Enhancement in thermal, mechanical and electrical properties of novel PVA nanocomposite embedded with SrO nanofillers and the analysis of its thermal degradation behavior by nonisothermal approach

Effect of SrO nanofillers on the physical and chemical properties of newly prepared PVA nanocomposites was investigated in‐depth in this article. The structure of SrO nanopowder and PVA nanocomposites were analyzed using FTIR for surface chemistry and XRD for crystallographic nature. The extent of d...

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Veröffentlicht in:Polymer composites 2020-04, Vol.41 (4), p.1277-1290
Hauptverfasser: Jayaraj, Selvi, Vellaichamy, Parthasarathy, Sehar, Mahalakshmi, Ramasamy, Anbarasan, Ponnusamy, Senthil Kumar, Daramola, Michael O.
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container_end_page 1290
container_issue 4
container_start_page 1277
container_title Polymer composites
container_volume 41
creator Jayaraj, Selvi
Vellaichamy, Parthasarathy
Sehar, Mahalakshmi
Ramasamy, Anbarasan
Ponnusamy, Senthil Kumar
Daramola, Michael O.
description Effect of SrO nanofillers on the physical and chemical properties of newly prepared PVA nanocomposites was investigated in‐depth in this article. The structure of SrO nanopowder and PVA nanocomposites were analyzed using FTIR for surface chemistry and XRD for crystallographic nature. The extent of dispersion and particle size of SrO nanopowders were obtained from TEM micrographs. The average particle size of the SrO nanopowder was 57 nm. The uniformly dispersed SrO nanofillers in the host PVA matrix were observed from the TEM micrographs. The prepared PVA nanocomposites displayed a high absorption in the UV region. The thermal stability of PVA nanocomposites was enhanced after the addition of SrO nanofillers. The nonisothermal degradation study was carried out using different kinetic models for the prepared PVA nanocomposites. The Young's modulus (Y) and tensile strength of the PVA nanocomposites were higher than that of the pristine PVA. The DC conductivity of PVA was also increased when the PVA was embedded with the SrO nanoparticles. Highlights The novel PVA nanocomposites embedded with SrO nanofillers were prepared by the solution casting method. The band gap of PVA was decreased gradually while increasing the concentration of SrO nanofillers. The thermal degradation of polymer composites was studied under nonisothermal heating using several kinetic models. The thermal stability of PVA was enhanced after the addition of SrO nanofillers. The electrical and mechanical Properties of PVA nanocomposites were also improved.
doi_str_mv 10.1002/pc.25453
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The structure of SrO nanopowder and PVA nanocomposites were analyzed using FTIR for surface chemistry and XRD for crystallographic nature. The extent of dispersion and particle size of SrO nanopowders were obtained from TEM micrographs. The average particle size of the SrO nanopowder was 57 nm. The uniformly dispersed SrO nanofillers in the host PVA matrix were observed from the TEM micrographs. The prepared PVA nanocomposites displayed a high absorption in the UV region. The thermal stability of PVA nanocomposites was enhanced after the addition of SrO nanofillers. The nonisothermal degradation study was carried out using different kinetic models for the prepared PVA nanocomposites. The Young's modulus (Y) and tensile strength of the PVA nanocomposites were higher than that of the pristine PVA. The DC conductivity of PVA was also increased when the PVA was embedded with the SrO nanoparticles. Highlights The novel PVA nanocomposites embedded with SrO nanofillers were prepared by the solution casting method. The band gap of PVA was decreased gradually while increasing the concentration of SrO nanofillers. The thermal degradation of polymer composites was studied under nonisothermal heating using several kinetic models. The thermal stability of PVA was enhanced after the addition of SrO nanofillers. The electrical and mechanical Properties of PVA nanocomposites were also improved.