Solvent-free synthesis of 1-amidoalkyl-2-naphthols using magnetic nanoparticle-supported 2-(((4-(1-iminoethyl)phenyl)imino)methyl)phenol Cu (II) or Zn (II) Schiff base complexes
Two magnetic nanoparticle-supported 2-(((4-(1-iminoethyl)phenyl)imino)methyl)phenols were successfully synthesized, characterized, and applied in the one-pot three-component reaction of substituted benzaldehydes, 2-naphthol, and amides for synthesis of 1-amidoalkyl-2-naphthols. These three-component...
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Veröffentlicht in: | Research on chemical intermediates 2020-06, Vol.46 (6), p.3145-3164 |
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creator | Ghorbani, Fatemeh Kiyani, Hamzeh Pourmousavi, Seied Ali Ajloo, Davood |
description | Two magnetic nanoparticle-supported 2-(((4-(1-iminoethyl)phenyl)imino)methyl)phenols were successfully synthesized, characterized, and applied in the one-pot three-component reaction of substituted benzaldehydes, 2-naphthol, and amides for synthesis of 1-amidoalkyl-2-naphthols. These three-component processes occurred under solvent-free reaction conditions at 80 °C. The magnetically recoverable supported Schiff base metal catalysts can be reused several times in the model reaction. The synthesized catalysts are also easily separated from the reaction mixture by applying an external magnet. This procedure offers the advantages of simple, operational procedure as well as no use of hazardous organic solvents. |
doi_str_mv | 10.1007/s11164-020-04142-7 |
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These three-component processes occurred under solvent-free reaction conditions at 80 °C. The magnetically recoverable supported Schiff base metal catalysts can be reused several times in the model reaction. The synthesized catalysts are also easily separated from the reaction mixture by applying an external magnet. 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These three-component processes occurred under solvent-free reaction conditions at 80 °C. The magnetically recoverable supported Schiff base metal catalysts can be reused several times in the model reaction. The synthesized catalysts are also easily separated from the reaction mixture by applying an external magnet. This procedure offers the advantages of simple, operational procedure as well as no use of hazardous organic solvents.</description><subject>Amides</subject><subject>Base metal</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Imines</subject><subject>Inorganic Chemistry</subject><subject>Nanoparticles</subject><subject>Naphthol</subject><subject>Phenols</subject><subject>Physical Chemistry</subject><subject>Solvents</subject><issn>0922-6168</issn><issn>1568-5675</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9Uc1u1DAYtBCVWFpegJMlLtmDwT-xnRzRip-VKnFouXCxnPjLJsWxg51U7NvwDDxCn4zQIPXGaUajmfn0aRB6zehbRql-lxljqiSUU0JLVnKin6Edk6oiUmn5HO1ozTlRTFUv0Muc7yhlsqroDv2-if4ewky6BIDzOcw95CHj2GFG7Di4aP33syecBDv1cx99xksewgmP9hRgHlocbIiTTSv1QPIyTTHN4B5-cVIURUkKRoZxCBHm_uz3Uw9hhUdlPz5p0ePDgovjcY9jwt_CRm_afug63NgMuI3j5OEn5Ct00Vmf4dU_vERfP364PXwm118-HQ_vr0krpFof4qoBqR2USteqbpqGCmm1q1zTCOdk1XXCKl63rhZCu5JaCtoyKS1XgrFGXKI3W--U4o8F8mzu4pLCetJwUdeC1bqSq4tvrjbFnBN0ZkrDaNPZMGr-bmO2bcy6jXncxug1JLZQXs3hBOmp-j-pP2PNk_g</recordid><startdate>20200601</startdate><enddate>20200601</enddate><creator>Ghorbani, Fatemeh</creator><creator>Kiyani, Hamzeh</creator><creator>Pourmousavi, Seied Ali</creator><creator>Ajloo, Davood</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20200601</creationdate><title>Solvent-free synthesis of 1-amidoalkyl-2-naphthols using magnetic nanoparticle-supported 2-(((4-(1-iminoethyl)phenyl)imino)methyl)phenol Cu (II) or Zn (II) Schiff base complexes</title><author>Ghorbani, Fatemeh ; Kiyani, Hamzeh ; Pourmousavi, Seied Ali ; Ajloo, Davood</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-f26be57de467969bbb035a7d8dbb3dd58ff3a629cd9337d40a0e7a155a26311b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Amides</topic><topic>Base metal</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Imines</topic><topic>Inorganic Chemistry</topic><topic>Nanoparticles</topic><topic>Naphthol</topic><topic>Phenols</topic><topic>Physical Chemistry</topic><topic>Solvents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ghorbani, Fatemeh</creatorcontrib><creatorcontrib>Kiyani, Hamzeh</creatorcontrib><creatorcontrib>Pourmousavi, Seied Ali</creatorcontrib><creatorcontrib>Ajloo, Davood</creatorcontrib><collection>CrossRef</collection><jtitle>Research on chemical intermediates</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ghorbani, Fatemeh</au><au>Kiyani, Hamzeh</au><au>Pourmousavi, Seied Ali</au><au>Ajloo, Davood</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solvent-free synthesis of 1-amidoalkyl-2-naphthols using magnetic nanoparticle-supported 2-(((4-(1-iminoethyl)phenyl)imino)methyl)phenol Cu (II) or Zn (II) Schiff base complexes</atitle><jtitle>Research on chemical intermediates</jtitle><stitle>Res Chem Intermed</stitle><date>2020-06-01</date><risdate>2020</risdate><volume>46</volume><issue>6</issue><spage>3145</spage><epage>3164</epage><pages>3145-3164</pages><issn>0922-6168</issn><eissn>1568-5675</eissn><abstract>Two magnetic nanoparticle-supported 2-(((4-(1-iminoethyl)phenyl)imino)methyl)phenols were successfully synthesized, characterized, and applied in the one-pot three-component reaction of substituted benzaldehydes, 2-naphthol, and amides for synthesis of 1-amidoalkyl-2-naphthols. These three-component processes occurred under solvent-free reaction conditions at 80 °C. The magnetically recoverable supported Schiff base metal catalysts can be reused several times in the model reaction. The synthesized catalysts are also easily separated from the reaction mixture by applying an external magnet. This procedure offers the advantages of simple, operational procedure as well as no use of hazardous organic solvents.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s11164-020-04142-7</doi><tpages>20</tpages></addata></record> |
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subjects | Amides Base metal Catalysis Catalysts Chemical synthesis Chemistry Chemistry and Materials Science Imines Inorganic Chemistry Nanoparticles Naphthol Phenols Physical Chemistry Solvents |
title | Solvent-free synthesis of 1-amidoalkyl-2-naphthols using magnetic nanoparticle-supported 2-(((4-(1-iminoethyl)phenyl)imino)methyl)phenol Cu (II) or Zn (II) Schiff base complexes |
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