A bio-resourced mannitol phospholipid ammonium reactive flame retardant for cotton with efficient antiflaming and durability
Bio-resourced mannitol was employed to synthesize eco-friendly ammonium salt of mannitol hexaphosphate acid ester (AMHPE) by facile, solvent-free tactics. Limiting oxygen index (LOI) of cotton treated with 20–30% AMHPE reached 36.0–42.3% to obtain high-efficiency flame retardancy. After 50 launderin...
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| Veröffentlicht in: | Cellulose (London) 2020-05, Vol.27 (8), p.4803-4815 |
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| creator | Zhang, Fengxiu Lu, Yi Wan, Caiyan Tian, Peixiu Liu, Mingsheng Zhang, Guangxian |
| description | Bio-resourced mannitol was employed to synthesize eco-friendly ammonium salt of mannitol hexaphosphate acid ester (AMHPE) by facile, solvent-free tactics. Limiting oxygen index (LOI) of cotton treated with 20–30% AMHPE reached 36.0–42.3% to obtain high-efficiency flame retardancy. After 50 laundering cycles, the LOI value of 30% AMHPE treated cotton still retains an LOI value of 27.9%, revealing outstanding durability owing to new P–O–C covalent bonds formed bewteen –P = O(ONH
4
)
2
+
groups of AMHPE and cotton. The decomposition temperature of treated cotton was significantly lowered and its char residue was much higher than control cotton in N
2
. The PHRR and THR values of treated cotton were notably declined to 93.41% and 56.54% respectively, and the residual is 28 times higher by contrast. The combustion products and flame retardant mechanism of treated cotton were analyzed by TG-IR and cone calorimetry. These results indicate that AMHPE flame retardant cotton has acquired efficient flame retardancy, excellent durability and thermostability.
Graphic abstract
Solvent-free synthesis of bio-resourced N–P synergetic flame retardant possessing excellent flame retardancy, unexceptionable durability and thermostability to reduce cotton fire hazard. |
| doi_str_mv | 10.1007/s10570-020-03064-2 |
| format | Article |
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4
)
2
+
groups of AMHPE and cotton. The decomposition temperature of treated cotton was significantly lowered and its char residue was much higher than control cotton in N
2
. The PHRR and THR values of treated cotton were notably declined to 93.41% and 56.54% respectively, and the residual is 28 times higher by contrast. The combustion products and flame retardant mechanism of treated cotton were analyzed by TG-IR and cone calorimetry. These results indicate that AMHPE flame retardant cotton has acquired efficient flame retardancy, excellent durability and thermostability.
Graphic abstract
Solvent-free synthesis of bio-resourced N–P synergetic flame retardant possessing excellent flame retardancy, unexceptionable durability and thermostability to reduce cotton fire hazard.</description><identifier>ISSN: 0969-0239</identifier><identifier>EISSN: 1572-882X</identifier><identifier>DOI: 10.1007/s10570-020-03064-2</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Bioorganic Chemistry ; Ceramics ; Chemistry ; Chemistry and Materials Science ; Combustion products ; Composites ; Cotton ; Covalent bonds ; Durability ; Flame retardants ; Glass ; Mannitol ; Natural Materials ; Organic Chemistry ; Original Research ; Phospholipids ; Physical Chemistry ; Polymer Sciences ; Solvents ; Sustainable Development ; Tactics ; Thermal stability</subject><ispartof>Cellulose (London), 2020-05, Vol.27 (8), p.4803-4815</ispartof><rights>Springer Nature B.V. 2020</rights><rights>Springer Nature B.V. 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-ac4157c46d7ee57c62eef3ea8f4831fe773449ddf25655a6138d4bb02a2abd783</citedby><cites>FETCH-LOGICAL-c356t-ac4157c46d7ee57c62eef3ea8f4831fe773449ddf25655a6138d4bb02a2abd783</cites><orcidid>0000-0001-6811-2808</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10570-020-03064-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10570-020-03064-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Zhang, Fengxiu</creatorcontrib><creatorcontrib>Lu, Yi</creatorcontrib><creatorcontrib>Wan, Caiyan</creatorcontrib><creatorcontrib>Tian, Peixiu</creatorcontrib><creatorcontrib>Liu, Mingsheng</creatorcontrib><creatorcontrib>Zhang, Guangxian</creatorcontrib><title>A bio-resourced mannitol phospholipid ammonium reactive flame retardant for cotton with efficient antiflaming and durability</title><title>Cellulose (London)</title><addtitle>Cellulose</addtitle><description>Bio-resourced mannitol was employed to synthesize eco-friendly ammonium salt of mannitol hexaphosphate acid ester (AMHPE) by facile, solvent-free tactics. Limiting oxygen index (LOI) of cotton treated with 20–30% AMHPE reached 36.0–42.3% to obtain high-efficiency flame retardancy. After 50 laundering cycles, the LOI value of 30% AMHPE treated cotton still retains an LOI value of 27.9%, revealing outstanding durability owing to new P–O–C covalent bonds formed bewteen –P = O(ONH
4
)
2
+
groups of AMHPE and cotton. The decomposition temperature of treated cotton was significantly lowered and its char residue was much higher than control cotton in N
2
. The PHRR and THR values of treated cotton were notably declined to 93.41% and 56.54% respectively, and the residual is 28 times higher by contrast. The combustion products and flame retardant mechanism of treated cotton were analyzed by TG-IR and cone calorimetry. These results indicate that AMHPE flame retardant cotton has acquired efficient flame retardancy, excellent durability and thermostability.
