A Biomimetic Synthesis of Racemic Dihydroanthracen‐1(2H)‐ones Using Sodium Borohydride in Water

Herein, we report a single step synthesis of racemic dihydroanthracenones by the reduction of anthraquinones using NaBH4 and Na2S2O4 in water. The racemic mixture is utilized to determine the enantiomeric excess for the chiral dihydroanthracenones reportedly synthesized by the chemoenzymatic reducti...

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Veröffentlicht in:	European journal of organic chemistry 2020-05, Vol.2020 (16), p.2425-2430
Hauptverfasser:	Mondal, Amit, Singh, Shailesh Kumar, Saha, Nirmal, Husain, Syed Masood
Format:	Artikel
Sprache:	eng
Schlagworte:	Anthraquinones Biomimetic synthesis Biomimetics Bisanthraquinones Dihydroanthracenones Enantioselectivity Natural products Reduction Sodium borohydride Sodium dithionite Synthesis
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