Formation of the Porous Structure of Fossil Coals upon Alkaline Activation with Thermal Shock
The porous structure of activated carbons (ACs) formed by fossil coals of different ranks upon alkaline activation with thermal shock (KOH, 800°C) was studied. It was established that the specific surface area of ACs decreased from 2012 to 818 m 2 /g, the pore volume decreased from 1.088 to 0.269 cm...
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Veröffentlicht in: | Solid fuel chemistry 2020-03, Vol.54 (2), p.79-86 |
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description | The porous structure of activated carbons (ACs) formed by fossil coals of different ranks upon alkaline activation with thermal shock (KOH, 800°C) was studied. It was established that the specific surface area of ACs decreased from 2012 to 818 m
2
/g, the pore volume decreased from 1.088 to 0.269 cm
3
/g, and the fraction of micropores linearly increased from 0.64 to 0.92 as the C
daf
of the test samples increased from 70.4 to 95.6%. It was shown that an increase in coal rank was responsible for the transition from a micro–mesoporous material to a nanoporous AC. |
doi_str_mv | 10.3103/S0361521920020068 |
format | Article |
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2
/g, the pore volume decreased from 1.088 to 0.269 cm
3
/g, and the fraction of micropores linearly increased from 0.64 to 0.92 as the C
daf
of the test samples increased from 70.4 to 95.6%. It was shown that an increase in coal rank was responsible for the transition from a micro–mesoporous material to a nanoporous AC.</description><identifier>ISSN: 0361-5219</identifier><identifier>EISSN: 1934-8029</identifier><identifier>DOI: 10.3103/S0361521920020068</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Activated carbon ; Activation ; Chemistry ; Chemistry and Materials Science ; Physical Chemistry ; Thermal shock</subject><ispartof>Solid fuel chemistry, 2020-03, Vol.54 (2), p.79-86</ispartof><rights>Allerton Press, Inc. 2020</rights><rights>Allerton Press, Inc. 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-674105364adb9cbd063518804ce58b1641e834976d056b42044c94670a8c3d683</citedby><cites>FETCH-LOGICAL-c316t-674105364adb9cbd063518804ce58b1641e834976d056b42044c94670a8c3d683</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.3103/S0361521920020068$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.3103/S0361521920020068$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Kucherenko, V. A.</creatorcontrib><creatorcontrib>Tamarkina, Yu. V.</creatorcontrib><creatorcontrib>Sabierova, V. A.</creatorcontrib><title>Formation of the Porous Structure of Fossil Coals upon Alkaline Activation with Thermal Shock</title><title>Solid fuel chemistry</title><addtitle>Solid Fuel Chem</addtitle><description>The porous structure of activated carbons (ACs) formed by fossil coals of different ranks upon alkaline activation with thermal shock (KOH, 800°C) was studied. It was established that the specific surface area of ACs decreased from 2012 to 818 m
2
/g, the pore volume decreased from 1.088 to 0.269 cm
3
/g, and the fraction of micropores linearly increased from 0.64 to 0.92 as the C
daf
of the test samples increased from 70.4 to 95.6%. It was shown that an increase in coal rank was responsible for the transition from a micro–mesoporous material to a nanoporous AC.</description><subject>Activated carbon</subject><subject>Activation</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Physical Chemistry</subject><subject>Thermal shock</subject><issn>0361-5219</issn><issn>1934-8029</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp1kF9LwzAUxYMoOKcfwLeAz9Wb5k-TxzGcEwYKm49S2jSz3bpmJqnitzelgg8iXLhwzzm_y70IXRO4pQTo3RqoIDwlKgWIJeQJmhBFWSIhVadoMsjJoJ-jC-93AJwrCRP0urDuUITGdthucagNfrbO9h6vg-t16J0Z5gvrfdPiuS1aj_tjNM_afdE2ncEzHZqPEfDZhBpvahOBLV7XVu8v0dk2RszVT5-il8X9Zr5MVk8Pj_PZKtGUiJCIjBHgVLCiKpUuKxCUEymBacNlSQQjRlKmMlEBFyVLgTGtmMigkJpWQtIpuhm5R2ffe-NDvrO96-LKPKVSUpLJTEUXGV3axXuc2eZH1xwK95UTyIcv5n--GDPpmPHR270Z90v-P_QNJKlx-A</recordid><startdate>20200301</startdate><enddate>20200301</enddate><creator>Kucherenko, V. A.</creator><creator>Tamarkina, Yu. V.</creator><creator>Sabierova, V. A.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20200301</creationdate><title>Formation of the Porous Structure of Fossil Coals upon Alkaline Activation with Thermal Shock</title><author>Kucherenko, V. A. ; Tamarkina, Yu. V. ; Sabierova, V. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-674105364adb9cbd063518804ce58b1641e834976d056b42044c94670a8c3d683</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Activated carbon</topic><topic>Activation</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Physical Chemistry</topic><topic>Thermal shock</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kucherenko, V. A.</creatorcontrib><creatorcontrib>Tamarkina, Yu. V.</creatorcontrib><creatorcontrib>Sabierova, V. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Solid fuel chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kucherenko, V. A.</au><au>Tamarkina, Yu. V.</au><au>Sabierova, V. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Formation of the Porous Structure of Fossil Coals upon Alkaline Activation with Thermal Shock</atitle><jtitle>Solid fuel chemistry</jtitle><stitle>Solid Fuel Chem</stitle><date>2020-03-01</date><risdate>2020</risdate><volume>54</volume><issue>2</issue><spage>79</spage><epage>86</epage><pages>79-86</pages><issn>0361-5219</issn><eissn>1934-8029</eissn><abstract>The porous structure of activated carbons (ACs) formed by fossil coals of different ranks upon alkaline activation with thermal shock (KOH, 800°C) was studied. It was established that the specific surface area of ACs decreased from 2012 to 818 m
2
/g, the pore volume decreased from 1.088 to 0.269 cm
3
/g, and the fraction of micropores linearly increased from 0.64 to 0.92 as the C
daf
of the test samples increased from 70.4 to 95.6%. It was shown that an increase in coal rank was responsible for the transition from a micro–mesoporous material to a nanoporous AC.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.3103/S0361521920020068</doi><tpages>8</tpages></addata></record> |
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subjects | Activated carbon Activation Chemistry Chemistry and Materials Science Physical Chemistry Thermal shock |
title | Formation of the Porous Structure of Fossil Coals upon Alkaline Activation with Thermal Shock |
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