Nickel(ii) N-heterocyclic carbene complexes as efficient catalysts for the Suzuki—Miyaura reaction
Catalytic activity of nickel( ii ) and palladium( ii ) N -heterocyclic carbene (NHC) complexes derived from imidazole, benzimidazole, and 1,2,4-triazole was comparatively evaluated in the cross-coupling reactions of aryl halides with arylboronic acids. Readily available nickel bis-NHC complexes (NHC...
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| Veröffentlicht in: | Russian chemical bulletin 2020-04, Vol.69 (4), p.683-690 |
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| container_title | Russian chemical bulletin |
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| creator | Soliev, S. B. Astakhov, A. V. Pasyukov, D. V. Chernyshev, V. M. |
| description | Catalytic activity of nickel(
ii
) and palladium(
ii
)
N
-heterocyclic carbene (NHC) complexes derived from imidazole, benzimidazole, and 1,2,4-triazole was comparatively evaluated in the cross-coupling reactions of aryl halides with arylboronic acids. Readily available nickel bis-NHC complexes (NHC)
2
NiX
2
(X = Cl, Br, or I) exhibited the activity comparable to that of the structurally related palladium complexes and, consequently, can be applied as efficient catalysts for the Suzuki—Miyaura reaction. |
| doi_str_mv | 10.1007/s11172-020-2818-3 |
| format | Article |
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ii
) and palladium(
ii
)
N
-heterocyclic carbene (NHC) complexes derived from imidazole, benzimidazole, and 1,2,4-triazole was comparatively evaluated in the cross-coupling reactions of aryl halides with arylboronic acids. Readily available nickel bis-NHC complexes (NHC)
2
NiX
2
(X = Cl, Br, or I) exhibited the activity comparable to that of the structurally related palladium complexes and, consequently, can be applied as efficient catalysts for the Suzuki—Miyaura reaction.</description><identifier>ISSN: 1066-5285</identifier><identifier>EISSN: 1573-9171</identifier><identifier>DOI: 10.1007/s11172-020-2818-3</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Aromatic compounds ; Catalysts ; Catalytic activity ; Chemical reactions ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Cross coupling ; Full Articles ; Halides ; Imidazole ; Inorganic Chemistry ; Nickel ; Organic Chemistry ; Palladium ; Triazoles</subject><ispartof>Russian chemical bulletin, 2020-04, Vol.69 (4), p.683-690</ispartof><rights>Springer Science+Business Media LLC 2020</rights><rights>Springer Science+Business Media LLC 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-7a9056b2d4bf93bf83bc3ba07badade46b59afd5ce4b8231c6b91235df4ed2dc3</citedby><cites>FETCH-LOGICAL-c316t-7a9056b2d4bf93bf83bc3ba07badade46b59afd5ce4b8231c6b91235df4ed2dc3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11172-020-2818-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11172-020-2818-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Soliev, S. B.</creatorcontrib><creatorcontrib>Astakhov, A. V.</creatorcontrib><creatorcontrib>Pasyukov, D. V.</creatorcontrib><creatorcontrib>Chernyshev, V. M.</creatorcontrib><title>Nickel(ii) N-heterocyclic carbene complexes as efficient catalysts for the Suzuki—Miyaura reaction</title><title>Russian chemical bulletin</title><addtitle>Russ Chem Bull</addtitle><description>Catalytic activity of nickel(
ii
) and palladium(
ii
)
N
-heterocyclic carbene (NHC) complexes derived from imidazole, benzimidazole, and 1,2,4-triazole was comparatively evaluated in the cross-coupling reactions of aryl halides with arylboronic acids. Readily available nickel bis-NHC complexes (NHC)
2
NiX
2
