Facile synthesis of nanoparticles titanium oxide as high-capacity and high-capability electrode for lithium-ion batteries
Anatase TiO 2 is prepared via a facile and eco-friendly synthesis method where titanium tetra isopropoxide and sodium alginate are used as the titanium precursor and templating agent, respectively. Structural characterization of the prepared sample via X-ray diffraction and Raman spectroscopies conf...
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| Veröffentlicht in: | Journal of applied electrochemistry 2020-05, Vol.50 (5), p.583-595 |
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| creator | El Ouardi, Karim Dahbi, Mouad Hakim, Charifa Güler, Mehmet Oğuz Akbulut, Hatem El Bouari, Abdeslam Saadoune, Ismael |
| description | Anatase TiO
2
is prepared via a facile and eco-friendly synthesis method where titanium tetra isopropoxide and sodium alginate are used as the titanium precursor and templating agent, respectively. Structural characterization of the prepared sample via X-ray diffraction and Raman spectroscopies confirm the formation of nanoparticles Titanium Oxide with anatase type structure without impurities. Further morphological characterization of the material showed the spherical shape of the particles. The prepared TiO
2
has been studied as an anode material for lithium-ion batteries. TiO
2
electrodes have delivered a reversible capacity of 266 mAh g
−1
, 275 mAh g
−1
with coulombic efficiencies of 70%, 75% during the first cycle under C/10 current rate for TiO
2
calcined at 300 °C and 450 °C, respectively. The activity of Ti
4+
/Ti
3+
redox couple during the lithiation/delithiation process was evidenced using X-ray Photoelectron Spectrometry. The high capacity retention was maintained for 100 cycles. The prepared nanoparticles TiO
2
has prodigious potential for large scale production of anode materials for lithium-ion batteries.
Graphic abstract |
| doi_str_mv | 10.1007/s10800-020-01419-y |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2392538251</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2392538251</sourcerecordid><originalsourceid>FETCH-LOGICAL-c356t-e0e6e12184617eac9995d84e92171e99bc5cec7344dd4d4804bbca023cc91d093</originalsourceid><addsrcrecordid>eNp9kMFKAzEURYMoWKs_4CrgOvqSyXSSpYhVoeBGwV3IZF7blHFSkxScvze1QncuwoPLuTdwCLnmcMsBmrvEQQEwEOVxyTUbT8iE141gSlXqlEwABGdK849zcpHSBgC0mMkJGefW-R5pGoe8xuQTDUs62CFsbcze9Zho9tkOfvdJw7fvkNpE1361Zs5uSzWP1A7dMWl9v8-wR5djKPgyRFqidRlgPgy0tTlj9JguydnS9gmv_u6UvM8f3x6e2eL16eXhfsFcVc8yQ8AZcsGVnPEGrdNa152SqAVvOGrdutqhayopu052UoFsW2dBVM5p3oGupuTmsLuN4WuHKZtN2MWhfGlEpUVdKVHzQokD5WJIKeLSbKP_tHE0HMxesTkoNkWx-VVsxlKqDqVU4GGF8Tj9T-sHet6Bxg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2392538251</pqid></control><display><type>article</type><title>Facile synthesis of nanoparticles titanium oxide as high-capacity and high-capability electrode for lithium-ion batteries</title><source>SpringerLink Journals - AutoHoldings</source><creator>El Ouardi, Karim ; Dahbi, Mouad ; Hakim, Charifa ; Güler, Mehmet Oğuz ; Akbulut, Hatem ; El Bouari, Abdeslam ; Saadoune, Ismael</creator><creatorcontrib>El Ouardi, Karim ; Dahbi, Mouad ; Hakim, Charifa ; Güler, Mehmet Oğuz ; Akbulut, Hatem ; El Bouari, Abdeslam ; Saadoune, Ismael</creatorcontrib><description>Anatase TiO
2
is prepared via a facile and eco-friendly synthesis method where titanium tetra isopropoxide and sodium alginate are used as the titanium precursor and templating agent, respectively. Structural characterization of the prepared sample via X-ray diffraction and Raman spectroscopies confirm the formation of nanoparticles Titanium Oxide with anatase type structure without impurities. Further morphological characterization of the material showed the spherical shape of the particles. The prepared TiO
2
has been studied as an anode material for lithium-ion batteries. TiO
2
electrodes have delivered a reversible capacity of 266 mAh g
−1
, 275 mAh g
−1
with coulombic efficiencies of 70%, 75% during the first cycle under C/10 current rate for TiO
2
calcined at 300 °C and 450 °C, respectively. The activity of Ti
4+
/Ti
3+
redox couple during the lithiation/delithiation process was evidenced using X-ray Photoelectron Spectrometry. The high capacity retention was maintained for 100 cycles. The prepared nanoparticles TiO
2
has prodigious potential for large scale production of anode materials for lithium-ion batteries.
