Synthesis, Crystal Structures, and Thermal Properties of Protic Metal-Containing Ionic Liquids, Diethanolammonium Halometallates: (HOCH2CH2)2NH2FeCl4 and ((HOCH2CH2)2NH2)2CoCl4
Protic metal-containing ionic liquids with the diethanolammonium cation (HO–CH 2 –CH 2 ) 2 (DEAH + ) and anions and (DEAHFeCl 4 ( I ), (DEAH) 2 CoCl 4 ( II )) are synthesized. The crystal structures of compounds I and II are determined by X-ray structure analysis (CIF files CCDC nos. 1957208 ( I ) a...
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| Veröffentlicht in: | Russian journal of coordination chemistry 2020-04, Vol.46 (4), p.268-275 |
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| creator | Zakharov, M. A. Filatova, Yu. V. Bykov, M. A. Avramenko, N. V. Aslanov, L. A. |
| description | Protic metal-containing ionic liquids with the diethanolammonium cation (HO–CH
2
–CH
2
)
2
(DEAH
+
) and anions
and
(DEAHFeCl
4
(
I
), (DEAH)
2
CoCl
4
(
II
)) are synthesized. The crystal structures of compounds
I
and
II
are determined by X-ray structure analysis (CIF files CCDC nos. 1957208 (
I
) and 1957189 (
II
)). Compound
I
has a layered structure. The layer consists of the DEAH
+
cations with the disordered system of hydrogen bonds and attached
anions. The structure of compound
II
represents a three-dimensional framework consisting of the DEAH
+
cations and
anions linked by hydrogen bonds. The thermal analysis shows that the melting points of compounds
I
(45°С) and
II
(55°С) are lower than 100°С, the enthalpy of melting of compound
I
is higher than that of compound
II
, and the decomposition temperature of compound
II
(210°С) is higher than that of compound
I
(128°C). |
| doi_str_mv | 10.1134/S1070328420040077 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2388318478</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2388318478</sourcerecordid><originalsourceid>FETCH-LOGICAL-c2317-ec9376dc7be5edefce893962cb63c77dd2d89935eb152b4b50937028f6ba026f3</originalsourceid><addsrcrecordid>eNp1UUtLxDAQLqLg8wd4K3hRsJpH26TepD4qrK6w67mk6dSNtMmapIf9V_5Es64gIkJgMt9rYCaKjjG6wJimlzOMGKKEpwShFCHGtqI9nCOeUIr5dvgHOlnzu9G-c28IYYSyYi_6mK20X4BT7jwu7cp50cczb0fpRwsBE7qN5wuwQ8CfrVmC9QpcbLp155WMHyFYktJoL5RW-jV-MDrAE_U-qjYE3CjwC6FNL4YhMOMQV6I3w9rVCw_uKj6tpmVFwjsjTxW5g7JPv8ae_ibOSGkCdRjtdKJ3cPRdD6KXu9t5WSWT6f1DeT1JJKGYJSALyvJWsgYyaKGTwAta5EQ2OZWMtS1peVHQDBqckSZtMhT0iPAubwQieUcPopNN7tKa9xGcr9_MaHUYWRPKedhqynhQ4Y1KWuOcha5eWjUIu6oxqteHqf8cJnjIxuOCVr-C_Un-3_QJafmNuA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2388318478</pqid></control><display><type>article</type><title>Synthesis, Crystal Structures, and Thermal Properties of Protic Metal-Containing Ionic Liquids, Diethanolammonium Halometallates: (HOCH2CH2)2NH2FeCl4 and ((HOCH2CH2)2NH2)2CoCl4</title><source>SpringerLink Journals - AutoHoldings</source><creator>Zakharov, M. A. ; Filatova, Yu. V. ; Bykov, M. A. ; Avramenko, N. V. ; Aslanov, L. A.</creator><creatorcontrib>Zakharov, M. A. ; Filatova, Yu. V. ; Bykov, M. A. ; Avramenko, N. V. ; Aslanov, L. A.</creatorcontrib><description>Protic metal-containing ionic liquids with the diethanolammonium cation (HO–CH
2
–CH
2
)
2
(DEAH
+
) and anions
and
(DEAHFeCl
4
(
I
), (DEAH)
2
CoCl
4
(
II
)) are synthesized. The crystal structures of compounds
I
and
II
are determined by X-ray structure analysis (CIF files CCDC nos. 1957208 (
I
) and 1957189 (
II
)). Compound
I
has a layered structure. The layer consists of the DEAH
+
cations with the disordered system of hydrogen bonds and attached
anions. The structure of compound
II
represents a three-dimensional framework consisting of the DEAH
+
cations and
anions linked by hydrogen bonds. The thermal analysis shows that the melting points of compounds
