Kinetic Investigations of Quaternization Reactions of Poly[2‐(dimethylamino)ethyl methacrylate] with Diverse Alkyl Halides
Kinetic investigations of the quaternization reactions of poly[2‐(dimethylamino)ethyl methacrylate] (PDMAEMA) with alkyl halides (1‐iodobutane, 1‐iodoheptane, and 1‐iododecane) are carried out at different temperatures. For this purpose, a PDMAEMA (Mn = 17.8 kDa, Ð = 1.35) synthesized via reversible...
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| Veröffentlicht in: | Macromolecular chemistry and physics 2020-05, Vol.221 (9), p.n/a |
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| container_title | Macromolecular chemistry and physics |
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| creator | De Jesús‐Téllez, Marco A. Sánchez‐Cerrillo, Dulce M. Quintana‐Owen, Patricia Schubert, Ulrich S. Contreras‐López, David Guerrero‐Sánchez, Carlos |
| description | Kinetic investigations of the quaternization reactions of poly[2‐(dimethylamino)ethyl methacrylate] (PDMAEMA) with alkyl halides (1‐iodobutane, 1‐iodoheptane, and 1‐iododecane) are carried out at different temperatures. For this purpose, a PDMAEMA (Mn = 17.8 kDa, Ð = 1.35) synthesized via reversible addition fragmentation chain transfer polymerization is utilized. The progress of the quaternization reactions is followed by proton nuclear magnetic resonance. As expected, the rate of quaternization is higher with increasing temperature. The experimental data are used to determine the following kinetic parameters: order of the reaction, Arrhenius' pre‐exponential factor, and activation energy. To the best of knowledge, this is the first contribution that provides detailed kinetic data of the quaternization reactions on PDMAEMA.
Kinetic investigations of the quaternization reactions of poly[2‐(dimethylamino)ethyl methacrylate] with different alkyl halides are reported at several temperatures. These data can be utilized for optimizing reactions conditions, chemical structure, and properties of well‐defined cationic polymers. |
| doi_str_mv | 10.1002/macp.201900543 |
| format | Article |
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Kinetic investigations of the quaternization reactions of poly[2‐(dimethylamino)ethyl methacrylate] with different alkyl halides are reported at several temperatures. These data can be utilized for optimizing reactions conditions, chemical structure, and properties of well‐defined cationic polymers.</description><subject>Addition polymerization</subject><subject>antimicrobial polymers</subject><subject>cationic polymers</subject><subject>Chain transfer</subject><subject>Halides</subject><subject>kinetic parameters</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Order parameters</subject><subject>quaternized PDMAEMA</subject><subject>RAFT polymerization</subject><issn>1022-1352</issn><issn>1521-3935</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><sourceid>WIN</sourceid><recordid>eNqFkMtOwzAQRSMEEqWwZR2JDSxS_IiTeFmVRyuKKAhWCEWuPaYueRQ7bRXEgk_gG_kS0hbBktWM7pw7o7med4hRByNETnMhZx2CMEeIhXTLa2FGcEA5ZdtNjwgJMGVk19tzbooQShCPW977lSmgMtIfFAtwlXkWlSkL55fav52LCmxh3taSfwdC_s5GZVY_kq-Pz2NlcqgmdSZyU5Qn69ZfKULaRqzgyV-aauKfmQVYB343e2mAvsiMArfv7WiROTj4qW3v4eL8vtcPhjeXg153GEjKQxokitOQ8XEouJYskYoxInSSKCXHKFKJjjTQRIEOVYwjkJoBCgVTEYkk0iBo2zva7J3Z8nXevJlOy7ktmpMpoTxmYYxD2lCdDSVt6ZwFnc6syYWtU4zSVcLpKuH0N-HGwDeGpcmg_odOr7u90Z_3Gz8ihFU</recordid><startdate>202005</startdate><enddate>202005</enddate><creator>De Jesús‐Téllez, Marco A.</creator><creator>Sánchez‐Cerrillo, Dulce M.</creator><creator>Quintana‐Owen, Patricia</creator><creator>Schubert, Ulrich S.</creator><creator>Contreras‐López, David</creator><creator>Guerrero‐Sánchez, Carlos</creator><general>Wiley Subscription Services, Inc</general><scope>24P</scope><scope>WIN</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-2649-9589</orcidid></search><sort><creationdate>202005</creationdate><title>Kinetic Investigations of Quaternization Reactions of Poly[2‐(dimethylamino)ethyl methacrylate] with Diverse Alkyl Halides</title><author>De Jesús‐Téllez, Marco A. ; Sánchez‐Cerrillo, Dulce M. ; Quintana‐Owen, Patricia ; Schubert, Ulrich S. ; Contreras‐López, David ; Guerrero‐Sánchez, Carlos</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3943-8d93459b4a9fc58cd552af88ddcb06d8f6fe38def4d716ecf5e04a5d626c0fea3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Addition polymerization</topic><topic>antimicrobial polymers</topic><topic>cationic polymers</topic><topic>Chain transfer</topic><topic>Halides</topic><topic>kinetic parameters</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Order parameters</topic><topic>quaternized PDMAEMA</topic><topic>RAFT polymerization</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>De Jesús‐Téllez, Marco A.</creatorcontrib><creatorcontrib>Sánchez‐Cerrillo, Dulce M.</creatorcontrib><creatorcontrib>Quintana‐Owen, Patricia</creatorcontrib><creatorcontrib>Schubert, Ulrich S.</creatorcontrib><creatorcontrib>Contreras‐López, David</creatorcontrib><creatorcontrib>Guerrero‐Sánchez, Carlos</creatorcontrib><collection>Wiley Online Library (Open Access Collection)</collection><collection>Wiley Online Library (Open Access Collection)</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Macromolecular chemistry and physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>De Jesús‐Téllez, Marco A.</au><au>Sánchez‐Cerrillo, Dulce M.</au><au>Quintana‐Owen, Patricia</au><au>Schubert, Ulrich S.</au><au>Contreras‐López, David</au><au>Guerrero‐Sánchez, Carlos</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Kinetic Investigations of Quaternization Reactions of Poly[2‐(dimethylamino)ethyl methacrylate] with Diverse Alkyl Halides</atitle><jtitle>Macromolecular chemistry and physics</jtitle><date>2020-05</date><risdate>2020</risdate><volume>221</volume><issue>9</issue><epage>n/a</epage><issn>1022-1352</issn><eissn>1521-3935</eissn><abstract>Kinetic investigations of the quaternization reactions of poly[2‐(dimethylamino)ethyl methacrylate] (PDMAEMA) with alkyl halides (1‐iodobutane, 1‐iodoheptane, and 1‐iododecane) are carried out at different temperatures. For this purpose, a PDMAEMA (Mn = 17.8 kDa, Ð = 1.35) synthesized via reversible addition fragmentation chain transfer polymerization is utilized. The progress of the quaternization reactions is followed by proton nuclear magnetic resonance. As expected, the rate of quaternization is higher with increasing temperature. The experimental data are used to determine the following kinetic parameters: order of the reaction, Arrhenius' pre‐exponential factor, and activation energy. To the best of knowledge, this is the first contribution that provides detailed kinetic data of the quaternization reactions on PDMAEMA.
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| subjects | Addition polymerization antimicrobial polymers cationic polymers Chain transfer Halides kinetic parameters NMR Nuclear magnetic resonance Order parameters quaternized PDMAEMA RAFT polymerization |
| title | Kinetic Investigations of Quaternization Reactions of Poly[2‐(dimethylamino)ethyl methacrylate] with Diverse Alkyl Halides |
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