Stereoselective Thermal Isomerization of Triphosphasumanenes, Utilized for Stereocontrolled Synthesis

We found stereoselective thermal isomerizations at the phosphorous centers of triphosphasumanenes in the solid state. Theoretical calculations and thermal analysis indicate that the isomerization is dominated by the thermodynamic stabilities of crystals depending on the alkoxy groups on their skelet...

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Veröffentlicht in:	Chemistry letters 2020-04, Vol.49 (4), p.419-422
Hauptverfasser:	Suda, Yuki, Furukawa, Shunsuke, Saito, Masaichi
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Sprache:	eng
Schlagworte:	Isomerization Stereoselectivity Synthesis Thermal analysis
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creator	Suda, Yuki Furukawa, Shunsuke Saito, Masaichi
description	We found stereoselective thermal isomerizations at the phosphorous centers of triphosphasumanenes in the solid state. Theoretical calculations and thermal analysis indicate that the isomerization is dominated by the thermodynamic stabilities of crystals depending on the alkoxy groups on their skeleton. The stereoselective isomerization of triphosphasumanene was utilized for the synthesis of a high out-of-plane anisotropic syn-derivative from a less out-of-plane anisotropic anti-derivative.
doi_str_mv	10.1246/cl.200032
format	Article
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source	Oxford University Press Journals All Titles (1996-Current)
subjects	Isomerization Stereoselectivity Synthesis Thermal analysis
title	Stereoselective Thermal Isomerization of Triphosphasumanenes, Utilized for Stereocontrolled Synthesis
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