Identification of Impurities in High-Pure Arsine by Chromatography–Mass-Spectrometry
A method of chromatography–mass spectrometry is used to study the impurity composition of arsine synthesized by the reaction of arsenic chloride with sodium borohydride. Capillary adsorption columns with adsorbents modified silica and polytrimethylsilylpropine is used for the separation of impuritie...
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| Veröffentlicht in: | Journal of analytical chemistry (New York, N.Y.) N.Y.), 2020-05, Vol.75 (5), p.600-607 |
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| container_title | Journal of analytical chemistry (New York, N.Y.) |
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| creator | Sozin, A. Yu Chernova, O. Yu Sorochkina, T. G. Kotkov, A. P. Grishnova, N. D. Polezhaev, D. M. Pushkarev, G. V. Bulanova, A. A. |
| description | A method of chromatography–mass spectrometry is used to study the impurity composition of arsine synthesized by the reaction of arsenic chloride with sodium borohydride. Capillary adsorption columns with adsorbents modified silica and polytrimethylsilylpropine is used for the separation of impurities. Impurities are identified by comparing their mass spectra with the NIST database, published data, as well as by reconstructing their structures from fragment ions. Impurities of permanent gases; saturated and unsaturated hydrocarbons C
1
–C
6
; chlorinated, oxygenated, and aromatic hydrocarbons; volatile inorganic hydrides; and alkyl derivatives of arsine, trimethyl fluorosilane, carbon sulfur dioxide, and dimethyl sulfide are identified in arsine. Mass spectra of C
2
H
3
AsH
2
, CH
3
AsHC
2
H
5
, and C
2
H
5
As
2
H
3
impurities are obtained for the first time. |
| doi_str_mv | 10.1134/S1061934820050172 |
| format | Article |
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1
–C
6
; chlorinated, oxygenated, and aromatic hydrocarbons; volatile inorganic hydrides; and alkyl derivatives of arsine, trimethyl fluorosilane, carbon sulfur dioxide, and dimethyl sulfide are identified in arsine. Mass spectra of C
2
H
3
AsH
2
, CH
3
AsHC
2
H
5
, and C
2
H
5
As
2
H
3
impurities are obtained for the first time.</description><identifier>ISSN: 1061-9348</identifier><identifier>EISSN: 1608-3199</identifier><identifier>DOI: 10.1134/S1061934820050172</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Adsorption ; Analytical Chemistry ; Aromatic hydrocarbons ; Arsenic compounds ; Chemical synthesis ; Chemical tests and reagents ; Chemistry ; Chemistry and Materials Science ; Chromatography ; Database industry ; Dimethyl sulfide ; Hydrocarbons ; Impurities ; Ions ; Mass spectra ; Mass spectrometry ; Mass spectroscopy ; Scientific imaging ; Silicon dioxide ; Sulfur dioxide</subject><ispartof>Journal of analytical chemistry (New York, N.Y.), 2020-05, Vol.75 (5), p.600-607</ispartof><rights>Pleiades Publishing, Ltd. 2020</rights><rights>COPYRIGHT 2020 Springer</rights><rights>Pleiades Publishing, Ltd. 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c455t-21822e1ad635b40a6bebde0177ef16486c2a9dfb74929d55541616a5d804d5283</citedby><cites>FETCH-LOGICAL-c455t-21822e1ad635b40a6bebde0177ef16486c2a9dfb74929d55541616a5d804d5283</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1061934820050172$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1061934820050172$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Sozin, A. Yu</creatorcontrib><creatorcontrib>Chernova, O. Yu</creatorcontrib><creatorcontrib>Sorochkina, T. G.</creatorcontrib><creatorcontrib>Kotkov, A. P.</creatorcontrib><creatorcontrib>Grishnova, N. D.</creatorcontrib><creatorcontrib>Polezhaev, D. M.</creatorcontrib><creatorcontrib>Pushkarev, G. V.</creatorcontrib><creatorcontrib>Bulanova, A. A.</creatorcontrib><title>Identification of Impurities in High-Pure Arsine by Chromatography–Mass-Spectrometry</title><title>Journal of analytical chemistry (New York, N.Y.)</title><addtitle>J Anal Chem</addtitle><description>A method of chromatography–mass spectrometry is used to study the impurity composition of arsine synthesized by the reaction of arsenic chloride with sodium borohydride. Capillary adsorption columns with adsorbents modified silica and polytrimethylsilylpropine is used for the separation of impurities. Impurities are identified by comparing their mass spectra with the NIST database, published data, as well as by reconstructing their structures from fragment ions. Impurities of permanent gases; saturated and unsaturated hydrocarbons C
1
–C
6
; chlorinated, oxygenated, and aromatic hydrocarbons; volatile inorganic hydrides; and alkyl derivatives of arsine, trimethyl fluorosilane, carbon sulfur dioxide, and dimethyl sulfide are identified in arsine. Mass spectra of C
2
H
3
AsH
2
, CH
3
AsHC
2
H
5
, and C
2
H
5
As
2
H
3
