An unexpected reaction of cinobufagin analogues in the presence of PPh3/I2
An unexpected reaction of cinobufagin analogues in the presence of PPh 3 /I 2 in EtOAc at room temperature to obtain diene compounds has been described. The whole process is carried out under mild conditions and the desired products are formed in good yields. It provides a simple, effective, and nov...
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| Veröffentlicht in: | Monatshefte für Chemie 2020, Vol.151 (4), p.617-623 |
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| container_title | Monatshefte für Chemie |
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| creator | Zhou, Yang Zhang, Yanzhi Chen, Xubing Hou, Jinjun Long, Huali Zhang, Zijia Guo, Dean Lei, Min Wu, Wanying |
| description | An unexpected reaction of cinobufagin analogues in the presence of PPh
3
/I
2
in EtOAc at room temperature to obtain diene compounds has been described. The whole process is carried out under mild conditions and the desired products are formed in good yields. It provides a simple, effective, and novel reaction method for the synthesis of diene compounds from corresponding substrates.
Graphic abstract |
| doi_str_mv | 10.1007/s00706-020-02577-7 |
| format | Article |
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/I
2
in EtOAc at room temperature to obtain diene compounds has been described. The whole process is carried out under mild conditions and the desired products are formed in good yields. It provides a simple, effective, and novel reaction method for the synthesis of diene compounds from corresponding substrates.
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/I
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/I
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| language | eng |
| recordid | cdi_proquest_journals_2398857402 |
| source | SpringerNature Journals |
| subjects | Analytical Chemistry Chemical synthesis Chemistry Chemistry and Materials Science Chemistry/Food Science Inorganic Chemistry Organic Chemistry Original Paper Physical Chemistry Room temperature Substrates Theoretical and Computational Chemistry |
| title | An unexpected reaction of cinobufagin analogues in the presence of PPh3/I2 |
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