Graphic abstract</description><identifier>ISSN: 0021-891X</identifier><identifier>EISSN: 1572-8838</identifier><identifier>DOI: 10.1007/s10800-020-01419-y</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Anatase ; Anodes ; Batteries ; Chemistry ; Chemistry and Materials Science ; Electrochemistry ; Electrode materials ; Electrodes ; Industrial Chemistry/Chemical Engineering ; Lithium ; Lithium-ion batteries ; Morphology ; Nanoparticles ; Photoelectrons ; Physical Chemistry ; Rechargeable batteries ; Research Article ; Sodium alginate ; Structural analysis ; Titanium ; Titanium dioxide ; Titanium oxides</subject><ispartof>Journal of applied electrochemistry, 2020-05, Vol.50 (5), p.583-595</ispartof><rights>Springer Nature B.V. 2020</rights><rights>Springer Nature B.V. 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-e0e6e12184617eac9995d84e92171e99bc5cec7344dd4d4804bbca023cc91d093</citedby><cites>FETCH-LOGICAL-c356t-e0e6e12184617eac9995d84e92171e99bc5cec7344dd4d4804bbca023cc91d093</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10800-020-01419-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10800-020-01419-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>El Ouardi, Karim</creatorcontrib><creatorcontrib>Dahbi, Mouad</creatorcontrib><creatorcontrib>Hakim, Charifa</creatorcontrib><creatorcontrib>Güler, Mehmet Oğuz</creatorcontrib><creatorcontrib>Akbulut, Hatem</creatorcontrib><creatorcontrib>El Bouari, Abdeslam</creatorcontrib><creatorcontrib>Saadoune, Ismael</creatorcontrib><title>Facile synthesis of nanoparticles titanium oxide as high-capacity and high-capability electrode for lithium-ion batteries</title><title>Journal of applied electrochemistry</title><addtitle>J Appl Electrochem</addtitle><description>Anatase TiO
2
is prepared via a facile and eco-friendly synthesis method where titanium tetra isopropoxide and sodium alginate are used as the titanium precursor and templating agent, respectively. Structural characterization of the prepared sample via X-ray diffraction and Raman spectroscopies confirm the formation of nanoparticles Titanium Oxide with anatase type structure without impurities. Further morphological characterization of the material showed the spherical shape of the particles. The prepared TiO
2
has been studied as an anode material for lithium-ion batteries. TiO
2
electrodes have delivered a reversible capacity of 266 mAh g
−1
, 275 mAh g
−1
with coulombic efficiencies of 70%, 75% during the first cycle under C/10 current rate for TiO
2
calcined at 300 °C and 450 °C, respectively. The activity of Ti
4+
/Ti
3+
redox couple during the lithiation/delithiation process was evidenced using X-ray Photoelectron Spectrometry. The high capacity retention was maintained for 100 cycles. The prepared nanoparticles TiO
2
has prodigious potential for large scale production of anode materials for lithium-ion batteries.
