Solvent-free synthesis of 1-amidoalkyl-2-naphthols using magnetic nanoparticle-supported 2-(((4-(1-iminoethyl)phenyl)imino)methyl)phenol Cu (II) or Zn (II) Schiff base complexes

Two magnetic nanoparticle-supported 2-(((4-(1-iminoethyl)phenyl)imino)methyl)phenols were successfully synthesized, characterized, and applied in the one-pot three-component reaction of substituted benzaldehydes, 2-naphthol, and amides for synthesis of 1-amidoalkyl-2-naphthols. These three-component...

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Veröffentlicht in:Research on chemical intermediates 2020-06, Vol.46 (6), p.3145-3164
Hauptverfasser: Ghorbani, Fatemeh, Kiyani, Hamzeh, Pourmousavi, Seied Ali, Ajloo, Davood
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container_issue 6
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container_title Research on chemical intermediates
container_volume 46
creator Ghorbani, Fatemeh
Kiyani, Hamzeh
Pourmousavi, Seied Ali
Ajloo, Davood
description Two magnetic nanoparticle-supported 2-(((4-(1-iminoethyl)phenyl)imino)methyl)phenols were successfully synthesized, characterized, and applied in the one-pot three-component reaction of substituted benzaldehydes, 2-naphthol, and amides for synthesis of 1-amidoalkyl-2-naphthols. These three-component processes occurred under solvent-free reaction conditions at 80 °C. The magnetically recoverable supported Schiff base metal catalysts can be reused several times in the model reaction. The synthesized catalysts are also easily separated from the reaction mixture by applying an external magnet. This procedure offers the advantages of simple, operational procedure as well as no use of hazardous organic solvents.
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subjects Amides
Base metal
Catalysis
Catalysts
Chemical synthesis
Chemistry
Chemistry and Materials Science
Imines
Inorganic Chemistry
Nanoparticles
Naphthol
Phenols
Physical Chemistry
Solvents
title Solvent-free synthesis of 1-amidoalkyl-2-naphthols using magnetic nanoparticle-supported 2-(((4-(1-iminoethyl)phenyl)imino)methyl)phenol Cu (II) or Zn (II) Schiff base complexes
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