</addtitle><description>A tetrazole based metal organic framework [Cu(Metet)]
n
(MOF-1) (MetetH = 5-methyl-1H-tetrazole) has been prepared under solvothermal condition using sodium azide and nitrile in presence of CuCl
2
·2H
2
O. The crystalline product thus obtained was characterized by spectral (FTIR, UV–visible and fluorescence) and single crystal X-ray diffraction analysis. Tetrazole ligand is formed in situ by the reaction of azide and nitrile used. X-ray data confirm the tetrahedral geometry around the Cu(II) ion where all the four coordination sites are provided by four N of the four different ligand (Metet). MOF-1 has trigonal crystal system with R-3 m space group. Topological analysis of MOF-1 shows 4,4-c binodal net with uncommon
ptr
topology and stoichiometry, (4-c)(4-c). The detailed structural analysis reveals the porous nature of the MOF with channel of dimensions, R
f
= 0.6 Å and R
fi
= 2 Å. Further, the present MOF shows excellent adsorption properties towards organic dye, Methylene blue (MB) and thus can be employed as a good adsorbent for organic pollutants to remove MB from waste water. The possible rationale behind the dye adsorption is the porous nature of the MOF-1.
Graphic Abstract</description><subject>Adsorption</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Copper</subject><subject>Dyes</subject><subject>Fluorescence</subject><subject>Inorganic Chemistry</subject><subject>Ligands</subject><subject>Metal-organic frameworks</subject><subject>Methylene blue</subject><subject>Organic Chemistry</subject><subject>Pollutants</subject><subject>Polymer Sciences</subject><subject>Single crystals</subject><subject>Sodium azides</subject><subject>Stoichiometry</subject><subject>Structural analysis</subject><subject>Tetrazoles</subject><subject>Topology</subject><subject>Wastewater treatment</subject><issn>1574-1443</issn><issn>1574-1451</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kD1PwzAQhi0EEqXwB5gsscAQOH_ETthKoYDUqh3KbLmJXVJCHOxUqPx6DEGwMZzuhuc93T0InRK4JADyKhDIgSdA8liM8UTsoQFJJU8IT8n-78zZIToKYQPAMkjJAD0vTef1h6sNvtHBlHjhvNsGPDOdrvHcr3VTFXji9at5d_4Fn8_mk4trvHStq926KiI0anS9C1XAuinx7c7gURmcb7vKNXjhXWt8V5lwjA6sroM5-elD9DS5W44fkun8_nE8miYFS0WXZNoamUFJqLZ5LqyQPLOZpVysKAgQKStLSU1OIEuZsEB1fMSm1Noytysj2RCd9Xtb7962JnRq47Y-nhgU5dEPAyZppGhPFd6F4I1Vra9etd8pAurLqOqNqphQ30aViCHWh0KEm7Xxf6v_SX0Co2l4gA</recordid><startdate>20200601</startdate><enddate>20200601</enddate><creator>Mariyam, Abeda</creator><creator>Shahid, M.</creator><creator>I., Mantasha</creator><creator>Khan, M. Shahnawaz</creator><creator>Ahmad, M. Shahwaz</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-3817-0286</orcidid></search><sort><creationdate>20200601</creationdate><title>Tetrazole Based Porous Metal Organic Framework (MOF): Topological Analysis and Dye Adsorption Properties</title><author>Mariyam, Abeda ; Shahid, M. ; I., Mantasha ; Khan, M. Shahnawaz ; Ahmad, M. Shahwaz</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-8afe780d12af996f6748f8f246b2060653dd72e9108536f02a380f52ffd9fbe73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Adsorption</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Copper</topic><topic>Dyes</topic><topic>Fluorescence</topic><topic>Inorganic Chemistry</topic><topic>Ligands</topic><topic>Metal-organic frameworks</topic><topic>Methylene blue</topic><topic>Organic Chemistry</topic><topic>Pollutants</topic><topic>Polymer Sciences</topic><topic>Single crystals</topic><topic>Sodium azides</topic><topic>Stoichiometry</topic><topic>Structural analysis</topic><topic>Tetrazoles</topic><topic>Topology</topic><topic>Wastewater treatment</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mariyam, Abeda</creatorcontrib><creatorcontrib>Shahid, M.</creatorcontrib><creatorcontrib>I., Mantasha</creatorcontrib><creatorcontrib>Khan, M. Shahnawaz</creatorcontrib><creatorcontrib>Ahmad, M. Shahwaz</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mariyam, Abeda</au><au>Shahid, M.</au><au>I., Mantasha</au><au>Khan, M. Shahnawaz</au><au>Ahmad, M. Shahwaz</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tetrazole Based Porous Metal Organic Framework (MOF): Topological Analysis and Dye Adsorption Properties</atitle><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle><stitle>J Inorg Organomet Polym</stitle><date>2020-06-01</date><risdate>2020</risdate><volume>30</volume><issue>6</issue><spage>1935</spage><epage>1943</epage><pages>1935-1943</pages><issn>1574-1443</issn><eissn>1574-1451</eissn><abstract>A tetrazole based metal organic framework [Cu(Metet)]
n
(MOF-1) (MetetH = 5-methyl-1H-tetrazole) has been prepared under solvothermal condition using sodium azide and nitrile in presence of CuCl
2
·2H
2
O. The crystalline product thus obtained was characterized by spectral (FTIR, UV–visible and fluorescence) and single crystal X-ray diffraction analysis. Tetrazole ligand is formed in situ by the reaction of azide and nitrile used. X-ray data confirm the tetrahedral geometry around the Cu(II) ion where all the four coordination sites are provided by four N of the four different ligand (Metet). MOF-1 has trigonal crystal system with R-3 m space group. Topological analysis of MOF-1 shows 4,4-c binodal net with uncommon
ptr
topology and stoichiometry, (4-c)(4-c). The detailed structural analysis reveals the porous nature of the MOF with channel of dimensions, R
f
= 0.6 Å and R
fi
= 2 Å. Further, the present MOF shows excellent adsorption properties towards organic dye, Methylene blue (MB) and thus can be employed as a good adsorbent for organic pollutants to remove MB from waste water. The possible rationale behind the dye adsorption is the porous nature of the MOF-1.
Graphic Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10904-019-01334-6</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0003-3817-0286</orcidid></addata></record> |
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| subjects | Adsorption Chemistry Chemistry and Materials Science Copper Dyes Fluorescence Inorganic Chemistry Ligands Metal-organic frameworks Methylene blue Organic Chemistry Pollutants Polymer Sciences Single crystals Sodium azides Stoichiometry Structural analysis Tetrazoles Topology Wastewater treatment |
| title | Tetrazole Based Porous Metal Organic Framework (MOF): Topological Analysis and Dye Adsorption Properties |
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