(X = Cl, Br, or I) exhibited the activity comparable to that of the structurally related palladium complexes and, consequently, can be applied as efficient catalysts for the Suzuki—Miyaura reaction.</description><subject>Aromatic compounds</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Chemical reactions</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Cross coupling</subject><subject>Full Articles</subject><subject>Halides</subject><subject>Imidazole</subject><subject>Inorganic Chemistry</subject><subject>Nickel</subject><subject>Organic Chemistry</subject><subject>Palladium</subject><subject>Triazoles</subject><issn>1066-5285</issn><issn>1573-9171</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp1kMtKxDAUhosoOI4-gLuAG11Ec-ktSxm8wagLdR1yOXEy02nHpAXryofwCX0SO1Rw5eocON__H_iS5JiSc0pIcREppQXDhBHMSlpivpNMaFZwLGhBd4ed5DnOWJntJwcxLgkhrCzLSWIfvFlBder9GXrAC2ghNKY3lTfIqKChBmSa9aaCd4hIRQTOeeOhbodzq6o-thG5JqB2Aeip--hW_vvz6973qgsKBVCm9U19mOw5VUU4-p3T5OX66nl2i-ePN3ezyzk2nOYtLpQgWa6ZTbUTXLuSa8O1IoVWVllIc50J5WxmINUl49TkWlDGM-tSsMwaPk1Oxt5NaN46iK1cNl2oh5eScZEKlhciHyg6UiY0MQZwchP8WoVeUiK3MuUoUw4y5Vam5EOGjZk4sPUrhL_m_0M_n_N6Pw</recordid><startdate>20200401</startdate><enddate>20200401</enddate><creator>Soliev, S. B.</creator><creator>Astakhov, A. V.</creator><creator>Pasyukov, D. V.</creator><creator>Chernyshev, V. M.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20200401</creationdate><title>Nickel(ii) N-heterocyclic carbene complexes as efficient catalysts for the Suzuki—Miyaura reaction</title><author>Soliev, S. B. ; Astakhov, A. V. ; Pasyukov, D. V. ; Chernyshev, V. M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-7a9056b2d4bf93bf83bc3ba07badade46b59afd5ce4b8231c6b91235df4ed2dc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Aromatic compounds</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Chemical reactions</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Cross coupling</topic><topic>Full Articles</topic><topic>Halides</topic><topic>Imidazole</topic><topic>Inorganic Chemistry</topic><topic>Nickel</topic><topic>Organic Chemistry</topic><topic>Palladium</topic><topic>Triazoles</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Soliev, S. B.</creatorcontrib><creatorcontrib>Astakhov, A. V.</creatorcontrib><creatorcontrib>Pasyukov, D. V.</creatorcontrib><creatorcontrib>Chernyshev, V. M.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian chemical bulletin</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Soliev, S. B.</au><au>Astakhov, A. V.</au><au>Pasyukov, D. V.</au><au>Chernyshev, V. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nickel(ii) N-heterocyclic carbene complexes as efficient catalysts for the Suzuki—Miyaura reaction</atitle><jtitle>Russian chemical bulletin</jtitle><stitle>Russ Chem Bull</stitle><date>2020-04-01</date><risdate>2020</risdate><volume>69</volume><issue>4</issue><spage>683</spage><epage>690</epage><pages>683-690</pages><issn>1066-5285</issn><eissn>1573-9171</eissn><abstract>Catalytic activity of nickel(
ii
) and palladium(
ii
)
N
-heterocyclic carbene (NHC) complexes derived from imidazole, benzimidazole, and 1,2,4-triazole was comparatively evaluated in the cross-coupling reactions of aryl halides with arylboronic acids. Readily available nickel bis-NHC complexes (NHC)
2
NiX
2
(X = Cl, Br, or I) exhibited the activity comparable to that of the structurally related palladium complexes and, consequently, can be applied as efficient catalysts for the Suzuki—Miyaura reaction.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11172-020-2818-3</doi><tpages>8</tpages></addata></record> |
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| source | SpringerNature Journals |
| subjects | Aromatic compounds Catalysts Catalytic activity Chemical reactions Chemistry Chemistry and Materials Science Chemistry/Food Science Cross coupling Full Articles Halides Imidazole Inorganic Chemistry Nickel Organic Chemistry Palladium Triazoles |
| title | Nickel(ii) N-heterocyclic carbene complexes as efficient catalysts for the Suzuki—Miyaura reaction |
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