Synthesis and Thermal Characterization of Polyurethanes Obtained from Cottonseed and Corn Oil-Based Polyols
The use of vegetable oils to replace fossil feedstock has become an area of opportunity and a priority for study in the field of polymer science. Vegetable oils are considered as renewable resources with high potential, low cost and full availability. The aim of this study is the synthesis of biobas...
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| Veröffentlicht in: | Journal of renewable materials 2016-06, Vol.4 (3), p.178-184 |
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| creator | Cruz-Aldaco, Karina Flores-Loyola, Erika Aguilar-González, Cristóbal Noé Burgos, Nuria Jiménez, Alfonso |
| description | The use of vegetable oils to replace fossil feedstock has become an area of opportunity and a priority for study in the field of polymer science. Vegetable oils are considered as renewable resources with high potential, low cost and full availability. The aim of this study is the synthesis
of biobased polyols from cottonseed oil (Gossypium barbadanse) and corn oil (Zea mays) as feedstock. Their synthesis was successfully performed, as can be concluded from the determination of their hydroxyl index as well as the structural and thermal characterization carried out
in this work. Polyurethanes from biobased polyols were synthesized with two different isocyanates (HDI and MDI) and variable polyol/isocyanate ratio and they were further characterized by infrared spectroscopy, thermogravimetric analysis, differential scanning calorimetry and scanning electron
microscopy, concluding that cottonseed and corn oils could be considered as valid alternatives for the synthesis of biobased polymeric materials. |
| doi_str_mv | 10.7569/JRM.2016.634107 |
| format | Article |
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of biobased polyols from cottonseed oil (Gossypium barbadanse) and corn oil (Zea mays) as feedstock. Their synthesis was successfully performed, as can be concluded from the determination of their hydroxyl index as well as the structural and thermal characterization carried out
in this work. Polyurethanes from biobased polyols were synthesized with two different isocyanates (HDI and MDI) and variable polyol/isocyanate ratio and they were further characterized by infrared spectroscopy, thermogravimetric analysis, differential scanning calorimetry and scanning electron
microscopy, concluding that cottonseed and corn oils could be considered as valid alternatives for the synthesis of biobased polymeric materials.</description><identifier>ISSN: 2164-6325</identifier><identifier>EISSN: 2164-6341</identifier><identifier>DOI: 10.7569/JRM.2016.634107</identifier><language>eng</language><publisher>Henderson: Tech Science Press</publisher><subject>Biobased Polyols ; Calorimetry ; Chemical synthesis ; Corn ; Corn Oil ; Cottonseed Oil ; Differential scanning calorimetry ; Infrared analysis ; Infrared spectroscopy ; Isocyanates ; Oils & fats ; Oilseeds ; Polymers ; Polyols ; Polyurethane resins ; Polyurethanes ; Raw materials ; Renewable resources ; Scanning electron microscopy ; Structural analysis ; Sustainable yield ; Thermodynamic properties ; Thermogravimetric analysis ; Vegetable Oils ; Vegetables</subject><ispartof>Journal of renewable materials, 2016-06, Vol.4 (3), p.178-184</ispartof><rights>2016. This work is licensed under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c472t-8fe058e7a23aea90a514a5712b25e7b2be1bb7c1df0e366a0398a2dd0ff897a93</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,27926,27927</link.rule.ids></links><search><creatorcontrib>Cruz-Aldaco, Karina</creatorcontrib><creatorcontrib>Flores-Loyola, Erika</creatorcontrib><creatorcontrib>Aguilar-González, Cristóbal Noé</creatorcontrib><creatorcontrib>Burgos, Nuria</creatorcontrib><creatorcontrib>Jiménez, Alfonso</creatorcontrib><title>Synthesis and Thermal Characterization of Polyurethanes Obtained from Cottonseed and Corn Oil-Based Polyols</title><title>Journal of renewable materials</title><addtitle>J Renew Mater</addtitle><description>The use of vegetable oils to replace fossil feedstock has become an area of opportunity and a priority for study in the field of polymer science. Vegetable oils are considered as renewable resources with high potential, low cost and full availability. The aim of this study is the synthesis
