Synthesis of an amino phosphinodiselenoic acid ester and β-amino diselenides employing P2Se5

The synthesis of a new class of amino phosphinodiselenoic acid ester and β-amino diselenides is conducted by employing a reaction between Nβ-protected aminoalkyl iodide and phosphorus pentaselenide (P2Se5) has been described. In the presence of protic solvents, amino phosphinodiselenoic acid esters...

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Veröffentlicht in:New journal of chemistry 2020-05, Vol.44 (18), p.7261-7264
Hauptverfasser: Kumar, L Roopesh, Sagar, N R, Divya, K, Madhu, C, Sureshbabu, Vommina V
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container_issue 18
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container_title New journal of chemistry
container_volume 44
creator Kumar, L Roopesh
Sagar, N R
Divya, K
Madhu, C
Sureshbabu, Vommina V
description The synthesis of a new class of amino phosphinodiselenoic acid ester and β-amino diselenides is conducted by employing a reaction between Nβ-protected aminoalkyl iodide and phosphorus pentaselenide (P2Se5) has been described. In the presence of protic solvents, amino phosphinodiselenoic acid esters were found to be the major products, whereas β-amino diselenides were formed exclusively when the reaction was carried out in polar aprotic solvents.
doi_str_mv 10.1039/d0nj00012d
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Esters
NMR
Nuclear magnetic resonance
Selenides
Solvents
Synthesis
title Synthesis of an amino phosphinodiselenoic acid ester and β-amino diselenides employing P2Se5
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