Pyrrolidines and piperidines bearing chiral tertiary alcohols by nickel-catalyzed enantioselective reductive cyclization of N-alkynones

Pyrrolidines and piperidines are important building blocks in organic synthesis. Numerous methods exist for constructing substituted pyrrolidines and piperidines. However, efficient syntheses of pyrrolidines and piperidines bearing chiral tertiary alcohols are limited. Here we report an efficient en...

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Veröffentlicht in:	Communications chemistry 2018-12, Vol.1 (1), Article 90
Hauptverfasser:	Liu, Guodu, Fu, Wenzhen, Mu, Xingye, Wu, Ting, Nie, Ming, Li, Kaidi, Xu, Xiaodong, Tang, Wenjun
Format:	Artikel
Sprache:	eng
Schlagworte:	639/638/403/935 639/638/549/972 639/638/77/883 Alcohol Alcohols Alkynes Bearing Carbonyls Catalysts Chemical reduction Chemistry Chemistry and Materials Science Chemistry/Food Science Enantiomers Ligands Nickel Piperidine Reagents Siloxanes Transition metals
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