of biobased polyols from cottonseed oil (Gossypium barbadanse) and corn oil (Zea mays) as feedstock. Their synthesis was successfully performed, as can be concluded from the determination of their hydroxyl index as well as the structural and thermal characterization carried out
in this work. Polyurethanes from biobased polyols were synthesized with two different isocyanates (HDI and MDI) and variable polyol/isocyanate ratio and they were further characterized by infrared spectroscopy, thermogravimetric analysis, differential scanning calorimetry and scanning electron
microscopy, concluding that cottonseed and corn oils could be considered as valid alternatives for the synthesis of biobased polymeric materials.</description><subject>Biobased Polyols</subject><subject>Calorimetry</subject><subject>Chemical synthesis</subject><subject>Corn</subject><subject>Corn Oil</subject><subject>Cottonseed Oil</subject><subject>Differential scanning calorimetry</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Isocyanates</subject><subject>Oils & fats</subject><subject>Oilseeds</subject><subject>Polymers</subject><subject>Polyols</subject><subject>Polyurethane resins</subject><subject>Polyurethanes</subject><subject>Raw materials</subject><subject>Renewable resources</subject><subject>Scanning electron microscopy</subject><subject>Structural analysis</subject><subject>Sustainable yield</subject><subject>Thermodynamic properties</subject><subject>Thermogravimetric analysis</subject><subject>Vegetable Oils</subject><subject>Vegetables</subject><issn>2164-6325</issn><issn>2164-6341</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1kE1P3DAQhqOqlYqAc6-Wes7ij8ROTlUbUT60aKsCZ2uSjNlss_Zie5GWX1-HlHJiLp6x5n1GerLsC6MLVcr67Pr3zYJTJhdSFIyqD9kRZ7LIp-nj_56Xn7PTEDY0VUWppOIo-3N7sHGNYQgEbE_u1ui3MJJmDR66iH54hjg4S5whv9x42HuMa7AYyKqNMFjsifFuSxoXo7MB0zxhGuctWQ1j_gNC-pqSbgwn2ScDY8DTf-9xdv_z_K65zJeri6vm-zLvCsVjXhmkZYUKuACEmkLJCigV4y0vUbW8Rda2qmO9oSikBCrqCnjfU2OqWkEtjrOvM3fn3eMeQ9Qbt_c2ndRc1IozXkqZts7mrc67EDwavfPDFvxBM6onqTpJ1ZNUPUtNieWcGOwD2ghv2KHTMez05HnSrJ8KK1KUM1qnOCtYpXs0sB-jjuD1w7MOIuG-vYObWBu_nY_TuYrXRmjw8aURfwGvtJhn</recordid><startdate>20160607</startdate><enddate>20160607</enddate><creator>Cruz-Aldaco, Karina</creator><creator>Flores-Loyola, Erika</creator><creator>Aguilar-González, Cristóbal Noé</creator><creator>Burgos, Nuria</creator><creator>Jiménez, Alfonso</creator><general>Tech Science Press</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PATMY</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>PYCSY</scope></search><sort><creationdate>20160607</creationdate><title>Synthesis and Thermal Characterization of Polyurethanes Obtained from Cottonseed and Corn Oil-Based Polyols</title><author>Cruz-Aldaco, Karina ; 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Vegetable oils are considered as renewable resources with high potential, low cost and full availability. The aim of this study is the synthesis
of biobased polyols from cottonseed oil (Gossypium barbadanse) and corn oil (Zea mays) as feedstock. Their synthesis was successfully performed, as can be concluded from the determination of their hydroxyl index as well as the structural and thermal characterization carried out
in this work. Polyurethanes from biobased polyols were synthesized with two different isocyanates (HDI and MDI) and variable polyol/isocyanate ratio and they were further characterized by infrared spectroscopy, thermogravimetric analysis, differential scanning calorimetry and scanning electron
microscopy, concluding that cottonseed and corn oils could be considered as valid alternatives for the synthesis of biobased polymeric materials.</abstract><cop>Henderson</cop><pub>Tech Science Press</pub><doi>10.7569/JRM.2016.634107</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
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| source | Tech Science Press; EZB Electronic Journals Library |
| subjects | Biobased Polyols Calorimetry Chemical synthesis Corn Corn Oil Cottonseed Oil Differential scanning calorimetry Infrared analysis Infrared spectroscopy Isocyanates Oils & fats Oilseeds Polymers Polyols Polyurethane resins Polyurethanes Raw materials Renewable resources Scanning electron microscopy Structural analysis Sustainable yield Thermodynamic properties Thermogravimetric analysis Vegetable Oils Vegetables |
| title | Synthesis and Thermal Characterization of Polyurethanes Obtained from Cottonseed and Corn Oil-Based Polyols |
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