I
(45°С) and
II
(55°С) are lower than 100°С, the enthalpy of melting of compound
I
is higher than that of compound
II
, and the decomposition temperature of compound
II
(210°С) is higher than that of compound
I
(128°C).</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S1070328420040077</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Anions ; Cations ; Chemical bonds ; Chemistry ; Chemistry and Materials Science ; Crystal structure ; Enthalpy ; Hydrogen bonds ; Inorganic Chemistry ; Ionic liquids ; Ions ; Melting points ; Physical Chemistry ; Structural analysis ; Thermal analysis ; Thermodynamic properties</subject><ispartof>Russian journal of coordination chemistry, 2020-04, Vol.46 (4), p.268-275</ispartof><rights>Pleiades Publishing, Ltd. 2020</rights><rights>Pleiades Publishing, Ltd. 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2317-ec9376dc7be5edefce893962cb63c77dd2d89935eb152b4b50937028f6ba026f3</citedby><cites>FETCH-LOGICAL-c2317-ec9376dc7be5edefce893962cb63c77dd2d89935eb152b4b50937028f6ba026f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070328420040077$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070328420040077$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Zakharov, M. A.</creatorcontrib><creatorcontrib>Filatova, Yu. V.</creatorcontrib><creatorcontrib>Bykov, M. A.</creatorcontrib><creatorcontrib>Avramenko, N. V.</creatorcontrib><creatorcontrib>Aslanov, L. A.</creatorcontrib><title>Synthesis, Crystal Structures, and Thermal Properties of Protic Metal-Containing Ionic Liquids, Diethanolammonium Halometallates: (HOCH2CH2)2NH2FeCl4 and ((HOCH2CH2)2NH2)2CoCl4</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>Protic metal-containing ionic liquids with the diethanolammonium cation (HO–CH
2
–CH
2
)
2
(DEAH
+
) and anions
and
(DEAHFeCl
4
(
I
), (DEAH)
2
CoCl
4
(
II
)) are synthesized. The crystal structures of compounds
I
and
II
are determined by X-ray structure analysis (CIF files CCDC nos. 1957208 (
I
) and 1957189 (
II
)). Compound
I
has a layered structure. The layer consists of the DEAH
+
cations with the disordered system of hydrogen bonds and attached
anions. The structure of compound
II
represents a three-dimensional framework consisting of the DEAH
+
cations and
anions linked by hydrogen bonds. The thermal analysis shows that the melting points of compounds
I
(45°С) and
II
(55°С) are lower than 100°С, the enthalpy of melting of compound
I
is higher than that of compound
II
, and the decomposition temperature of compound
II
(210°С) is higher than that of compound
I
(128°C).</description><subject>Anions</subject><subject>Cations</subject><subject>Chemical bonds</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystal structure</subject><subject>Enthalpy</subject><subject>Hydrogen bonds</subject><subject>Inorganic Chemistry</subject><subject>Ionic liquids</subject><subject>Ions</subject><subject>Melting points</subject><subject>Physical Chemistry</subject><subject>Structural analysis</subject><subject>Thermal analysis</subject><subject>Thermodynamic properties</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp1UUtLxDAQLqLg8wd4K3hRsJpH26TepD4qrK6w67mk6dSNtMmapIf9V_5Es64gIkJgMt9rYCaKjjG6wJimlzOMGKKEpwShFCHGtqI9nCOeUIr5dvgHOlnzu9G-c28IYYSyYi_6mK20X4BT7jwu7cp50cczb0fpRwsBE7qN5wuwQ8CfrVmC9QpcbLp155WMHyFYktJoL5RW-jV-MDrAE_U-qjYE3CjwC6FNL4YhMOMQV6I3w9rVCw_uKj6tpmVFwjsjTxW5g7JPv8ae_ibOSGkCdRjtdKJ3cPRdD6KXu9t5WSWT6f1DeT1JJKGYJSALyvJWsgYyaKGTwAta5EQ2OZWMtS1peVHQDBqckSZtMhT0iPAubwQieUcPopNN7tKa9xGcr9_MaHUYWRPKedhqynhQ4Y1KWuOcha5eWjUIu6oxqteHqf8cJnjIxuOCVr-C_Un-3_QJafmNuA</recordid><startdate>20200401</startdate><enddate>20200401</enddate><creator>Zakharov, M. A.