Highly Elastic and >200% Reversibly Stretchable Down‐Conversion White Light‐Emitting Diodes Based on Quantum Dot Gel Emitters
Combining the characteristics of different materials offers exciting new opportunities for advanced applications in various fields. Herein, white light‐emitting diodes (WLEDs) with >200% reversible stretchability are fabricated using six‐color quantum dots (QDs) gel emitters. Stable aqueous‐phase...
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description | Combining the characteristics of different materials offers exciting new opportunities for advanced applications in various fields. Herein, white light‐emitting diodes (WLEDs) with >200% reversible stretchability are fabricated using six‐color quantum dots (QDs) gel emitters. Stable aqueous‐phase alloy core/shell QDs with high quantum yield are obtained via ligand exchange using a ternary solvent system. Transparent and highly stretchable gels with large pores are created by binary‐solvent‐based gelation at low temperatures. Importantly, the QDs and the gel originate from the same two solvents, which make the QDs highly compatible with the gelation process. Consequently, QDs of six different colors are incorporated into the gel without any property degradation. The excellent optical properties of the QDs in the liquid phase (e.g., 17% higher photoluminescence (PL) intensity) are retained in the gel phase. The QD gel (QDG) exhibits elastic deformation up to 200%, with uniform PL over the entire gel. A down‐conversion WLED built using the QDG emitter produces cool white light with a color temperature of 6100 K, a color rendering index of 94, and a luminous efficacy of 72 lm W−1. In addition, the performance of the QDG‐based WLED remains unchanged even after more than 1000 bending/stretching cycles.
New down‐conversion white light‐emitting diodes with stretchable form factor are fabricated based on quantum dot gel emitters. |
doi_str_mv | 10.1002/adom.201901972 |
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New down‐conversion white light‐emitting diodes with stretchable form factor are fabricated based on quantum dot gel emitters.</description><identifier>ISSN: 2195-1071</identifier><identifier>EISSN: 2195-1071</identifier><identifier>DOI: 10.1002/adom.201901972</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Color temperature ; Conversion ; Elastic deformation ; Emitters ; form factors ; Gelation ; Gels ; Liquid phases ; Low temperature ; Luminous efficacy ; Materials science ; mechanical reliability ; Optical properties ; Optics ; Photoluminescence ; Quantum dots ; Solvents ; Stretchability ; White light ; white light emitting diodes</subject><ispartof>Advanced optical materials, 2020-04, Vol.8 (7), p.n/a</ispartof><rights>2020 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3172-ad0db54b6022708ace36c38019c23d74c89d07d3d7485af41b1625cc0b4bbd2e3</citedby><cites>FETCH-LOGICAL-c3172-ad0db54b6022708ace36c38019c23d74c89d07d3d7485af41b1625cc0b4bbd2e3</cites><orcidid>0000-0002-5403-1617</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fadom.201901972$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fadom.201901972$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Le, Thanh‐Hai</creatorcontrib><creatorcontrib>Choi, Yunseok</creatorcontrib><creatorcontrib>Kim, Semin</creatorcontrib><creatorcontrib>Lee, Unhan</creatorcontrib><creatorcontrib>Heo, Eunseo</creatorcontrib><creatorcontrib>Lee, Haney</creatorcontrib><creatorcontrib>Chae, Subin</creatorcontrib><creatorcontrib>Im, Won Bin</creatorcontrib><creatorcontrib>Yoon, Hyeonseok</creatorcontrib><title>Highly Elastic and >200% Reversibly Stretchable Down‐Conversion White Light‐Emitting Diodes Based on Quantum Dot Gel Emitters</title><title>Advanced optical materials</title><description>Combining the characteristics of different materials offers exciting new opportunities for advanced applications in various fields. Herein, white light‐emitting diodes (WLEDs) with >200% reversible stretchability are fabricated using six‐color quantum dots (QDs) gel emitters. Stable aqueous‐phase alloy core/shell QDs with high quantum yield are obtained via ligand exchange using a ternary solvent system. Transparent and highly stretchable gels with large pores are created by binary‐solvent‐based gelation at low temperatures. Importantly, the QDs and the gel originate from the same two solvents, which make the QDs highly compatible with the gelation process. Consequently, QDs of six different colors are incorporated into the gel without any property degradation. The excellent optical properties of the QDs in the liquid phase (e.g., 17% higher photoluminescence (PL) intensity) are retained in the gel phase. The QD gel (QDG) exhibits elastic deformation up to 200%, with uniform PL over the entire gel. A down‐conversion WLED built using the QDG emitter produces cool white light with a color temperature of 6100 K, a color rendering index of 94, and a luminous efficacy of 72 lm W−1. In addition, the performance of the QDG‐based WLED remains unchanged even after more than 1000 bending/stretching cycles.