</description><identifier>ISSN: 0272-8397</identifier><identifier>EISSN: 1548-0569</identifier><identifier>DOI: 10.1002/pc.25453</identifier><language>eng</language><publisher>Hoboken, USA: John Wiley &amp; Sons, Inc</publisher><subject>bandgap ; Chemical properties ; Crystallography ; degradation ; Electrical properties ; Electrical resistivity ; FWO ; Mechanical properties ; Modulus of elasticity ; Nanocomposites ; Nanoparticles ; Particle size ; Photomicrographs ; Polymer matrix composites ; PVA ; SrO nanoparticles ; Tensile strength ; Thermal degradation ; Thermal stability</subject><ispartof>Polymer composites, 2020-04, Vol.41 (4), p.1277-1290</ispartof><rights>2019 Society of Plastics Engineers</rights><rights>2020 Society of Plastics Engineers</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3303-51bd2d1f806c9ae3236826b2aaa92a2522913662570b4942a85998abb32e31753</citedby><cites>FETCH-LOGICAL-c3303-51bd2d1f806c9ae3236826b2aaa92a2522913662570b4942a85998abb32e31753</cites><orcidid>0000-0001-7621-1371</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpc.25453$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpc.25453$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Jayaraj, Selvi</creatorcontrib><creatorcontrib>Vellaichamy, Parthasarathy</creatorcontrib><creatorcontrib>Sehar, Mahalakshmi</creatorcontrib><creatorcontrib>Ramasamy, Anbarasan</creatorcontrib><creatorcontrib>Ponnusamy, Senthil Kumar</creatorcontrib><creatorcontrib>Daramola, Michael O.</creatorcontrib><title>Enhancement in thermal, mechanical and electrical properties of novel PVA nanocomposite embedded with SrO nanofillers and the analysis of its thermal degradation behavior by nonisothermal approach</title><title>Polymer composites</title><description>Effect of SrO nanofillers on the physical and chemical properties of newly prepared PVA nanocomposites was investigated in‐depth in this article. The structure of SrO nanopowder and PVA nanocomposites were analyzed using FTIR for surface chemistry and XRD for crystallographic nature. The extent of dispersion and particle size of SrO nanopowders were obtained from TEM micrographs. The average particle size of the SrO nanopowder was 57 nm. The uniformly dispersed SrO nanofillers in the host PVA matrix were observed from the TEM micrographs. The prepared PVA nanocomposites displayed a high absorption in the UV region. The thermal stability of PVA nanocomposites was enhanced after the addition of SrO nanofillers. The nonisothermal degradation study was carried out using different kinetic models for the prepared PVA nanocomposites. The Young's modulus (Y) and tensile strength of the PVA nanocomposites were higher than that of the pristine PVA. The DC conductivity of PVA was also increased when the PVA was embedded with the SrO nanoparticles. Highlights The novel PVA nanocomposites embedded with SrO nanofillers were prepared by the solution casting method. The band gap of PVA was decreased gradually while increasing the concentration of SrO nanofillers. The thermal degradation of polymer composites was studied under nonisothermal heating using several kinetic models. The thermal stability of PVA was enhanced after the addition of SrO nanofillers. 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The structure of SrO nanopowder and PVA nanocomposites were analyzed using FTIR for surface chemistry and XRD for crystallographic nature. The extent of dispersion and particle size of SrO nanopowders were obtained from TEM micrographs. The average particle size of the SrO nanopowder was 57 nm. The uniformly dispersed SrO nanofillers in the host PVA matrix were observed from the TEM micrographs. The prepared PVA nanocomposites displayed a high absorption in the UV region. The thermal stability of PVA nanocomposites was enhanced after the addition of SrO nanofillers. The nonisothermal degradation study was carried out using different kinetic models for the prepared PVA nanocomposites. The Young's modulus (Y) and tensile strength of the PVA nanocomposites were higher than that of the pristine PVA. The DC conductivity of PVA was also increased when the PVA was embedded with the SrO nanoparticles. Highlights The novel PVA nanocomposites embedded with SrO nanofillers were prepared by the solution casting method. The band gap of PVA was decreased gradually while increasing the concentration of SrO nanofillers. The thermal degradation of polymer composites was studied under nonisothermal heating using several kinetic models. The thermal stability of PVA was enhanced after the addition of SrO nanofillers. The electrical and mechanical Properties of PVA nanocomposites were also improved.</abstract><cop>Hoboken, USA</cop><pub>John Wiley &amp; Sons, Inc</pub><doi>10.1002/pc.25453</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0001-7621-1371</orcidid></addata></record>
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subjects bandgap
Chemical properties
Crystallography
degradation
Electrical properties
Electrical resistivity
FWO
Mechanical properties
Modulus of elasticity
Nanocomposites
Nanoparticles
Particle size
Photomicrographs
Polymer matrix composites
PVA
SrO nanoparticles
Tensile strength
Thermal degradation
Thermal stability
title Enhancement in thermal, mechanical and electrical properties of novel PVA nanocomposite embedded with SrO nanofillers and the analysis of its thermal degradation behavior by nonisothermal approach
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