Niobium Monoxide Superstructures

The cubic and orthorhombic models of Nb 3 O 3 and Nb 6 O 6 superstructures of nonstoichiometric niobium monoxide Nb 0.75 O 0.75 with double defects have been proposed for the first time on the basis of the symmetry analysis and concepts of the channel of a disorder—order transition and the distribut...

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Veröffentlicht in:JETP letters 2020-02, Vol.111 (3), p.176-182
1. Verfasser: Gusev, A. I.
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description The cubic and orthorhombic models of Nb 3 O 3 and Nb 6 O 6 superstructures of nonstoichiometric niobium monoxide Nb 0.75 O 0.75 with double defects have been proposed for the first time on the basis of the symmetry analysis and concepts of the channel of a disorder—order transition and the distribution function. The channel of the disorder—order transition associated with the formation of considered model superstructures includes three superstructure vectors, which are the arms k 10 (1) , k 10 (2) and k 10 (3) of the k 10 Lifshitz star. The distribution functions of O and Nb atoms over the sites of the Nb 3 O 3 and Nb 6 O 6 superstructures have been calculated. It has been shown that a decrease in the temperature can be accompanied by the formation of the Nb 3 O 3 cubic, Nb 3 O 3 orthorhombic, and Nb 6 O 6 orthorhombic phases through successive disorder—order and order—order transitions.
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subjects Atomic
Biological and Medical Physics
Biophysics
Condensed Matter
Distribution functions
Molecular
Niobium oxides
Optical and Plasma Physics
Particle and Nuclear Physics
Physics
Physics and Astronomy
Quantum Information Technology
Solid State Physics
Spintronics
Superstructures
title Niobium Monoxide Superstructures
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