New down‐conversion white light‐emitting diodes with stretchable form factor are fabricated based on quantum dot gel emitters.</description><subject>Color temperature</subject><subject>Conversion</subject><subject>Elastic deformation</subject><subject>Emitters</subject><subject>form factors</subject><subject>Gelation</subject><subject>Gels</subject><subject>Liquid phases</subject><subject>Low temperature</subject><subject>Luminous efficacy</subject><subject>Materials science</subject><subject>mechanical reliability</subject><subject>Optical properties</subject><subject>Optics</subject><subject>Photoluminescence</subject><subject>Quantum dots</subject><subject>Solvents</subject><subject>Stretchability</subject><subject>White light</subject><subject>white light emitting diodes</subject><issn>2195-1071</issn><issn>2195-1071</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFkEtLAzEUhYMoWGq3rgPicupN5r0RaltboVJ84XLIJGmbMo-aZCzd6T_wN_pLTFtRd0IgN5zvnEsOQqcEugSAXjBRl10KJHUnpgeoRUkaegRicvhnPkYdY5YA4B5-GsQt9D5W80WxwcOCGas4ZpXAlxTgHN_LV6mNyp34YLW0fMHyQuJBva4-3z76dbWT6wo_L5SVeOJyrBOGpbJWVXM8ULWQBl8xIwV22F3DKtuULsDikSzwDnQRJ-hoxgojO993Gz1dDx_7Y28yHd30exOP-ySmHhMg8jDII6A0hoRx6UfcT9x3OfVFHPAkFRCL7ZiEbBaQnEQ05BzyIM8FlX4bne1zV7p-aaSx2bJudOVWZtRPIkJoEgeO6u4prmtjtJxlK61KpjcZgWzbdLZtOvtp2hnSvWGtCrn5h856g-ntr_cLV8mEBA</recordid><startdate>20200401</startdate><enddate>20200401</enddate><creator>Le, Thanh‐Hai</creator><creator>Choi, Yunseok</creator><creator>Kim, Semin</creator><creator>Lee, Unhan</creator><creator>Heo, Eunseo</creator><creator>Lee, Haney</creator><creator>Chae, Subin</creator><creator>Im, Won Bin</creator><creator>Yoon, Hyeonseok</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-5403-1617</orcidid></search><sort><creationdate>20200401</creationdate><title>Highly Elastic and >200% Reversibly Stretchable Down‐Conversion White Light‐Emitting Diodes Based on Quantum Dot Gel Emitters</title><author>Le, Thanh‐Hai ; Choi, Yunseok ; Kim, Semin ; Lee, Unhan ; Heo, Eunseo ; Lee, Haney ; Chae, Subin ; Im, Won Bin ; Yoon, Hyeonseok</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3172-ad0db54b6022708ace36c38019c23d74c89d07d3d7485af41b1625cc0b4bbd2e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Color temperature</topic><topic>Conversion</topic><topic>Elastic deformation</topic><topic>Emitters</topic><topic>form factors</topic><topic>Gelation</topic><topic>Gels</topic><topic>Liquid phases</topic><topic>Low temperature</topic><topic>Luminous efficacy</topic><topic>Materials science</topic><topic>mechanical reliability</topic><topic>Optical properties</topic><topic>Optics</topic><topic>Photoluminescence</topic><topic>Quantum dots</topic><topic>Solvents</topic><topic>Stretchability</topic><topic>White light</topic><topic>white light emitting diodes</topic><toplevel>online_resources</toplevel><creatorcontrib>Le, Thanh‐Hai</creatorcontrib><creatorcontrib>Choi, Yunseok</creatorcontrib><creatorcontrib>Kim, Semin</creatorcontrib><creatorcontrib>Lee, Unhan</creatorcontrib><creatorcontrib>Heo, Eunseo</creatorcontrib><creatorcontrib>Lee, Haney</creatorcontrib><creatorcontrib>Chae, Subin</creatorcontrib><creatorcontrib>Im, Won Bin</creatorcontrib><creatorcontrib>Yoon, Hyeonseok</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Advanced optical materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Le, Thanh‐Hai</au><au>Choi, Yunseok</au><au>Kim, Semin</au><au>Lee, Unhan</au><au>Heo, Eunseo</au><au>Lee, Haney</au><au>Chae, Subin</au><au>Im, Won Bin</au><au>Yoon, Hyeonseok</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Highly Elastic and >200% Reversibly Stretchable Down‐Conversion White Light‐Emitting Diodes Based on Quantum Dot Gel Emitters</atitle><jtitle>Advanced optical materials</jtitle><date>2020-04-01</date><risdate>2020</risdate><volume>8</volume><issue>7</issue><epage>n/a</epage><issn>2195-1071</issn><eissn>2195-1071</eissn><abstract>Combining the characteristics of different materials offers exciting new opportunities for advanced applications in various fields. Herein, white light‐emitting diodes (WLEDs) with >200% reversible stretchability are fabricated using six‐color quantum dots (QDs) gel emitters. Stable aqueous‐phase alloy core/shell QDs with high quantum yield are obtained via ligand exchange using a ternary solvent system. Transparent and highly stretchable gels with large pores are created by binary‐solvent‐based gelation at low temperatures. Importantly, the QDs and the gel originate from the same two solvents, which make the QDs highly compatible with the gelation process. Consequently, QDs of six different colors are incorporated into the gel without any property degradation. The excellent optical properties of the QDs in the liquid phase (e.g., 17% higher photoluminescence (PL) intensity) are retained in the gel phase. The QD gel (QDG) exhibits elastic deformation up to 200%, with uniform PL over the entire gel. A down‐conversion WLED built using the QDG emitter produces cool white light with a color temperature of 6100 K, a color rendering index of 94, and a luminous efficacy of 72 lm W−1. In addition, the performance of the QDG‐based WLED remains unchanged even after more than 1000 bending/stretching cycles.
New down‐conversion white light‐emitting diodes with stretchable form factor are fabricated based on quantum dot gel emitters.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/adom.201901972</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-5403-1617</orcidid></addata></record> |
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subjects | Color temperature Conversion Elastic deformation Emitters form factors Gelation Gels Liquid phases Low temperature Luminous efficacy Materials science mechanical reliability Optical properties Optics Photoluminescence Quantum dots Solvents Stretchability White light white light emitting diodes |
title | Highly Elastic and >200% Reversibly Stretchable Down‐Conversion White Light‐Emitting Diodes Based on Quantum Dot Gel Emitters |
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