Electrodeposition of Fe–W Coatings from a Citric Bath with Use of Divided Electrolytic Cell
The use of the separated anode and cathode spaces during electrodeposition of the Fe–W alloy from a citrate bath (separation was carried out using a membrane with an average pore diameter of 0.74 μm) made it possible to significantly (up to 2 times) increase the current efficiency and deposition rat...
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| Veröffentlicht in: | Russian journal of applied chemistry 2020-03, Vol.93 (3), p.375-379 |
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| container_title | Russian journal of applied chemistry |
| container_volume | 93 |
| creator | Danil’chuk, V. V. Shul’man, A. I. Gotelyak, A. V. Yushchenko, S. P. Kovalenko, K. V. Dikusar, A. I. |
| description | The use of the separated anode and cathode spaces during electrodeposition of the Fe–W alloy from a citrate bath (separation was carried out using a membrane with an average pore diameter of 0.74 μm) made it possible to significantly (up to 2 times) increase the current efficiency and deposition rate when using a graphite anode and to increase the performance electrolyte (constancy of surface composition and surface microhardness up to 4 A h l
–1
). The dynamics of changes in the concentrations of the alloy-forming components of the electrolyte was studied and it was shown that it is defined not only by the electrodeposition of iron and tungsten into the alloy, but also by the absorption of tungstate by the anode. |
| doi_str_mv | 10.1134/S107042722003009X |
| format | Article |
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–1
). The dynamics of changes in the concentrations of the alloy-forming components of the electrolyte was studied and it was shown that it is defined not only by the electrodeposition of iron and tungsten into the alloy, but also by the absorption of tungstate by the anode.</description><identifier>ISSN: 1070-4272</identifier><identifier>EISSN: 1608-3296</identifier><identifier>DOI: 10.1134/S107042722003009X</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Anodes ; Applied Electrochemistry and Metal Corrosion Protection ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Coated electrodes ; Current efficiency ; Electrodeposition ; Electrolytes ; Electrolytic cells ; Ferrous alloys ; Industrial Chemistry/Chemical Engineering ; Iron ; Microhardness ; Tungsten</subject><ispartof>Russian journal of applied chemistry, 2020-03, Vol.93 (3), p.375-379</ispartof><rights>Pleiades Publishing, Ltd. 2020</rights><rights>Pleiades Publishing, Ltd. 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-f8381a6766a704889fe2a106dda4feff5cce56fb0c3aa0600cdccd8b8ea436973</citedby><cites>FETCH-LOGICAL-c353t-f8381a6766a704889fe2a106dda4feff5cce56fb0c3aa0600cdccd8b8ea436973</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S107042722003009X$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S107042722003009X$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Danil’chuk, V. V.</creatorcontrib><creatorcontrib>Shul’man, A. I.</creatorcontrib><creatorcontrib>Gotelyak, A. V.</creatorcontrib><creatorcontrib>Yushchenko, S. P.</creatorcontrib><creatorcontrib>Kovalenko, K. V.</creatorcontrib><creatorcontrib>Dikusar, A. I.</creatorcontrib><title>Electrodeposition of Fe–W Coatings from a Citric Bath with Use of Divided Electrolytic Cell</title><title>Russian journal of applied chemistry</title><addtitle>Russ J Appl Chem</addtitle><description>The use of the separated anode and cathode spaces during electrodeposition of the Fe–W alloy from a citrate bath (separation was carried out using a membrane with an average pore diameter of 0.74 μm) made it possible to significantly (up to 2 times) increase the current efficiency and deposition rate when using a graphite anode and to increase the performance electrolyte (constancy of surface composition and surface microhardness up to 4 A h l
–1
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–1
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| ispartof | Russian journal of applied chemistry, 2020-03, Vol.93 (3), p.375-379 |
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| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Anodes Applied Electrochemistry and Metal Corrosion Protection Chemistry Chemistry and Materials Science Chemistry/Food Science Coated electrodes Current efficiency Electrodeposition Electrolytes Electrolytic cells Ferrous alloys Industrial Chemistry/Chemical Engineering Iron Microhardness Tungsten |
| title | Electrodeposition of Fe–W Coatings from a Citric Bath with Use of Divided Electrolytic Cell |
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