Isolation and characterization of a lithiated pyridine - aggregation in the solid state and in solution

Pyridyllithiums are ubiquitous intermediates used for the electrophilic functionalization of pyridines. In this work, the isolation of a pyridyllithium is reported. Single crystal XRD revealed a dimer in the solid state. In THF solution it was identified as a monomer using DOSY NMR spectroscopy. Cal...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2020-04, Vol.56 (3), p.416-4163
Hauptverfasser:	Schmidlin, Nadja M. C, Scherer, Harald, Hoffmann, Anke, Böttcher, Tobias
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystallography Dimers NMR spectroscopy Pyridines Single crystals Solid state
Online-Zugang:	Volltext
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