Graphic abstract
Solvent-free synthesis of bio-resourced N–P synergetic flame retardant possessing excellent flame retardancy, unexceptionable durability and thermostability to reduce cotton fire hazard.</description><subject>Bioorganic Chemistry</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Combustion products</subject><subject>Composites</subject><subject>Cotton</subject><subject>Covalent bonds</subject><subject>Durability</subject><subject>Flame retardants</subject><subject>Glass</subject><subject>Mannitol</subject><subject>Natural Materials</subject><subject>Organic Chemistry</subject><subject>Original Research</subject><subject>Phospholipids</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Solvents</subject><subject>Sustainable Development</subject><subject>Tactics</subject><subject>Thermal stability</subject><issn>0969-0239</issn><issn>1572-882X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kE9LxDAQxYMouK5-AU8Bz9U0SZP2uCz-gwUvCt5K2kx2s7RNTVJlwQ9vtII3D0MmvPdmmB9Clzm5zgmRNyEnhSQZoakYETyjR2iRF5JmZUlfj9GCVKJKMqtO0VkIe0JIJWm-QJ8r3FiXeQhu8i1o3KthsNF1eNy5kKqzo9VY9b0b7NRjD6qN9h2w6VQP6RuV12qI2DiPWxejG_CHjTsMxtjWQlKSar_ddtimXmM9edXYzsbDOToxqgtw8fsu0cvd7fP6Ids83T-uV5usZYWImWp5OqXlQkuA1AgKYBio0vCS5QakZJxXWhtaiKJQImel5k1DqKKq0bJkS3Q1zx29e5sgxHqfrh3SyjoR4bysCiGTi86u1rsQPJh69LZX_lDnpP6mXM-U60S5_qGc0kvE5lBI5mEL_m_0P6kvp7mDAA</recordid><startdate>20200501</startdate><enddate>20200501</enddate><creator>Zhang, Fengxiu</creator><creator>Lu, Yi</creator><creator>Wan, Caiyan</creator><creator>Tian, Peixiu</creator><creator>Liu, Mingsheng</creator><creator>Zhang, Guangxian</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0001-6811-2808</orcidid></search><sort><creationdate>20200501</creationdate><title>A bio-resourced mannitol phospholipid ammonium reactive flame retardant for cotton with efficient antiflaming and durability</title><author>Zhang, Fengxiu ; Lu, Yi ; Wan, Caiyan ; Tian, Peixiu ; Liu, Mingsheng ; Zhang, Guangxian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-ac4157c46d7ee57c62eef3ea8f4831fe773449ddf25655a6138d4bb02a2abd783</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Bioorganic Chemistry</topic><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Combustion products</topic><topic>Composites</topic><topic>Cotton</topic><topic>Covalent bonds</topic><topic>Durability</topic><topic>Flame retardants</topic><topic>Glass</topic><topic>Mannitol</topic><topic>Natural Materials</topic><topic>Organic Chemistry</topic><topic>Original Research</topic><topic>Phospholipids</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Solvents</topic><topic>Sustainable Development</topic><topic>Tactics</topic><topic>Thermal stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Fengxiu</creatorcontrib><creatorcontrib>Lu, Yi</creatorcontrib><creatorcontrib>Wan, Caiyan</creatorcontrib><creatorcontrib>Tian, Peixiu</creatorcontrib><creatorcontrib>Liu, Mingsheng</creatorcontrib><creatorcontrib>Zhang, Guangxian</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Cellulose (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Fengxiu</au><au>Lu, Yi</au><au>Wan, Caiyan</au><au>Tian, Peixiu</au><au>Liu, Mingsheng</au><au>Zhang, Guangxian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A bio-resourced mannitol phospholipid ammonium reactive flame retardant for cotton with efficient antiflaming and durability</atitle><jtitle>Cellulose (London)</jtitle><stitle>Cellulose</stitle><date>2020-05-01</date><risdate>2020</risdate><volume>27</volume><issue>8</issue><spage>4803</spage><epage>4815</epage><pages>4803-4815</pages><issn>0969-0239</issn><eissn>1572-882X</eissn><abstract>Bio-resourced mannitol was employed to synthesize eco-friendly ammonium salt of mannitol hexaphosphate acid ester (AMHPE) by facile, solvent-free tactics. Limiting oxygen index (LOI) of cotton treated with 20–30% AMHPE reached 36.0–42.3% to obtain high-efficiency flame retardancy. After 50 laundering cycles, the LOI value of 30% AMHPE treated cotton still retains an LOI value of 27.9%, revealing outstanding durability owing to new P–O–C covalent bonds formed bewteen –P = O(ONH
4
)
2
+
groups of AMHPE and cotton. The decomposition temperature of treated cotton was significantly lowered and its char residue was much higher than control cotton in N
2
. The PHRR and THR values of treated cotton were notably declined to 93.41% and 56.54% respectively, and the residual is 28 times higher by contrast. The combustion products and flame retardant mechanism of treated cotton were analyzed by TG-IR and cone calorimetry. These results indicate that AMHPE flame retardant cotton has acquired efficient flame retardancy, excellent durability and thermostability.
Graphic abstract
Solvent-free synthesis of bio-resourced N–P synergetic flame retardant possessing excellent flame retardancy, unexceptionable durability and thermostability to reduce cotton fire hazard.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10570-020-03064-2</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0001-6811-2808</orcidid></addata></record> |
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| subjects | Bioorganic Chemistry Ceramics Chemistry Chemistry and Materials Science Combustion products Composites Cotton Covalent bonds Durability Flame retardants Glass Mannitol Natural Materials Organic Chemistry Original Research Phospholipids Physical Chemistry Polymer Sciences Solvents Sustainable Development Tactics Thermal stability |
| title | A bio-resourced mannitol phospholipid ammonium reactive flame retardant for cotton with efficient antiflaming and durability |
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