Carbene-catalyzed asymmetric Friedel–Crafts alkylation-annulation sequence and rapid synthesis of indole-fused polycyclic alkaloids

Organocatalyzed asymmetric Friedel–Craft reactions have enabled the rapid construction of chiral molecules with highly enantioselectivity enriching the toolbox of chemists for producing complex substances. Here, we report N-heterocyclic carbene-catalyzed asymmetric indole Friedel–Crafts alkylation-a...

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Veröffentlicht in:	Communications chemistry 2019-07, Vol.2 (1), Article 85
Hauptverfasser:	Anwar, Muhammad, Yang, Shuang, Xu, Weici, Liu, Jinggong, Perveen, Saima, Kong, Xiangwen, Zehra, Syeda Tazeen, Fang, Xinqiang
Format:	Artikel
Sprache:	eng
Schlagworte:	639/638/77/883 639/638/77/889 Alkaloids Alkylation Asymmetry Chemical reactions Chemistry Chemistry and Materials Science Chemistry/Food Science Chemists Enantiomers Friedel-Crafts reaction Natural products Organic chemistry Reaction mechanisms Reaction products Stereoselectivity
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