Refractive Parameters and Band Energy Structure of K2SO4 Crystals Doped with Copper
Potassium sulfate crystals with a copper content of 1.7% were synthesized, and the dependence of their refractive indices n i ( λ ) and birefringence Δn i ( λ ) on their dispersion was studied. It was found that the dispersion n i ( λ ) in the spectral range of 300–700 nm is normal while introductio...
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| Veröffentlicht in: | Journal of applied spectroscopy 2020-03, Vol.87 (1), p.143-149 |
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| container_title | Journal of applied spectroscopy |
| container_volume | 87 |
| creator | Stadnyk, V. Yo Matviiv, R. B. Rudysh, M. Ya Brezvin, R. S. Shchepanskyi, P. A. Andrievskii, B. V. |
| description | Potassium sulfate crystals with a copper content of 1.7% were synthesized, and the dependence of their refractive indices
n
i
(
λ
) and birefringence
Δn
i
(
λ
) on their dispersion was studied. It was found that the dispersion
n
i
(
λ
) in the spectral range of 300–700 nm is normal while introduction of the impurity leads to a decrease of ni and of the electron polarizability. The band energy structure of potassium sulfate crystal doped with 1.7% of Cu
2+
was calculated. Introduction of the impurity leads to a decrease in the forbidden band width (E
g
= 5.3 and 4.9 eV for pure and doped crystals respectively). The optical functions of doped potassium sulfate crystals were calculated. |
| doi_str_mv | 10.1007/s10812-020-00975-7 |
| format | Article |
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n
i
(
λ
) and birefringence
Δn
i
(
λ
) on their dispersion was studied. It was found that the dispersion
n
i
(
λ
) in the spectral range of 300–700 nm is normal while introduction of the impurity leads to a decrease of ni and of the electron polarizability. The band energy structure of potassium sulfate crystal doped with 1.7% of Cu
2+
was calculated. Introduction of the impurity leads to a decrease in the forbidden band width (E
g
= 5.3 and 4.9 eV for pure and doped crystals respectively). The optical functions of doped potassium sulfate crystals were calculated.</description><identifier>ISSN: 0021-9037</identifier><identifier>EISSN: 1573-8647</identifier><identifier>DOI: 10.1007/s10812-020-00975-7</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Analytical Chemistry ; Atomic/Molecular Structure and Spectra ; Birefringence ; Copper ; Crystal structure ; Crystals ; Dispersion ; Doped crystals ; Forbidden bands ; Impurities ; Mathematical analysis ; Physics ; Physics and Astronomy ; Potassium ; Potassium sulfate ; Refractivity</subject><ispartof>Journal of applied spectroscopy, 2020-03, Vol.87 (1), p.143-149</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2020</rights><rights>Springer Science+Business Media, LLC, part of Springer Nature 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-b68ffc1f894bb9a453818c25d05e56a1127f856dfd5c48656ac4743cbb96c9993</citedby><cites>FETCH-LOGICAL-c319t-b68ffc1f894bb9a453818c25d05e56a1127f856dfd5c48656ac4743cbb96c9993</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10812-020-00975-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10812-020-00975-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Stadnyk, V. Yo</creatorcontrib><creatorcontrib>Matviiv, R. B.</creatorcontrib><creatorcontrib>Rudysh, M. Ya</creatorcontrib><creatorcontrib>Brezvin, R. S.</creatorcontrib><creatorcontrib>Shchepanskyi, P. A.</creatorcontrib><creatorcontrib>Andrievskii, B. V.</creatorcontrib><title>Refractive Parameters and Band Energy Structure of K2SO4 Crystals Doped with Copper</title><title>Journal of applied spectroscopy</title><addtitle>J Appl Spectrosc</addtitle><description>Potassium sulfate crystals with a copper content of 1.7% were synthesized, and the dependence of their refractive indices
n
i
(
λ
) and birefringence
Δn
i
(
λ
) on their dispersion was studied. It was found that the dispersion
n
i
(
λ
) in the spectral range of 300–700 nm is normal while introduction of the impurity leads to a decrease of ni and of the electron polarizability. The band energy structure of potassium sulfate crystal doped with 1.7% of Cu
2+
was calculated. Introduction of the impurity leads to a decrease in the forbidden band width (E
g
