Scalable synthesis of hydroxymethyl alkylfuranoates as stable 2,5-furandicarboxylic acid precursors
Hydroxymethyl furanoic acid and its derivatives have been synthesized in high yields and purity from gluconolactone. The reaction sequence allows the recovery of reagents and the use of bio-friendly chemicals and solvents, and can easily be scaled up. The reaction product on a >100 gram scale can...
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| Veröffentlicht in: | Green chemistry : an international journal and green chemistry resource : GC 2020-04, Vol.22 (8), p.2399-242 |
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| container_title | Green chemistry : an international journal and green chemistry resource : GC |
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| creator | Pedersen, Martin Jæger Jurys, Arminas Pedersen, Christian Marcus |
| description | Hydroxymethyl furanoic acid and its derivatives have been synthesized in high yields and purity from gluconolactone. The reaction sequence allows the recovery of reagents and the use of bio-friendly chemicals and solvents, and can easily be scaled up. The reaction product on a >100 gram scale can be purified by a single purification method, such as distillation or precipitation. The overall yield is above 50%.
Hydroxymethyl furanoic acid and its derivatives have been synthesized in high yields and purity from gluconolactone. |
| doi_str_mv | 10.1039/d0gc00770f |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1463-9262 |
| ispartof | Green chemistry : an international journal and green chemistry resource : GC, 2020-04, Vol.22 (8), p.2399-242 |
| issn | 1463-9262 1463-9270 |
| language | eng |
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| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Distillation Gluconolactone Green chemistry Purification Reaction products Reagents |
| title | Scalable synthesis of hydroxymethyl alkylfuranoates as stable 2,5-furandicarboxylic acid precursors |
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