Clue on ocean redox condition from trace element and rare earth element (REE) composition of iron formation and carbonate rocks from the late Paleoproterozoic Morar Formation, Gwalior Group, central India

Trace element and rare earth element (REE) composition of iron formation and carbonate rocks from the Morar Formation, Gwalior Group, central India provides valuable information on the redox condition of late Paleoproterozoic Ocean. Facies types of iron formation suggest deposition in various oceani...

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Veröffentlicht in:Journal of Mineralogical and Petrological Sciences 2020, Vol.115(2), pp.175-191
Hauptverfasser: PAUL, Pritam P., CHAKRABORTY, Partha Pratim, SHIRAISHI, Fumito, DAS, Kaushik, KAMEI, Atsushi, BHATTACHARYA, Sourabh
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container_end_page 191
container_issue 2
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container_title Journal of Mineralogical and Petrological Sciences
container_volume 115
creator PAUL, Pritam P.
CHAKRABORTY, Partha Pratim
SHIRAISHI, Fumito
DAS, Kaushik
KAMEI, Atsushi
BHATTACHARYA, Sourabh
description Trace element and rare earth element (REE) composition of iron formation and carbonate rocks from the Morar Formation, Gwalior Group, central India provides valuable information on the redox condition of late Paleoproterozoic Ocean. Facies types of iron formation suggest deposition in various oceanic environments ranging from shoreface–beach to subtidal shelf settings, whereas carbonates belong to shallow and deep subtidal settings. (La/Nd)SN values between 0.53 and 23.60, MREE enrichment and small negative (0.69) to positive (1.46) Ce anomaly in iron formation suggest a stratified character for the Gwalior Sea with development of shallow transitional redoxcline. Whereas deep sea is interpreted as near anoxic and ferruginous, the shallow sea was not very high in dissolved oxygen (DO2) either. A suboxic to mild oxic shallow sea condition (DO2 ≥ 0.2 µM) is interpreted allowing Mn (II) oxidation and Ce sequestration. Carbonates, however, do not register any geochemical signature of redoxcline possibly because of the depositional setting either close to or below the redoxcline.
doi_str_mv 10.2465/jmps.191011
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subjects Anoxia
Carbonate rocks
Carbonates
Cerium
Composition
Deep sea
Dissolved oxygen
Gwalior Group
Iron
Isotopes
Manganese
Marine environment
Morar Formation
Oxidation
Oxidoreductions
Paleoproterozoic
Rare earth elements
Redoxcline
REE
Trace element
Trace elements
title Clue on ocean redox condition from trace element and rare earth element (REE) composition of iron formation and carbonate rocks from the late Paleoproterozoic Morar Formation, Gwalior Group, central India
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