</creator><creator>Filatova, Yu. V.</creator><creator>Bykov, M. A.</creator><creator>Avramenko, N. V.</creator><creator>Aslanov, L. A.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20200401</creationdate><title>Synthesis, Crystal Structures, and Thermal Properties of Protic Metal-Containing Ionic Liquids, Diethanolammonium Halometallates: (HOCH2CH2)2NH2FeCl4 and ((HOCH2CH2)2NH2)2CoCl4</title><author>Zakharov, M. A. ; Filatova, Yu. V. ; Bykov, M. A. ; Avramenko, N. V. ; Aslanov, L. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2317-ec9376dc7be5edefce893962cb63c77dd2d89935eb152b4b50937028f6ba026f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Anions</topic><topic>Cations</topic><topic>Chemical bonds</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystal structure</topic><topic>Enthalpy</topic><topic>Hydrogen bonds</topic><topic>Inorganic Chemistry</topic><topic>Ionic liquids</topic><topic>Ions</topic><topic>Melting points</topic><topic>Physical Chemistry</topic><topic>Structural analysis</topic><topic>Thermal analysis</topic><topic>Thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zakharov, M. A.</creatorcontrib><creatorcontrib>Filatova, Yu. V.</creatorcontrib><creatorcontrib>Bykov, M. A.</creatorcontrib><creatorcontrib>Avramenko, N. V.</creatorcontrib><creatorcontrib>Aslanov, L. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zakharov, M. A.</au><au>Filatova, Yu. V.</au><au>Bykov, M. A.</au><au>Avramenko, N. V.</au><au>Aslanov, L. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, Crystal Structures, and Thermal Properties of Protic Metal-Containing Ionic Liquids, Diethanolammonium Halometallates: (HOCH2CH2)2NH2FeCl4 and ((HOCH2CH2)2NH2)2CoCl4</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2020-04-01</date><risdate>2020</risdate><volume>46</volume><issue>4</issue><spage>268</spage><epage>275</epage><pages>268-275</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>Protic metal-containing ionic liquids with the diethanolammonium cation (HO–CH
2
–CH
2
)
2
(DEAH
+
) and anions
and
(DEAHFeCl
4
(
I
), (DEAH)
2
CoCl
4
(
II
)) are synthesized. The crystal structures of compounds
I
and
II
are determined by X-ray structure analysis (CIF files CCDC nos. 1957208 (
I
) and 1957189 (
II
)). Compound
I
has a layered structure. The layer consists of the DEAH
+
cations with the disordered system of hydrogen bonds and attached
anions. The structure of compound
II
represents a three-dimensional framework consisting of the DEAH
+
cations and
anions linked by hydrogen bonds. The thermal analysis shows that the melting points of compounds
I
(45°С) and
II
(55°С) are lower than 100°С, the enthalpy of melting of compound
I
is higher than that of compound
II
, and the decomposition temperature of compound
II
(210°С) is higher than that of compound
I
(128°C).</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070328420040077</doi><tpages>8</tpages></addata></record> |
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| ispartof | Russian journal of coordination chemistry, 2020-04, Vol.46 (4), p.268-275 |
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| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Anions Cations Chemical bonds Chemistry Chemistry and Materials Science Crystal structure Enthalpy Hydrogen bonds Inorganic Chemistry Ionic liquids Ions Melting points Physical Chemistry Structural analysis Thermal analysis Thermodynamic properties |
| title | Synthesis, Crystal Structures, and Thermal Properties of Protic Metal-Containing Ionic Liquids, Diethanolammonium Halometallates: (HOCH2CH2)2NH2FeCl4 and ((HOCH2CH2)2NH2)2CoCl4 |
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