Diastereoselective olefin amidoacylation via photoredox PCET/nickel-dual catalysis: reaction scope and mechanistic insights

The selective 1,2-aminoacylation of olefins provides opportunities for the rapid construction of nitrogen-containing molecules. However, the lack of CO-free acylation reactions has limited their application. By using photoredox proton-coupled electron transfer (PCET)/Ni dual-catalysis, a highly regi...

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Veröffentlicht in:	Chemical science (Cambridge) 2020-01, Vol.11 (16), p.4131-4137
Hauptverfasser:	Zheng, Shuai, Zhang, Shuo-Qing, Saeednia, Borna, Zhou, Jiawang, Anna, Jessica M., Hong, Xin, Molander, Gary A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acylation Alkenes Aromatic compounds Carboxylic acids Catalysis Crystallography Electron transfer Nickel Stereoselectivity
Online-Zugang:	Volltext
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