Graphic abstract</description><subject>Anatase</subject><subject>Anodes</subject><subject>Batteries</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Electrochemistry</subject><subject>Electrode materials</subject><subject>Electrodes</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Lithium</subject><subject>Lithium-ion batteries</subject><subject>Morphology</subject><subject>Nanoparticles</subject><subject>Photoelectrons</subject><subject>Physical Chemistry</subject><subject>Rechargeable batteries</subject><subject>Research Article</subject><subject>Sodium alginate</subject><subject>Structural analysis</subject><subject>Titanium</subject><subject>Titanium dioxide</subject><subject>Titanium oxides</subject><issn>0021-891X</issn><issn>1572-8838</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kMFKAzEURYMoWKs_4CrgOvqSyXSSpYhVoeBGwV3IZF7blHFSkxScvze1QncuwoPLuTdwCLnmcMsBmrvEQQEwEOVxyTUbT8iE141gSlXqlEwABGdK849zcpHSBgC0mMkJGefW-R5pGoe8xuQTDUs62CFsbcze9Zho9tkOfvdJw7fvkNpE1361Zs5uSzWP1A7dMWl9v8-wR5djKPgyRFqidRlgPgy0tTlj9JguydnS9gmv_u6UvM8f3x6e2eL16eXhfsFcVc8yQ8AZcsGVnPEGrdNa152SqAVvOGrdutqhayopu052UoFsW2dBVM5p3oGupuTmsLuN4WuHKZtN2MWhfGlEpUVdKVHzQokD5WJIKeLSbKP_tHE0HMxesTkoNkWx-VVsxlKqDqVU4GGF8Tj9T-sHet6Bxg</recordid><startdate>20200501</startdate><enddate>20200501</enddate><creator>El Ouardi, Karim</creator><creator>Dahbi, Mouad</creator><creator>Hakim, Charifa</creator><creator>Güler, Mehmet Oğuz</creator><creator>Akbulut, Hatem</creator><creator>El Bouari, Abdeslam</creator><creator>Saadoune, Ismael</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20200501</creationdate><title>Facile synthesis of nanoparticles titanium oxide as high-capacity and high-capability electrode for lithium-ion batteries</title><author>El Ouardi, Karim ; Dahbi, Mouad ; Hakim, Charifa ; Güler, Mehmet Oğuz ; Akbulut, Hatem ; El Bouari, Abdeslam ; Saadoune, Ismael</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-e0e6e12184617eac9995d84e92171e99bc5cec7344dd4d4804bbca023cc91d093</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Anatase</topic><topic>Anodes</topic><topic>Batteries</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Electrochemistry</topic><topic>Electrode materials</topic><topic>Electrodes</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Lithium</topic><topic>Lithium-ion batteries</topic><topic>Morphology</topic><topic>Nanoparticles</topic><topic>Photoelectrons</topic><topic>Physical Chemistry</topic><topic>Rechargeable batteries</topic><topic>Research Article</topic><topic>Sodium alginate</topic><topic>Structural analysis</topic><topic>Titanium</topic><topic>Titanium dioxide</topic><topic>Titanium oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>El Ouardi, Karim</creatorcontrib><creatorcontrib>Dahbi, Mouad</creatorcontrib><creatorcontrib>Hakim, Charifa</creatorcontrib><creatorcontrib>Güler, Mehmet Oğuz</creatorcontrib><creatorcontrib>Akbulut, Hatem</creatorcontrib><creatorcontrib>El Bouari, Abdeslam</creatorcontrib><creatorcontrib>Saadoune, Ismael</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of applied electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>El Ouardi, Karim</au><au>Dahbi, Mouad</au><au>Hakim, Charifa</au><au>Güler, Mehmet Oğuz</au><au>Akbulut, Hatem</au><au>El Bouari, Abdeslam</au><au>Saadoune, Ismael</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Facile synthesis of nanoparticles titanium oxide as high-capacity and high-capability electrode for lithium-ion batteries</atitle><jtitle>Journal of applied electrochemistry</jtitle><stitle>J Appl Electrochem</stitle><date>2020-05-01</date><risdate>2020</risdate><volume>50</volume><issue>5</issue><spage>583</spage><epage>595</epage><pages>583-595</pages><issn>0021-891X</issn><eissn>1572-8838</eissn><abstract>Anatase TiO
2
is prepared via a facile and eco-friendly synthesis method where titanium tetra isopropoxide and sodium alginate are used as the titanium precursor and templating agent, respectively. Structural characterization of the prepared sample via X-ray diffraction and Raman spectroscopies confirm the formation of nanoparticles Titanium Oxide with anatase type structure without impurities. Further morphological characterization of the material showed the spherical shape of the particles. The prepared TiO
2
has been studied as an anode material for lithium-ion batteries. TiO
2
electrodes have delivered a reversible capacity of 266 mAh g
−1
, 275 mAh g
−1
with coulombic efficiencies of 70%, 75% during the first cycle under C/10 current rate for TiO
2
calcined at 300 °C and 450 °C, respectively. The activity of Ti
4+
/Ti
3+
redox couple during the lithiation/delithiation process was evidenced using X-ray Photoelectron Spectrometry. The high capacity retention was maintained for 100 cycles. The prepared nanoparticles TiO
2
has prodigious potential for large scale production of anode materials for lithium-ion batteries.
Graphic abstract</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10800-020-01419-y</doi><tpages>13</tpages></addata></record> |
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| subjects | Anatase Anodes Batteries Chemistry Chemistry and Materials Science Electrochemistry Electrode materials Electrodes Industrial Chemistry/Chemical Engineering Lithium Lithium-ion batteries Morphology Nanoparticles Photoelectrons Physical Chemistry Rechargeable batteries Research Article Sodium alginate Structural analysis Titanium Titanium dioxide Titanium oxides |
| title | Facile synthesis of nanoparticles titanium oxide as high-capacity and high-capability electrode for lithium-ion batteries |
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