impurities are obtained for the first time.</description><subject>Adsorption</subject><subject>Analytical Chemistry</subject><subject>Aromatic hydrocarbons</subject><subject>Arsenic compounds</subject><subject>Chemical synthesis</subject><subject>Chemical tests and reagents</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chromatography</subject><subject>Database industry</subject><subject>Dimethyl sulfide</subject><subject>Hydrocarbons</subject><subject>Impurities</subject><subject>Ions</subject><subject>Mass spectra</subject><subject>Mass spectrometry</subject><subject>Mass spectroscopy</subject><subject>Scientific imaging</subject><subject>Silicon dioxide</subject><subject>Sulfur dioxide</subject><issn>1061-9348</issn><issn>1608-3199</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp1kcFq3DAQhk1poGnaB-jN0FMOTjWSpbWOy9I2CykN3SRXIdtjr8JaciQZure8Q94wTxKFDbRLNuggMf_3SYMmy74AOQNg5bcVEAGSlRUlhBOY0XfZMQhSFQykfJ_OKS6e8w_ZxxBuCSGyAnGc3SxbtNF0ptHROJu7Ll8O4-RNNBhyY_Nz06-Ly8ljPvfBWMzrbb5Yezfo6Hqvx_X28f7hlw6hWI3YxBRg9NtP2VGnNwE_v-wn2fWP71eL8-Li98_lYn5RNCXnsaBQUYqgW8F4XRItaqxbTO3PsANRVqKhWrZdPSsllS3nvAQBQvO2ImXLacVOsq-7e0fv7iYMUd26ydv0pKJMSgYzyf-jer1BZWznotfNYEKj5oJSySpGSaKKA1SPFr3eOIudSeU9_uwAn1aLg2kOCqd7QmIi_o29nkJQy9WffRZ2bONdCB47NXozaL9VQNTzxNWriSeH7pyQWNuj__cZb0tPtTmqZw</recordid><startdate>20200501</startdate><enddate>20200501</enddate><creator>Sozin, A. Yu</creator><creator>Chernova, O. Yu</creator><creator>Sorochkina, T. G.</creator><creator>Kotkov, A. P.</creator><creator>Grishnova, N. D.</creator><creator>Polezhaev, D. M.</creator><creator>Pushkarev, G. V.</creator><creator>Bulanova, A. A.</creator><general>Pleiades Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope></search><sort><creationdate>20200501</creationdate><title>Identification of Impurities in High-Pure Arsine by Chromatography–Mass-Spectrometry</title><author>Sozin, A. Yu ; Chernova, O. Yu ; Sorochkina, T. G. ; Kotkov, A. P. ; Grishnova, N. D. ; Polezhaev, D. M. ; Pushkarev, G. V. ; Bulanova, A. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c455t-21822e1ad635b40a6bebde0177ef16486c2a9dfb74929d55541616a5d804d5283</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Adsorption</topic><topic>Analytical Chemistry</topic><topic>Aromatic hydrocarbons</topic><topic>Arsenic compounds</topic><topic>Chemical synthesis</topic><topic>Chemical tests and reagents</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chromatography</topic><topic>Database industry</topic><topic>Dimethyl sulfide</topic><topic>Hydrocarbons</topic><topic>Impurities</topic><topic>Ions</topic><topic>Mass spectra</topic><topic>Mass spectrometry</topic><topic>Mass spectroscopy</topic><topic>Scientific imaging</topic><topic>Silicon dioxide</topic><topic>Sulfur dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sozin, A. Yu</creatorcontrib><creatorcontrib>Chernova, O. Yu</creatorcontrib><creatorcontrib>Sorochkina, T. G.</creatorcontrib><creatorcontrib>Kotkov, A. P.</creatorcontrib><creatorcontrib>Grishnova, N. D.</creatorcontrib><creatorcontrib>Polezhaev, D. M.</creatorcontrib><creatorcontrib>Pushkarev, G. V.</creatorcontrib><creatorcontrib>Bulanova, A. A.</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sozin, A. Yu</au><au>Chernova, O. Yu</au><au>Sorochkina, T. G.</au><au>Kotkov, A. P.</au><au>Grishnova, N. D.</au><au>Polezhaev, D. M.</au><au>Pushkarev, G. V.</au><au>Bulanova, A. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Identification of Impurities in High-Pure Arsine by Chromatography–Mass-Spectrometry</atitle><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle><stitle>J Anal Chem</stitle><date>2020-05-01</date><risdate>2020</risdate><volume>75</volume><issue>5</issue><spage>600</spage><epage>607</epage><pages>600-607</pages><issn>1061-9348</issn><eissn>1608-3199</eissn><abstract>A method of chromatography–mass spectrometry is used to study the impurity composition of arsine synthesized by the reaction of arsenic chloride with sodium borohydride. Capillary adsorption columns with adsorbents modified silica and polytrimethylsilylpropine is used for the separation of impurities. Impurities are identified by comparing their mass spectra with the NIST database, published data, as well as by reconstructing their structures from fragment ions. Impurities of permanent gases; saturated and unsaturated hydrocarbons C
1
–C
6
; chlorinated, oxygenated, and aromatic hydrocarbons; volatile inorganic hydrides; and alkyl derivatives of arsine, trimethyl fluorosilane, carbon sulfur dioxide, and dimethyl sulfide are identified in arsine. Mass spectra of C
2
H
3
AsH
2
, CH
3
AsHC
2
H
5
, and C
2
H
5
As
2
H
3
impurities are obtained for the first time.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1061934820050172</doi><tpages>8</tpages></addata></record> |
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| subjects | Adsorption Analytical Chemistry Aromatic hydrocarbons Arsenic compounds Chemical synthesis Chemical tests and reagents Chemistry Chemistry and Materials Science Chromatography Database industry Dimethyl sulfide Hydrocarbons Impurities Ions Mass spectra Mass spectrometry Mass spectroscopy Scientific imaging Silicon dioxide Sulfur dioxide |
| title | Identification of Impurities in High-Pure Arsine by Chromatography–Mass-Spectrometry |
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