= 5.3 and 4.9 eV for pure and doped crystals respectively). The optical functions of doped potassium sulfate crystals were calculated.</description><subject>Analytical Chemistry</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Birefringence</subject><subject>Copper</subject><subject>Crystal structure</subject><subject>Crystals</subject><subject>Dispersion</subject><subject>Doped crystals</subject><subject>Forbidden bands</subject><subject>Impurities</subject><subject>Mathematical analysis</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Potassium</subject><subject>Potassium sulfate</subject><subject>Refractivity</subject><issn>0021-9037</issn><issn>1573-8647</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhoMoWKt_wFPAczQfm01y1LVVsVCxeg5pNqktdndNskr_vakrePMyAzPPOwMPAOcEXxKMxVUkWBKKMMUIYyU4EgdgRLhgSJaFOAQjjClBCjNxDE5i3OBMSYpHYPHsfDA2rT8dfDLBbF1yIULT1PBmXyaNC6sdXKTQ29QHB1sPH-liXsAq7GIy7xHetp2r4dc6vcGq7ToXTsGRzwt39tvH4HU6eanu0Wx-91Bdz5BlRCW0LKX3lnipiuVSmYIzSaSlvMbc8dIQQoWXvKx9zW0hyzyyhSiYzXBplVJsDC6Gu11oP3oXk960fWjyS02ZVJRTRUWm6EDZ0MYYnNddWG9N2GmC9V6eHuTpLE__yNP7EBtCMcPNyoW_0_-kvgFgqnDW</recordid><startdate>20200301</startdate><enddate>20200301</enddate><creator>Stadnyk, V. Yo</creator><creator>Matviiv, R. B.</creator><creator>Rudysh, M. Ya</creator><creator>Brezvin, R. S.</creator><creator>Shchepanskyi, P. A.</creator><creator>Andrievskii, B. V.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20200301</creationdate><title>Refractive Parameters and Band Energy Structure of K2SO4 Crystals Doped with Copper</title><author>Stadnyk, V. Yo ; Matviiv, R. B. ; Rudysh, M. Ya ; Brezvin, R. S. ; Shchepanskyi, P. A. ; Andrievskii, B. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-b68ffc1f894bb9a453818c25d05e56a1127f856dfd5c48656ac4743cbb96c9993</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Analytical Chemistry</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Birefringence</topic><topic>Copper</topic><topic>Crystal structure</topic><topic>Crystals</topic><topic>Dispersion</topic><topic>Doped crystals</topic><topic>Forbidden bands</topic><topic>Impurities</topic><topic>Mathematical analysis</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Potassium</topic><topic>Potassium sulfate</topic><topic>Refractivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Stadnyk, V. Yo</creatorcontrib><creatorcontrib>Matviiv, R. B.</creatorcontrib><creatorcontrib>Rudysh, M. Ya</creatorcontrib><creatorcontrib>Brezvin, R. S.</creatorcontrib><creatorcontrib>Shchepanskyi, P. A.</creatorcontrib><creatorcontrib>Andrievskii, B. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of applied spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Stadnyk, V. Yo</au><au>Matviiv, R. B.</au><au>Rudysh, M. Ya</au><au>Brezvin, R. S.</au><au>Shchepanskyi, P. A.</au><au>Andrievskii, B. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Refractive Parameters and Band Energy Structure of K2SO4 Crystals Doped with Copper</atitle><jtitle>Journal of applied spectroscopy</jtitle><stitle>J Appl Spectrosc</stitle><date>2020-03-01</date><risdate>2020</risdate><volume>87</volume><issue>1</issue><spage>143</spage><epage>149</epage><pages>143-149</pages><issn>0021-9037</issn><eissn>1573-8647</eissn><abstract>Potassium sulfate crystals with a copper content of 1.7% were synthesized, and the dependence of their refractive indices
n
i
(
λ
) and birefringence
Δn
i
(
λ
) on their dispersion was studied. It was found that the dispersion
n
i
(
λ
) in the spectral range of 300–700 nm is normal while introduction of the impurity leads to a decrease of ni and of the electron polarizability. The band energy structure of potassium sulfate crystal doped with 1.7% of Cu
2+
was calculated. Introduction of the impurity leads to a decrease in the forbidden band width (E
g
= 5.3 and 4.9 eV for pure and doped crystals respectively). The optical functions of doped potassium sulfate crystals were calculated.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10812-020-00975-7</doi><tpages>7</tpages></addata></record> |
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| issn | 0021-9037 1573-8647 |
| language | eng |
| recordid | cdi_proquest_journals_2389252927 |
| source | SpringerLink Journals |
| subjects | Analytical Chemistry Atomic/Molecular Structure and Spectra Birefringence Copper Crystal structure Crystals Dispersion Doped crystals Forbidden bands Impurities Mathematical analysis Physics Physics and Astronomy Potassium Potassium sulfate Refractivity |
| title | Refractive Parameters and Band Energy Structure of K2SO4 Crystals Doped with Copper |
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